Phase-Separation-Induced Porous Lithiophilic Polymer Coating for High-Efficiency Lithium Metal Batteries

Solid-electrolyte interphase (SEI) plays a pivotal role in stabilizing lithium (Li) metal anode for rechargeable batteries. However, electrolyte-derived SEI often suffers from poor stability, leading to Li dendrite growth, consumption of electrolyte, and short cycle life. Here, we report a porous li...

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Published inNano letters Vol. 21; no. 11; pp. 4757 - 4764
Main Authors Wang, Dongdong, Liu, Hongxia, Liu, Fang, Ma, Guorong, Yang, Jian, Gu, Xiaodan, Zhou, Meng, Chen, Zheng
Format Journal Article
LanguageEnglish
Published American Chemical Society 09.06.2021
Subjects
lithiophilic interface
solid-electrolyte interphase
phase separation
PVDF−PAN blends coating
lithium metal anodes
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Abstract Solid-electrolyte interphase (SEI) plays a pivotal role in stabilizing lithium (Li) metal anode for rechargeable batteries. However, electrolyte-derived SEI often suffers from poor stability, leading to Li dendrite growth, consumption of electrolyte, and short cycle life. Here, we report a porous lithiophilic polymer coating induced by phase separation of polyvinylidenefluoride–polyacrylonitrile (PVDF–PAN) blends for stabilizing Li metal anode. Different from single polymer coating, PVDF–PAN blends protective layer with porous structures caused by phase separation can provide effective Li+ transport channels and regulate uniform Li+ flux. The lithiophilic functional groups of CN and C–F can promote uniform Li deposition and accelerate Li+ diffusion at the same time during plating/stripping process. As a result, Li||NCM811 full cells using PVDF–PAN coated Li present an apparently improved cycling stability and higher Coulombic efficiency with lean electrolyte (7.5 μL mA h–1), limited Li supply (N/P ratio = 2.4), and high areal capacity (4.0 mA h cm–2).
AbstractList Solid-electrolyte interphase (SEI) plays a pivotal role in stabilizing lithium (Li) metal anode for rechargeable batteries. However, electrolyte-derived SEI often suffers from poor stability, leading to Li dendrite growth, consumption of electrolyte, and short cycle life. Here, we report a porous lithiophilic polymer coating induced by phase separation of polyvinylidenefluoride–polyacrylonitrile (PVDF–PAN) blends for stabilizing Li metal anode. Different from single polymer coating, PVDF–PAN blends protective layer with porous structures caused by phase separation can provide effective Li+ transport channels and regulate uniform Li+ flux. The lithiophilic functional groups of CN and C–F can promote uniform Li deposition and accelerate Li+ diffusion at the same time during plating/stripping process. As a result, Li||NCM811 full cells using PVDF–PAN coated Li present an apparently improved cycling stability and higher Coulombic efficiency with lean electrolyte (7.5 μL mA h–1), limited Li supply (N/P ratio = 2.4), and high areal capacity (4.0 mA h cm–2).
Solid-electrolyte interphase (SEI) plays a pivotal role in stabilizing lithium (Li) metal anode for rechargeable batteries. However, electrolyte-derived SEI often suffers from poor stability, leading to Li dendrite growth, consumption of electrolyte, and short cycle life. Here, we report a porous lithiophilic polymer coating induced by phase separation of polyvinylidenefluoride-polyacrylonitrile (PVDF-PAN) blends for stabilizing Li metal anode. Different from single polymer coating, PVDF-PAN blends protective layer with porous structures caused by phase separation can provide effective Li+ transport channels and regulate uniform Li+ flux. The lithiophilic functional groups of C≡N and C-F can promote uniform Li deposition and accelerate Li+ diffusion at the same time during plating/stripping process. As a result, Li||NCM811 full cells using PVDF-PAN coated Li present an apparently improved cycling stability and higher Coulombic efficiency with lean electrolyte (7.5 μL mA h-1), limited Li supply (N/P ratio = 2.4), and high areal capacity (4.0 mA h cm-2).Solid-electrolyte interphase (SEI) plays a pivotal role in stabilizing lithium (Li) metal anode for rechargeable batteries. However, electrolyte-derived SEI often suffers from poor stability, leading to Li dendrite growth, consumption of electrolyte, and short cycle life. Here, we report a porous lithiophilic polymer coating induced by phase separation of polyvinylidenefluoride-polyacrylonitrile (PVDF-PAN) blends for stabilizing Li metal anode. Different from single polymer coating, PVDF-PAN blends protective layer with porous structures caused by phase separation can provide effective Li+ transport channels and regulate uniform Li+ flux. The lithiophilic functional groups of C≡N and C-F can promote uniform Li deposition and accelerate Li+ diffusion at the same time during plating/stripping process. As a result, Li||NCM811 full cells using PVDF-PAN coated Li present an apparently improved cycling stability and higher Coulombic efficiency with lean electrolyte (7.5 μL mA h-1), limited Li supply (N/P ratio = 2.4), and high areal capacity (4.0 mA h cm-2).
Author Wang, Dongdong
Gu, Xiaodan
Yang, Jian
Ma, Guorong
Liu, Hongxia
Chen, Zheng
Liu, Fang
Zhou, Meng
AuthorAffiliation Sustainable Power and Energy Center
School of Polymer Science and Engineering, Center for Optoelectronic Materials and Device
Key Laboratory for Green Chemical Technology of Ministry of Education, R&D Center for Petrochemical Technology
Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering
Department of Chemical and Materials Engineering
Program of Chemical Engineering
Department of NanoEngineering
Departments of Materials Science and Engineering
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  organization: Sustainable Power and Energy Center
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solid-electrolyte interphase
phase separation
PVDF−PAN blends coating
lithium metal anodes
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Snippet Solid-electrolyte interphase (SEI) plays a pivotal role in stabilizing lithium (Li) metal anode for rechargeable batteries. However, electrolyte-derived SEI...
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Title Phase-Separation-Induced Porous Lithiophilic Polymer Coating for High-Efficiency Lithium Metal Batteries
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