Rational Design of a Laminated Dual-Polymer/Polymer–Ceramic Composite Electrolyte for High-Voltage All-Solid-State Lithium Batteries

We present a multi-layer approach to design a laminated dual-polymer/polymer–ceramic composite electrolyte (LDPPCCE) for high-voltage all-solid-state lithium batteries. An anode friendly poly­(ethylene oxide) (PEO) serves as a matrix to face the Li-metal anode. To enhance the room-temperature Li+-io...

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Published inACS materials letters Vol. 2; no. 4; pp. 317 - 324
Main Authors Yu, Xingwen, Li, Jianyu, Manthiram, Arumugam
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 06.04.2020
ACS Publications
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Abstract We present a multi-layer approach to design a laminated dual-polymer/polymer–ceramic composite electrolyte (LDPPCCE) for high-voltage all-solid-state lithium batteries. An anode friendly poly­(ethylene oxide) (PEO) serves as a matrix to face the Li-metal anode. To enhance the room-temperature Li+-ion conductivity, succinonitrile (SN) is incorporated into the PEO. At the cathode side, an oxidation tolerant poly­(acrylonitrile) (PAN) matrix is employed. To enhance the ionic conductivity and suppress lithium dendrite, NASICON-type lithium aluminum titanium phosphate (Li1+x Al x Ti2–x (PO4)3, LATP) powder is integrated into the PAN. The PEO-SN dual-polymer and the PAN-LATP composite deliver matched ionic conductivity. Uniting the two electrolyte layers, the resulting elastic LDPPCCE exhibits an ionic conductivity of 1.31 × 10–4 S cm–1 at ambient temperature with an electrochemical stability window of 0–5 V. All-solid-state lithium cells, fabricated with the LDPPCCE electrolyte, high-capacity/high-voltage LiNi0.8Co0.1Mn0.1O2 cathode, and lithium–metal anode exhibit exceptional electrochemical performance with a long cycle life.
AbstractList We present a multi-layer approach to design a laminated dual-polymer/polymer–ceramic composite electrolyte (LDPPCCE) for high-voltage all-solid-state lithium batteries. An anode friendly poly­(ethylene oxide) (PEO) serves as a matrix to face the Li-metal anode. To enhance the room-temperature Li+-ion conductivity, succinonitrile (SN) is incorporated into the PEO. At the cathode side, an oxidation tolerant poly­(acrylonitrile) (PAN) matrix is employed. To enhance the ionic conductivity and suppress lithium dendrite, NASICON-type lithium aluminum titanium phosphate (Li1+x Al x Ti2–x (PO4)3, LATP) powder is integrated into the PAN. The PEO-SN dual-polymer and the PAN-LATP composite deliver matched ionic conductivity. Uniting the two electrolyte layers, the resulting elastic LDPPCCE exhibits an ionic conductivity of 1.31 × 10–4 S cm–1 at ambient temperature with an electrochemical stability window of 0–5 V. All-solid-state lithium cells, fabricated with the LDPPCCE electrolyte, high-capacity/high-voltage LiNi0.8Co0.1Mn0.1O2 cathode, and lithium–metal anode exhibit exceptional electrochemical performance with a long cycle life.
Not provided.
Author Yu, Xingwen
Manthiram, Arumugam
Li, Jianyu
AuthorAffiliation McKetta Department of Chemical Engineering and Texas Materials Institute
AuthorAffiliation_xml – name: McKetta Department of Chemical Engineering and Texas Materials Institute
Author_xml – sequence: 1
  givenname: Xingwen
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  givenname: Arumugam
  orcidid: 0000-0003-0237-9563
  surname: Manthiram
  fullname: Manthiram, Arumugam
  email: manth@austin.utexas.edu
BackLink https://www.osti.gov/biblio/1801687$$D View this record in Osti.gov
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Snippet We present a multi-layer approach to design a laminated dual-polymer/polymer–ceramic composite electrolyte (LDPPCCE) for high-voltage all-solid-state lithium...
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SubjectTerms Materials Science
Title Rational Design of a Laminated Dual-Polymer/Polymer–Ceramic Composite Electrolyte for High-Voltage All-Solid-State Lithium Batteries
URI http://dx.doi.org/10.1021/acsmaterialslett.9b00535
https://www.osti.gov/biblio/1801687
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