Reducing Substrate Pinning of Block Copolymer Microdomains with a Buffer Layer of Polymer Brushes
We study the range of orientational order of a single layer of cylindrical block copolymer microdomains annealed on several types of substrates. The orientational persistence length or nematic correlation length (ξ) is evaluated using recently developed imaging and analysis methods to measure the gr...
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Published in | Macromolecules Vol. 33; no. 3; pp. 857 - 865 |
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Main Authors | , , , , , , , , , , , , |
Format | Journal Article |
Language | English |
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Washington, DC
American Chemical Society
08.02.2000
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Abstract | We study the range of orientational order of a single layer of cylindrical block copolymer microdomains annealed on several types of substrates. The orientational persistence length or nematic correlation length (ξ) is evaluated using recently developed imaging and analysis methods to measure the grain size of the block copolymer microdomains. We show that the substrate can lower ξ for block copolymers with a majority component that interacts strongly with the substrate, but this can be mitigated by attaching a buffer layer of polystyrene brushes to the substrate. In addition, we show that, for a block copolymer where the block that strongly interacts with the substrate is the minority component, the microdomain correlation length does not increase when substrates are treated with this buffer layer. We suggest that in this case the brushes do not increase ξ not only because of the lower volume fraction of the strongly interacting component but also because there are block copolymer wetting layers at the free and substrate interfaces that decouple the microdomains from the substrate in a similar manner as the polystyrene brushes. |
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AbstractList | We study the range of orientational order of a single layer of cylindrical block copolymer microdomains annealed on several types of substrates. The orientational persistence length or nematic correlation length (ξ) is evaluated using recently developed imaging and analysis methods to measure the grain size of the block copolymer microdomains. We show that the substrate can lower ξ for block copolymers with a majority component that interacts strongly with the substrate, but this can be mitigated by attaching a buffer layer of polystyrene brushes to the substrate. In addition, we show that, for a block copolymer where the block that strongly interacts with the substrate is the minority component, the microdomain correlation length does not increase when substrates are treated with this buffer layer. We suggest that in this case the brushes do not increase ξ not only because of the lower volume fraction of the strongly interacting component but also because there are block copolymer wetting layers at the free and substrate interfaces that decouple the microdomains from the substrate in a similar manner as the polystyrene brushes. |
Author | Russell, T. P Huse, David A Egolf, David A Daniel, Abishai Huang, E Adamson, Douglas H Mansky, P Melnikov, Ilarion V Bodenschatz, Eberhard Register, Richard A Hawker, Craig J Harrison, Christopher Chaikin, Paul M |
