Geochronology and geochemistry of the Banjiaoyuan tin deposit, southern Hunan Province and its geological implications

[Display omitted] •Precisely determined the metallogenic age of Banjiaoyuan tin deposit.•Analyzed the origin of ore-forming fluid.•Discussed the elemental substitution mechanism and precipitation of cassiterites in Banjiaoyuan tin deposit. Situated in the central part of the Southern Hunan segment o...

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Published inOre geology reviews Vol. 168; p. 106038
Main Authors Zhang, Zunzun, Xu, Guofeng, Lu, Youyue, Liu, Lei, Hu, Tianyang, Zhang, Tuyan, Du, Yun, Fu, Jianming, Zhang, Kun, Dai, Pingyun
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.05.2024
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Abstract [Display omitted] •Precisely determined the metallogenic age of Banjiaoyuan tin deposit.•Analyzed the origin of ore-forming fluid.•Discussed the elemental substitution mechanism and precipitation of cassiterites in Banjiaoyuan tin deposit. Situated in the central part of the Southern Hunan segment of the Nanling Metallogenic Belt, the Banjiaoyuan tin deposit represents a significant Indosinian quartz vein type tin deposit. Based on field geological surveys and petrographic observations, the mineralization in the area can be divided into three stages: (I) early greisen stage, (II) cassiterite-quartz vein stage, and (III) late barren quartz vein stage. The dating results show that the 40Ar-39Ar plateau age of muscovite in stage I is 215.51 ± 0.87 Ma, and the Rb-Sr isochronous age of quartz mineral in stage II is 214.2 ± 3.1 Ma (MSWD = 1.3), both of which are coincide with the cassiterite U-Pb lower intercept age (215.7 ± 1.3 Ma, MSWD = 1.2), confirming the existence of metallogenic events in this region during the late Indosinian. The δD and δ18O of quartz in stage II range from −66.2 to −80.2 ‰, and 3.71 to 6.17 ‰, respectively, indicating that the ore-forming fluid is mainly derived from a mixture of magmatic-hydrothermal fluids and a small amount of meteoric water. We applied LA-ICP-MS chemical mapping and trace elements analysis to cassiterites, found that they underwent a transition from oxidation to reduction during precipitation when the fluids tend to be more volatile-rich and highly fractionated. The formation of the Banjiaoyuan tin deposit is closely related to the late Indosinian magmatic activity in the Yangmingshan region. Besides, the deep and peripheral parts of the mining area also have the potential for large-scale vein-type and greisen-type W-Sn mineralization.
AbstractList [Display omitted] •Precisely determined the metallogenic age of Banjiaoyuan tin deposit.•Analyzed the origin of ore-forming fluid.•Discussed the elemental substitution mechanism and precipitation of cassiterites in Banjiaoyuan tin deposit. Situated in the central part of the Southern Hunan segment of the Nanling Metallogenic Belt, the Banjiaoyuan tin deposit represents a significant Indosinian quartz vein type tin deposit. Based on field geological surveys and petrographic observations, the mineralization in the area can be divided into three stages: (I) early greisen stage, (II) cassiterite-quartz vein stage, and (III) late barren quartz vein stage. The dating results show that the 40Ar-39Ar plateau age of muscovite in stage I is 215.51 ± 0.87 Ma, and the Rb-Sr isochronous age of quartz mineral in stage II is 214.2 ± 3.1 Ma (MSWD = 1.3), both of which are coincide with the cassiterite U-Pb lower intercept age (215.7 ± 1.3 Ma, MSWD = 1.2), confirming the existence of metallogenic events in this region during the late Indosinian. The δD and δ18O of quartz in stage II range from −66.2 to −80.2 ‰, and 3.71 to 6.17 ‰, respectively, indicating that the ore-forming fluid is mainly derived from a mixture of magmatic-hydrothermal fluids and a small amount of meteoric water. We applied LA-ICP-MS chemical mapping and trace elements analysis to cassiterites, found that they underwent a transition from oxidation to reduction during precipitation when the fluids tend to be more volatile-rich and highly fractionated. The formation of the Banjiaoyuan tin deposit is closely related to the late Indosinian magmatic activity in the Yangmingshan region. Besides, the deep and peripheral parts of the mining area also have the potential for large-scale vein-type and greisen-type W-Sn mineralization.
ArticleNumber 106038
Author Zhang, Tuyan
Hu, Tianyang
Lu, Youyue
Fu, Jianming
Du, Yun
Zhang, Kun
Xu, Guofeng
Dai, Pingyun
Zhang, Zunzun
Liu, Lei
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  surname: Zhang
  fullname: Zhang, Zunzun
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  givenname: Guofeng
  surname: Xu
  fullname: Xu, Guofeng
  organization: Key Laboratory of Metallogenic Prediction of Nonferrous Metals and Geological Environment Monitoring, Ministry of Education, School of Geosciences and Info-Physics, Central South University, Changsha 410083, China
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  surname: Liu
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  email: liu01@ustc.edu.cn
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  givenname: Yun
  surname: Du
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  organization: Hunan Institute of Geological Survey, Changsha, Hunan 410116, China
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  surname: Dai
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  organization: Wuhan Centre, China Geological Survey (Central South China Innovation Center for Geosciences), Wuhan 430205, China
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Keywords Muscovite Ar-Ar dating
Nanling metallogenic belt
Quartz vein type tin ore
Rb-Sr dating of quartz
LA-ICP-MS chemical mapping of cassiterite
Language English
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Snippet [Display omitted] •Precisely determined the metallogenic age of Banjiaoyuan tin deposit.•Analyzed the origin of ore-forming fluid.•Discussed the elemental...
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SubjectTerms LA-ICP-MS chemical mapping of cassiterite
Muscovite Ar-Ar dating
Nanling metallogenic belt
Quartz vein type tin ore
Rb-Sr dating of quartz
Title Geochronology and geochemistry of the Banjiaoyuan tin deposit, southern Hunan Province and its geological implications
URI https://dx.doi.org/10.1016/j.oregeorev.2024.106038
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