Rational Design of a Laminated Dual-Polymer/Polymer–Ceramic Composite Electrolyte for High-Voltage All-Solid-State Lithium Batteries
We present a multi-layer approach to design a laminated dual-polymer/polymer–ceramic composite electrolyte (LDPPCCE) for high-voltage all-solid-state lithium batteries. An anode friendly poly(ethylene oxide) (PEO) serves as a matrix to face the Li-metal anode. To enhance the room-temperature Li+-io...
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Published in | ACS materials letters Vol. 2; no. 4; pp. 317 - 324 |
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Language | English |
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American Chemical Society
06.04.2020
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Abstract | We present a multi-layer approach to design a laminated dual-polymer/polymer–ceramic composite electrolyte (LDPPCCE) for high-voltage all-solid-state lithium batteries. An anode friendly poly(ethylene oxide) (PEO) serves as a matrix to face the Li-metal anode. To enhance the room-temperature Li+-ion conductivity, succinonitrile (SN) is incorporated into the PEO. At the cathode side, an oxidation tolerant poly(acrylonitrile) (PAN) matrix is employed. To enhance the ionic conductivity and suppress lithium dendrite, NASICON-type lithium aluminum titanium phosphate (Li1+x Al x Ti2–x (PO4)3, LATP) powder is integrated into the PAN. The PEO-SN dual-polymer and the PAN-LATP composite deliver matched ionic conductivity. Uniting the two electrolyte layers, the resulting elastic LDPPCCE exhibits an ionic conductivity of 1.31 × 10–4 S cm–1 at ambient temperature with an electrochemical stability window of 0–5 V. All-solid-state lithium cells, fabricated with the LDPPCCE electrolyte, high-capacity/high-voltage LiNi0.8Co0.1Mn0.1O2 cathode, and lithium–metal anode exhibit exceptional electrochemical performance with a long cycle life. |
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AbstractList | We present a multi-layer approach to design a laminated dual-polymer/polymer–ceramic composite electrolyte (LDPPCCE) for high-voltage all-solid-state lithium batteries. An anode friendly poly(ethylene oxide) (PEO) serves as a matrix to face the Li-metal anode. To enhance the room-temperature Li+-ion conductivity, succinonitrile (SN) is incorporated into the PEO. At the cathode side, an oxidation tolerant poly(acrylonitrile) (PAN) matrix is employed. To enhance the ionic conductivity and suppress lithium dendrite, NASICON-type lithium aluminum titanium phosphate (Li1+x Al x Ti2–x (PO4)3, LATP) powder is integrated into the PAN. The PEO-SN dual-polymer and the PAN-LATP composite deliver matched ionic conductivity. Uniting the two electrolyte layers, the resulting elastic LDPPCCE exhibits an ionic conductivity of 1.31 × 10–4 S cm–1 at ambient temperature with an electrochemical stability window of 0–5 V. All-solid-state lithium cells, fabricated with the LDPPCCE electrolyte, high-capacity/high-voltage LiNi0.8Co0.1Mn0.1O2 cathode, and lithium–metal anode exhibit exceptional electrochemical performance with a long cycle life. Not provided. |
Author | Yu, Xingwen Manthiram, Arumugam Li, Jianyu |
AuthorAffiliation | McKetta Department of Chemical Engineering and Texas Materials Institute |
AuthorAffiliation_xml | – name: McKetta Department of Chemical Engineering and Texas Materials Institute |
Author_xml | – sequence: 1 givenname: Xingwen surname: Yu fullname: Yu, Xingwen – sequence: 2 givenname: Jianyu surname: Li fullname: Li, Jianyu – sequence: 3 givenname: Arumugam orcidid: 0000-0003-0237-9563 surname: Manthiram fullname: Manthiram, Arumugam email: manth@austin.utexas.edu |
BackLink | https://www.osti.gov/biblio/1801687$$D View this record in Osti.gov |
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Title | Rational Design of a Laminated Dual-Polymer/Polymer–Ceramic Composite Electrolyte for High-Voltage All-Solid-State Lithium Batteries |
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