Author_xml | – sequence: 1 givenname: Christopher surname: Harrison fullname: Harrison, Christopher – sequence: 2 givenname: Paul M surname: Chaikin fullname: Chaikin, Paul M – sequence: 3 givenname: David A surname: Huse fullname: Huse, David A – sequence: 4 givenname: Richard A surname: Register fullname: Register, Richard A – sequence: 5 givenname: Douglas H surname: Adamson fullname: Adamson, Douglas H – sequence: 6 givenname: Abishai surname: Daniel fullname: Daniel, Abishai – sequence: 7 givenname: E surname: Huang fullname: Huang, E – sequence: 8 givenname: P surname: Mansky fullname: Mansky, P – sequence: 9 givenname: T. P surname: Russell fullname: Russell, T. P – sequence: 10 givenname: Craig J surname: Hawker fullname: Hawker, Craig J – sequence: 11 givenname: David A surname: Egolf fullname: Egolf, David A – sequence: 12 givenname: Ilarion V surname: Melnikov fullname: Melnikov, Ilarion V – sequence: 13 givenname: Eberhard surname: Bodenschatz fullname: Bodenschatz, Eberhard |
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Cites_doi | 10.1021/ma980705+ 10.1021/ma00048a036 10.1007/978-1-4899-2566-4 10.1021/ma9515137 10.1021/ma9600724 10.1007/BF00353023 10.1021/la960774m 10.1007/BF01115708 10.1021/ja00103a055 10.1021/ma00117a032 10.1021/ma00058a022 10.1103/PhysRevLett.80.3228 10.1016/S0032-3861(97)00613-7 10.1146/annurev.pc.41.100190.002521 10.1021/ma9716037 10.1002/macp.1992.021931009 10.1126/science.275.5305.1458 10.1103/PhysRevA.14.2307 10.1021/ma00124a011 10.1051/jphys:01990005108077700 10.1103/PhysRevB.23.316 10.1116/1.589860 10.1103/PhysRevLett.77.3677 10.1021/ma00199a006 10.1021/ma971086s 10.1002/pol.1975.180130703 10.5254/1.3547458 10.1007/BF00687278 10.1063/1.477702 10.1021/ma951905d 10.1017/CBO9780511622496 10.1021/ma00232a023 |
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Keywords | Triblock copolymer Domain structure Order parameter SBS Morphology Temperature effect Experimental study Cylindrical shape Correlation length Thin film |
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References | Tung L. H. (ma991551gb00022/ma991551gb00022_1) 1977 Chen J. T. (ma991551gb00011/ma991551gb00011_1) 1996; 31 Dai H. J. (ma991551gb00004/ma991551gb00004_1) 1996; 77 Harrison C. (ma991551gb00009/ma991551gb00009_1) 1998; 16 Harrison C. (ma991551gb00014/ma991551gb00014_1) 1998; 31 Krause S. (ma991551gb00020/ma991551gb00020_1) 1982; 15 Hawker C. J. (ma991551gb00026/ma991551gb00026_1) 1996; 29 Annis B. K. (ma991551gb00010/ma991551gb00010_1) 1992; 193 Ahagon A. (ma991551gb00016/ma991551gb00016_1) 1975; 13 Toner J. (ma991551gb00036/ma991551gb00036_1) 1980; 23 Morrison F. (ma991551gb00021/ma991551gb00021_1) 1989; 22 Harrison C. (ma991551gb00013/ma991551gb00013_1) 1998; 30 Harrison C. Ph.D. (ma991551gb00037/ma991551gb00037_1) 1999 Park M. (ma991551gb00008/ma991551gb00008_1) 1997; 29 Amundson K. (ma991551gb00035/ma991551gb00035_1) 1993; 26 Balsara N. P. (ma991551gb00006/ma991551gb00006_1) 1992; 25 Park M. (ma991551gb00028/ma991551gb00028_1) 1997 Henkee C. S. (ma991551gb00002/ma991551gb00002_1) 1988; 23 Bates F. S. (ma991551gb00001/ma991551gb00001_1) 1990; 41 Chandrasekhar S. (ma991551gb00034/ma991551gb00034_1) 1992 Newstein M. C. (ma991551gb00003/ma991551gb00003_1) 1998; 31 Hawker C. J. (ma991551gb00024/ma991551gb00024_1) 1994; 116 Egolf D. A. (ma991551gb00032/ma991551gb00032_1) 1998; 80 Meyer R. B. (ma991551gb00033/ma991551gb00033_1) 1976; 14 Newstein M. C. (ma991551gb00007/ma991551gb00007_1) 1995; 28 Coulon G. (ma991551gb00029/ma991551gb00029_1) 1990; 51 Jones R. A. L. (ma991551gb00017/ma991551gb00017_1) 1992; 25 Hawker C. J. (ma991551gb00025/ma991551gb00025_1) 1996; 29 Mansky P. (ma991551gb00023/ma991551gb00023_1) 1997; 275 van Dijk M. A. (ma991551gb00031/ma991551gb00031_1) 1995; 28 van Roosmalen A. J. (ma991551gb00027/ma991551gb00027_1) 1991 Garetz B. A. (ma991551gb00005/ma991551gb00005_1) 1996; 29 Huang E. (ma991551gb00015/ma991551gb00015_1) 1998; 31 Mansky P. (ma991551gb00018/ma991551gb00018_1) 1995; 30 Morton M. (ma991551gb00019/ma991551gb00019_1) 1975; 48 Lee T. (ma991551gb00030/ma991551gb00030_1) 1997; 13 Hahm J. (ma991551gb00012/ma991551gb00012_1) 1998; 109 |
