Nanoscale Electrical Degradation of Silicon–Carbon Composite Anode Materials for Lithium-Ion Batteries

High-performance lithium-ion batteries (LIBs) are in increasing demand for a variety of applications in rapidly growing energy-related fields including electric vehicles. To develop high-performance LIBs, it is necessary to comprehensively understand the degradation mechanism of the LIB electrodes....

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Published inACS applied materials & interfaces Vol. 10; no. 29; pp. 24549 - 24553
Main Authors Kim, Seong Heon, Kim, Yong Su, Baek, Woon Joong, Heo, Sung, Yun, Dong-Jin, Han, Sungsoo, Jung, Heechul
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 25.07.2018
Subjects
electrical degradation
Si−C composite
LIB degradation mechanism
scanning spreading resistance microscopy
SSRM
Li-ion battery
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Abstract High-performance lithium-ion batteries (LIBs) are in increasing demand for a variety of applications in rapidly growing energy-related fields including electric vehicles. To develop high-performance LIBs, it is necessary to comprehensively understand the degradation mechanism of the LIB electrodes. From this viewpoint, it is crucial to investigate how the electrical properties of LIB electrodes change under charging and discharging. Here, we probe the local electrical properties of LIB electrodes with nanoscale resolution by scanning spreading resistance microscopy (SSRM). Via quantitative and comparative SSRM measurements on pristine and degraded LIB anodes of Si–C composites blended with graphite (Gr) particles, the electrical degradation of the LIB anodes is visualized. The electrical conductivity of the Si–C composite particles considerably degraded over 300 cycles of charging and discharging, whereas the Gr particles maintained their conductivity.
AbstractList High-performance lithium-ion batteries (LIBs) are in increasing demand for a variety of applications in rapidly growing energy-related fields including electric vehicles. To develop high-performance LIBs, it is necessary to comprehensively understand the degradation mechanism of the LIB electrodes. From this viewpoint, it is crucial to investigate how the electrical properties of LIB electrodes change under charging and discharging. Here, we probe the local electrical properties of LIB electrodes with nanoscale resolution by scanning spreading resistance microscopy (SSRM). Via quantitative and comparative SSRM measurements on pristine and degraded LIB anodes of Si-C composites blended with graphite (Gr) particles, the electrical degradation of the LIB anodes is visualized. The electrical conductivity of the Si-C composite particles considerably degraded over 300 cycles of charging and discharging, whereas the Gr particles maintained their conductivity.
Author Yun, Dong-Jin
Baek, Woon Joong
Kim, Yong Su
Heo, Sung
Kim, Seong Heon
Jung, Heechul
Han, Sungsoo
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Keywords electrical degradation
Si−C composite
LIB degradation mechanism
scanning spreading resistance microscopy
SSRM
Li-ion battery
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Title Nanoscale Electrical Degradation of Silicon–Carbon Composite Anode Materials for Lithium-Ion Batteries
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