Ecofriendly Synthesis of Ceria Foam via Carboxymethylcellulose Gelation: Application for the Epoxidation of Chalcone

A simple and innovative process is described for the ecofriendly preparation of ceria foams via carboxymethylcellulose gelation by Ce4+ cations; heat treatment of the ensuing xerogels produces ceria foams. The influence of the concentration of cerium and of the calcination temperature of the xerogel...

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Published inACS sustainable chemistry & engineering Vol. 3; no. 11; pp. 2786 - 2795
Main Authors Ramananarivo, H. R, Maati, H, Amadine, O, Abdelouahdi, K, Barakat, A, Ihiawakrim, D, Ersen, O, Varma, Rajender S, Solhy, A
Format Journal Article
LanguageEnglish
Published American Chemical Society 02.11.2015
Subjects
Chemical and Process Engineering
Engineering Sciences
Epoxidation
Ceria foams
Xerogel
Gelation
Chalcone
Biopolymer
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Abstract A simple and innovative process is described for the ecofriendly preparation of ceria foams via carboxymethylcellulose gelation by Ce4+ cations; heat treatment of the ensuing xerogels produces ceria foams. The influence of the concentration of cerium and of the calcination temperature of the xerogels is studied. Several characterization methods have been used and the obtained results demonstrate that this technique allows the controlled growth of ceria foams. The foamy structure apparently is responsible for UV absorption, and the ceria foam is basic enough to promote the epoxidation of chalcone; comparison of the catalytic activity of the ceria foam versus ceria prepared via a coprecipitation method shows that the ceria foam is most active as it promotes epoxidation of electron-deficient alkenes with dilute aqueous hydrogen peroxide.
AbstractList A simple and innovative process is described for the ecofriendly preparation of ceria foams via carboxymethylcellulose gelation by Ce4+ cations; heat treatment of the ensuing xerogels produces ceria foams. The influence of the concentration of cerium and of the calcination temperature of the xerogels is studied. Several characterization methods have been used and the obtained results demonstrate that this technique allows the controlled growth of ceria foams. The foamy structure apparently is responsible for UV absorption, and the ceria foam is basic enough to promote the epoxidation of chalcone; comparison of the catalytic activity of the ceria foam versus ceria prepared via a coprecipitation method shows that the ceria foam is most active as it promotes epoxidation of electron-deficient alkenes with dilute aqueous hydrogen peroxide.
Author Maati, H
Ihiawakrim, D
Abdelouahdi, K
Varma, Rajender S
Ramananarivo, H. R
Amadine, O
Ersen, O
Solhy, A
Barakat, A
AuthorAffiliation Université Mohammed VI Polytechnique
UATRS-CNRST, Angle Allal Fassi/FAR
U.S. Environmental Protection Agency
FST
National Risk Management Research Laboratory, Sustainable Technology Division
CNRS-UdS UMR 7504
Université Hassan II
IPCMS-Groupe Surfaces & Interfaces
Center for Advanced Materials
INRA, UMR 1208 (IATE) 2
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Cites_doi 10.1039/C2CY20458D
10.1002/anie.201106064
10.1016/j.micromeso.2013.05.011
10.1021/jp104715w
10.1002/adma.200702249
10.1021/jp804572t
10.1016/j.taap.2014.10.011
10.1016/j.jssc.2008.02.034
10.1039/C5CC00360A
10.1021/am300732v
10.1021/ic00201a033
10.1016/j.ccr.2014.01.013
10.1039/c0jm03267k
10.1016/j.ccr.2014.01.035
10.1111/j.1744-7402.2008.02303.x
10.1021/jp202720g
10.1002/adsc.200390051
10.1002/ejic.201200907
10.1002/anie.201108708
10.1002/anie.201310420
10.1021/cm062471b
10.1021/jp200645q
10.1002/anie.201308384
10.1021/nn200126a
10.1021/cg200299y
10.1021/cg101585b
10.1016/j.fuel.2013.06.023
10.1021/cm0507967
10.1039/c2ee22310d
10.1016/j.matchemphys.2005.10.030
10.1021/jp9065168
10.1016/S0040-4039(00)86236-X
10.1021/ja01059a037
10.1016/j.bmcl.2010.08.106
10.1002/cssc.201100374
10.1016/j.jpowsour.2013.04.130
10.1016/j.apcatb.2007.09.006
10.1021/cm051352d
10.1039/C2CS35443H
10.1016/j.jallcom.2013.06.094
10.1021/cg901515r
10.1016/S0920-5861(98)00510-0
10.1038/nmat1129
10.1021/jp074011r
10.1002/anie.201107838
10.1016/j.catcom.2013.02.002