References_xml | – volume: 31 start-page: 7641 year: 1998 ident: ma991551gb00015/ma991551gb00015_1 publication-title: Macromolecules doi: 10.1021/ma980705+ contributor: fullname: Huang E. – volume: 25 start-page: 6072 year: 1992 ident: ma991551gb00006/ma991551gb00006_1 publication-title: J. Macromolecules doi: 10.1021/ma00048a036 contributor: fullname: Balsara N. P. – volume-title: Dry Etching for VLSI year: 1991 ident: ma991551gb00027/ma991551gb00027_1 doi: 10.1007/978-1-4899-2566-4 contributor: fullname: van Roosmalen A. J. – volume: 29 start-page: 2686 year: 1996 ident: ma991551gb00026/ma991551gb00026_1 publication-title: Macromolecules doi: 10.1021/ma9515137 contributor: fullname: Hawker C. J. – volume: 29 start-page: 4675 year: 1996 ident: ma991551gb00005/ma991551gb00005_1 publication-title: Macromolecules doi: 10.1021/ma9600724 contributor: fullname: Garetz B. A. – volume: 30 start-page: 1987 year: 1995 ident: ma991551gb00018/ma991551gb00018_1 publication-title: J. Mater. Sci. doi: 10.1007/BF00353023 contributor: fullname: Mansky P. – volume-title: Fractionation of Synthetic Polymers: Principles and Practices year: 1977 ident: ma991551gb00022/ma991551gb00022_1 contributor: fullname: Tung L. H. – volume: 13 start-page: 3866 year: 1997 ident: ma991551gb00030/ma991551gb00030_1 publication-title: Langmuir doi: 10.1021/la960774m contributor: fullname: Lee T. – volume: 23 start-page: 1685 year: 1988 ident: ma991551gb00002/ma991551gb00002_1 publication-title: J. Mater. Sci. doi: 10.1007/BF01115708 contributor: fullname: Henkee C. S. – volume: 25 start-page: 2539 year: 1992 ident: ma991551gb00017/ma991551gb00017_1 publication-title: J. Macromolecules contributor: fullname: Jones R. A. L. – volume: 116 start-page: 11314 year: 1994 ident: ma991551gb00024/ma991551gb00024_1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00103a055 contributor: fullname: Hawker C. J. – volume: 28 start-page: 4587 year: 1995 ident: ma991551gb00007/ma991551gb00007_1 publication-title: Macromolecules doi: 10.1021/ma00117a032 contributor: fullname: Newstein M. C. – volume: 26 start-page: 1324 year: 1993 ident: ma991551gb00035/ma991551gb00035_1 publication-title: Macromolecules doi: 10.1021/ma00058a022 contributor: fullname: Amundson K. – volume-title: Mater. Res. Soc. Symp. Proc. year: 1997 ident: ma991551gb00028/ma991551gb00028_1 contributor: fullname: Park M. – volume: 80 start-page: 3228 year: 1998 ident: ma991551gb00032/ma991551gb00032_1 publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.80.3228 contributor: fullname: Egolf D. A. – volume: 30 start-page: 2733 year: 1998 ident: ma991551gb00013/ma991551gb00013_1 publication-title: Polymer doi: 10.1016/S0032-3861(97)00613-7 contributor: fullname: Harrison C. – volume: 41 start-page: 525 year: 1990 ident: ma991551gb00001/ma991551gb00001_1 publication-title: Annu. Rev. Phys. Chem. doi: 10.1146/annurev.pc.41.100190.002521 contributor: fullname: Bates F. S. – volume: 31 start-page: 2185 year: 1998 ident: ma991551gb00014/ma991551gb00014_1 publication-title: Macromolecules doi: 10.1021/ma9716037 contributor: fullname: Harrison C. – volume: 193 start-page: 2589 year: 1992 ident: ma991551gb00010/ma991551gb00010_1 publication-title: Makromol. Chem. doi: 10.1002/macp.1992.021931009 contributor: fullname: Annis B. K. – volume: 275 start-page: 