Dolomitization of felsic volcaniclastic rocks in continental strata: A study from the Lower Cretaceous of the A'nan Sag in Er'lian Basin, China

Dolomitization of fine-grained volcaniclastic rocks is common in the Lower Cretaceous of the A'nan Sag in the Er'lian Basin of China. Analysis of core samples shows that the organic-rich volcaniclastic rocks are mainly composed of reworked felsic volcanic materials and terrigenous clay min...

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Published inSedimentary geology Vol. 353; pp. 13 - 27
Main Authors Zhu, Shifa, Yue, Hui, Zhu, Xiaomin, Sun, Shuyang, Wei, Wei, Liu, Xin, Jia, Ye
Format Journal Article
LanguageEnglish
Published Elsevier B.V 15.05.2017
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Abstract Dolomitization of fine-grained volcaniclastic rocks is common in the Lower Cretaceous of the A'nan Sag in the Er'lian Basin of China. Analysis of core samples shows that the organic-rich volcaniclastic rocks are mainly composed of reworked felsic volcanic materials and terrigenous clay minerals. The fine-grained volcaniclastic rocks can be divided into four types: volcaniclastic rocks without carbonatization, volcaniclastic rocks with ferroan dolomites, dolomitized and calcified volcaniclastic rocks, and calcified volcaniclastic rocks. The parent rocks of the volcaniclastic rocks have high silicon and potassium contents and low iron and magnesium contents, and are probably felsic magma of the calc-alkaline series. The average values of δ13CPDB of the carbonate minerals are about 3.13‰; the average values of δ18OPDB are about −16.74‰. The compositions of C and O isotopes are probably influenced by bacterial methanogenesis. Iron, magnesium, and calcium are probably derived from illitization of terrigenous smectite. A model for dolomitization of felsic volcaniclastic rock is proposed, including three stages: 1) mixed sedimentation and bacterial methanogenesis (<75°C); 2) transformation of clay minerals (>70°C) and dolomitization (75 to 97°C); and 3) dissolution. Late dissolution of authigenic carbonate minerals, creating abundant secondary pores, is significant for hydrocarbon accumulation.
AbstractList Dolomitization of fine-grained volcaniclastic rocks is common in the Lower Cretaceous of the A'nan Sag in the Er'lian Basin of China. Analysis of core samples shows that the organic-rich volcaniclastic rocks are mainly composed of reworked felsic volcanic materials and terrigenous clay minerals. The fine-grained volcaniclastic rocks can be divided into four types: volcaniclastic rocks without carbonatization, volcaniclastic rocks with ferroan dolomites, dolomitized and calcified volcaniclastic rocks, and calcified volcaniclastic rocks. The parent rocks of the volcaniclastic rocks have high silicon and potassium contents and low iron and magnesium contents, and are probably felsic magma of the calc-alkaline series. The average values of δ13CPDB of the carbonate minerals are about 3.13‰; the average values of δ18OPDB are about −16.74‰. The compositions of C and O isotopes are probably influenced by bacterial methanogenesis. Iron, magnesium, and calcium are probably derived from illitization of terrigenous smectite. A model for dolomitization of felsic volcaniclastic rock is proposed, including three stages: 1) mixed sedimentation and bacterial methanogenesis (<75°C); 2) transformation of clay minerals (>70°C) and dolomitization (75 to 97°C); and 3) dissolution. Late dissolution of authigenic carbonate minerals, creating abundant secondary pores, is significant for hydrocarbon accumulation.
Author Jia, Ye
Wei, Wei
Yue, Hui
Zhu, Xiaomin
Liu, Xin
Zhu, Shifa
Sun, Shuyang
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Keywords Ferroan dolomite
A'nan Sag
Volcaniclastic rock
Dolomitization
Felsic volcanic materials
Er'lian Basin
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Snippet Dolomitization of fine-grained volcaniclastic rocks is common in the Lower Cretaceous of the A'nan Sag in the Er'lian Basin of China. Analysis of core samples...
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StartPage 13
SubjectTerms A'nan Sag
Dolomitization
Er'lian Basin
Felsic volcanic materials
Ferroan dolomite
Volcaniclastic rock
Title Dolomitization of felsic volcaniclastic rocks in continental strata: A study from the Lower Cretaceous of the A'nan Sag in Er'lian Basin, China
URI https://dx.doi.org/10.1016/j.sedgeo.2017.03.004
Volume 353
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