10.1039/C2CE26540K
10.1016/j.materresbull.2013.06.038
10.1039/B509985D
10.1021/cr020471z
10.1021/ar300035z
10.1002/ejic.201201058
10.1021/jp807348n
10.1002/anie.200902994
10.1021/jp101553x
10.1021/ef3013757
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Issue 11
Keywords Epoxidation
Ceria foams
Xerogel
Gelation
Chalcone
Biopolymer
Language English
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References ref9/cit9
ref45/cit45
ref3/cit3
ref27/cit27
ref56/cit56
ref16/cit16
ref52/cit52
ref23/cit23
ref8/cit8
ref31/cit31
ref2/cit2
ref34/cit34
ref37/cit37
ref20/cit20
ref48/cit48
ref17/cit17
ref10/cit10
ref35/cit35
Hutzler D. (ref28/cit28) 1999
ref53/cit53
ref19/cit19
ref21/cit21
ref42/cit42
ref46/cit46
ref49/cit49
ref13/cit13
ref24/cit24
ref38/cit38
ref50/cit50
ref54/cit54
ref6/cit6
ref36/cit36
ref18/cit18
ref11/cit11
ref25/cit25
ref29/cit29
ref32/cit32
ref39/cit39
ref14/cit14
ref57/cit57
ref5/cit5
ref51/cit51
ref43/cit43
ref40/cit40
ref26/cit26
ref55/cit55
ref12/cit12
ref15/cit15
ref41/cit41
ref22/cit22
ref33/cit33
ref4/cit4
ref30/cit30
ref47/cit47
ref1/cit1
ref44/cit44
ref7/cit7
References_xml – ident: ref35/cit35
  doi: 10.1039/C2CY20458D
– ident: ref50/cit50
  doi: 10.1002/anie.201106064
– ident: ref7/cit7
  doi: 10.1016/j.micromeso.2013.05.011
– ident: ref18/cit18
  doi: 10.1021/jp104715w
– ident: ref29/cit29
  doi: 10.1002/adma.200702249
– ident: ref31/cit31
  doi: 10.1021/jp804572t
– ident: ref42/cit42
  doi: 10.1016/j.taap.2014.10.011
– ident: ref6/cit6
  doi: 10.1016/j.jssc.2008.02.034
– ident: ref44/cit44
  doi: 10.1039/C5CC00360A
– ident: ref56/cit56
  doi: 10.1021/am300732v
– ident: ref15/cit15
  doi: 10.1021/ic00201a033
– ident: ref47/cit47
  doi: 10.1016/j.ccr.2014.01.013
– ident: ref38/cit38
  doi: 10.1039/c0jm03267k
– ident: ref53/cit53
  doi: 10.1016/j.ccr.2014.01.035
– ident: ref27/cit27
  doi: 10.1111/j.1744-7402.2008.02303.x
– ident: ref57/cit57
  doi: 10.1021/jp202720g
– ident: ref48/cit48
  doi: 10.1002/adsc.200390051
– ident: ref36/cit36
  doi: 10.1002/ejic.201200907
– ident: ref33/cit33
  doi: 10.1002/anie.201108708
– ident: ref51/cit51
  doi: 10.1002/anie.201310420
– ident: ref21/cit21
  doi: 10.1021/cm062471b
– ident: ref25/cit25
  doi: 10.1021/jp200645q
– ident: ref52/cit52
  doi: 10.1002/anie.201308384
– ident: ref8/cit8
  doi: 10.1021/nn200126a
– ident: ref16/cit16
  doi: 10.1021/cg200299y
– ident: ref20/cit20
  doi: 10.1021/cg101585b
– ident: ref24/cit24
  doi: 10.1016/j.fuel.2013.06.023
– ident: ref10/cit10
  doi: 10.1021/cm0507967
– ident: ref1/cit1
  doi: 10.1039/c2ee22310d
– ident: ref11/cit11
  doi: 10.1016/j.matchemphys.2005.10.030
– ident: ref9/cit9
  doi: 10.1021/jp9065168
– ident: ref40/cit40
  doi: 10.1016/S0040-4039(00)86236-X
– ident: ref45/cit45
  doi: 10.1021/ja01059a037
– ident: ref41/cit41
  doi: 10.1016/j.bmcl.2010.08.106
– ident: ref30/cit30
  doi: 10.1002/cssc.201100374
– ident: ref5/cit5
  doi: 10.1016/j.jpowsour.2013.04.130
– ident: ref26/cit26
  doi: 10.1016/j.apcatb.2007.09.006
– ident: ref14/cit14
  doi: 10.1021/cm051352d
– ident: ref46/cit46
  doi: 10.1039/C2CS35443H
– ident: ref4/cit4
  doi: 10.1016/j.jallcom.2013.06.094
– ident: ref19/cit19
  doi: 10.1021/cg901515r
– ident: ref2/cit2
  doi: 10.1016/S0920-5861(98)00510-0
– ident: ref22/cit22
  doi: 10.1038/nmat1129
– ident: ref12/cit12
  doi: 10.1021/jp074011r
– ident: ref32/cit32
  doi: 10.1002/anie.201107838
– ident: ref3/cit3
  doi: 10.1016/j.catcom.2013.02.002
– ident: ref37/cit37
  doi: 10.1039/C2CE26540K
– ident: ref39/cit39
  doi: 10.1016/j.materresbull.2013.06.038
– ident: ref49/cit49
  doi: 10.1039/B509985D
– ident: ref54/cit54
  doi: 10.1021/cr020471z
– ident: ref43/cit43
  doi: 10.1021/ar300035z
– ident: ref55/cit55
  doi: 10.1002/ejic.201201058
– ident: ref17/cit17
  doi: 10.1021/jp807348n
– ident: ref23/cit23
  doi: 10.1002/anie.200902994
– volume-title: The Physics of Foams
  year: 1999
  ident: ref28/cit28
  contributor:
    fullname: Hutzler D.
– ident: ref13/cit13
  doi: 10.1021/jp101553x
– ident: ref34/cit34
  doi: 10.1021/ef3013757
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Title Ecofriendly Synthesis of Ceria Foam via Carboxymethylcellulose Gelation: Application for the Epoxidation of Chalcone
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