1458 year: 1997 ident: ma991551gb00023/ma991551gb00023_1 publication-title: Science doi: 10.1126/science.275.5305.1458 contributor: fullname: Mansky P. – volume: 14 start-page: 2307 year: 1976 ident: ma991551gb00033/ma991551gb00033_1 publication-title: Phys. Rev. A doi: 10.1103/PhysRevA.14.2307 contributor: fullname: Meyer R. B. – volume: 29 start-page: 4494 year: 1997 ident: ma991551gb00008/ma991551gb00008_1 publication-title: Science contributor: fullname: Park M. – volume: 28 start-page: 6773 year: 1995 ident: ma991551gb00031/ma991551gb00031_1 publication-title: Macromolecules doi: 10.1021/ma00124a011 contributor: fullname: van Dijk M. A. – volume: 51 start-page: 777 year: 1990 ident: ma991551gb00029/ma991551gb00029_1 publication-title: J. Phys. (Paris) doi: 10.1051/jphys:01990005108077700 contributor: fullname: Coulon G. – volume: 23 start-page: 316 year: 1980 ident: ma991551gb00036/ma991551gb00036_1 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.23.316 contributor: fullname: Toner J. – volume: 16 start-page: 544 year: 1998 ident: ma991551gb00009/ma991551gb00009_1 publication-title: J. Vac. Sci. Technol. B doi: 10.1116/1.589860 contributor: fullname: Harrison C. – volume: 77 start-page: 3677 year: 1996 ident: ma991551gb00004/ma991551gb00004_1 publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.77.3677 contributor: fullname: Dai H. J. – volume: 22 start-page: 3533 year: 1989 ident: ma991551gb00021/ma991551gb00021_1 publication-title: Macromolecules doi: 10.1021/ma00199a006 contributor: fullname: Morrison F. – volume: 31 start-page: 64 year: 1998 ident: ma991551gb00003/ma991551gb00003_1 publication-title: J. Macromolecules doi: 10.1021/ma971086s contributor: fullname: Newstein M. C. – volume: 13 start-page: 1285 year: 1975 ident: ma991551gb00016/ma991551gb00016_1 publication-title: J. Polym. Sci., Polym. Phys. Ed. doi: 10.1002/pol.1975.180130703 contributor: fullname: Ahagon A. – volume: 48 start-page: 359 year: 1975 ident: ma991551gb00019/ma991551gb00019_1 publication-title: J. Rubber Chem. Technol. doi: 10.5254/1.3547458 contributor: fullname: Morton M. – volume: 31 start-page: 2531 year: 1996 ident: ma991551gb00011/ma991551gb00011_1 publication-title: J. Mater. Sci. doi: 10.1007/BF00687278 contributor: fullname: Chen J. T. – volume-title: Princeton University year: 1999 ident: ma991551gb00037/ma991551gb00037_1 contributor: fullname: Harrison C. Ph.D. – volume: 109 start-page: 10111 year: 1998 ident: ma991551gb00012/ma991551gb00012_1 publication-title: J. Chem. Phys. doi: 10.1063/1.477702 contributor: fullname: Hahm J. – volume: 29 start-page: 5245 year: 1996 ident: ma991551gb00025/ma991551gb00025_1 publication-title: Macromolecules doi: 10.1021/ma951905d contributor: fullname: Hawker C. J. – volume-title: Liquid Crystals year: 1992 ident: ma991551gb00034/ma991551gb00034_1 doi: 10.1017/CBO9780511622496 contributor: fullname: Chandrasekhar S. – volume: 15 start-page: 1076 year: 1982 ident: ma991551gb00020/ma991551gb00020_1 publication-title: Macromolecules doi: 10.1021/ma00232a023 contributor: fullname: Krause S. |
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Snippet | We study the range of orientational order of a single layer of cylindrical block copolymer microdomains annealed on several types of substrates. The... |
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SubjectTerms | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization Structure, morphology and analysis |
Title | Reducing Substrate Pinning of Block Copolymer Microdomains with a Buffer Layer of Polymer Brushes |
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