Dynamic Observation of Confined Molecules in Self-Assembled Molecular Corrals

Molecular corrals self-assembled on a Si(111)-(7 × 7) surface after pyrrole exposure, enclosing silicon adatom sites where trimethylphosphine (TMP) was then datively adsorbed. The phosphine’s dynamic motion was investigated by scanning tunneling microscopy. The TMP was confined by the corral, hoppin...

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Published inJournal of physical chemistry. C Vol. 118; no. 47; pp. 27465 - 27469
Main Authors Shimomura, Masaru, Iwanabe, Ai, Kiyose, Takashi
Format Journal Article
LanguageEnglish
Published American Chemical Society 26.11.2014
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Abstract Molecular corrals self-assembled on a Si(111)-(7 × 7) surface after pyrrole exposure, enclosing silicon adatom sites where trimethylphosphine (TMP) was then datively adsorbed. The phosphine’s dynamic motion was investigated by scanning tunneling microscopy. The TMP was confined by the corral, hopping on adatom sites within it. Density functional theory calculations showed covalent bonding between the pyrroles and surface silicon atoms because of N–H dissociative adsorption. An electropositive potential around the TMP/Si cluster may induce electrostatic repulsion between the adsorbed molecules.
AbstractList Molecular corrals self-assembled on a Si(111)-(7 × 7) surface after pyrrole exposure, enclosing silicon adatom sites where trimethylphosphine (TMP) was then datively adsorbed. The phosphine’s dynamic motion was investigated by scanning tunneling microscopy. The TMP was confined by the corral, hopping on adatom sites within it. Density functional theory calculations showed covalent bonding between the pyrroles and surface silicon atoms because of N–H dissociative adsorption. An electropositive potential around the TMP/Si cluster may induce electrostatic repulsion between the adsorbed molecules.
Author Iwanabe, Ai
Shimomura, Masaru
Kiyose, Takashi
AuthorAffiliation Faculty of Engineering
Department of Electronics and Materials Science, Graduate School of Engineering
Shizuoka University
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crossref_primary_10_1016_j_apsusc_2022_156005
crossref_primary_10_1021_acsomega_3c05604
Cites_doi 10.1103/PhysRevB.65.115311
10.1016/j.susc.2004.06.090
10.1063/1.1619941
10.1103/PhysRevB.37.785
10.1021/jp105933f
10.1016/0039-6028(95)00791-1
10.1016/j.chemphys.2009.02.010
10.1021/jp030259e
10.1116/1.573160
10.1063/1.464913
10.1016/0167-2789(84)90260-4
10.1038/nature02010
10.1103/PhysRevLett.56.1972
10.1002/adma.201004291
10.3390/s120607259
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References Carter F. L. (ref1/cit1) 1984; 10
Zhang Y. P. (ref6/cit6) 2010; 114
Tsutsui M. (ref4/cit4) 2012; 12
Tao F. (ref14/cit14) 2002; 65
Peng X. (ref8/cit8) 2009; 359
Lee C. (ref12/cit12) 1988; 37
Tomimoto H. (ref15/cit15) 2004; 566
Song H. (ref3/cit3) 2011; 23
Frisch M. J. (ref11/cit11) 2010
Yuan Z. L. (ref7/cit7) 2003; 119
Shimomura M. (ref10/cit10) 1995; 341
Becke A. D. (ref13/cit13) 1993; 98
Tao F. (ref9/cit9) 2003; 107
Kubatkin S. (ref2/cit2) 2003; 425
Takayanagi K. (ref5/cit5) 1985; 3
Hamers R. J. (ref16/cit16) 1986; 56
References_xml – volume: 65
  start-page: 115311
  year: 2002
  ident: ref14/cit14
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.65.115311
  contributor:
    fullname: Tao F.
– volume: 566
  start-page: 664
  year: 2004
  ident: ref15/cit15
  publication-title: Surf. Sci.
  doi: 10.1016/j.susc.2004.06.090
  contributor:
    fullname: Tomimoto H.
– volume: 119
  start-page: 10389
  year: 2003
  ident: ref7/cit7
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.1619941
  contributor:
    fullname: Yuan Z. L.
– volume: 37
  start-page: 785
  year: 1988
  ident: ref12/cit12
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.37.785
  contributor:
    fullname: Lee C.
– volume: 114
  start-page: 16625
  year: 2010
  ident: ref6/cit6
  publication-title: J. Phys. Chem. C
  doi: 10.1021/jp105933f
  contributor:
    fullname: Zhang Y. P.
– volume: 341
  start-page: L1061
  year: 1995
  ident: ref10/cit10
  publication-title: Surf. Sci.
  doi: 10.1016/0039-6028(95)00791-1
  contributor:
    fullname: Shimomura M.
– volume: 359
  start-page: 21
  year: 2009
  ident: ref8/cit8
  publication-title: Chem. Phys.
  doi: 10.1016/j.chemphys.2009.02.010
  contributor:
    fullname: Peng X.
– volume: 107
  start-page: 6384
  year: 2003
  ident: ref9/cit9
  publication-title: J. Phys. Chem. B
  doi: 10.1021/jp030259e
  contributor:
    fullname: Tao F.
– volume: 3
  start-page: 1502
  year: 1985
  ident: ref5/cit5
  publication-title: J. Vac. Sci. Technol. A
  doi: 10.1116/1.573160
  contributor:
    fullname: Takayanagi K.
– volume-title: Gaussian 09
  year: 2010
  ident: ref11/cit11
  contributor:
    fullname: Frisch M. J.
– volume: 98
  start-page: 5648
  year: 1993
  ident: ref13/cit13
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.464913
  contributor:
    fullname: Becke A. D.
– volume: 10
  start-page: 175
  year: 1984
  ident: ref1/cit1
  publication-title: Phys. D (Amsterdam, Netherlands)
  doi: 10.1016/0167-2789(84)90260-4
  contributor:
    fullname: Carter F. L.
– volume: 425
  start-page: 698
  year: 2003
  ident: ref2/cit2
  publication-title: Nature
  doi: 10.1038/nature02010
  contributor:
    fullname: Kubatkin S.
– volume: 56
  start-page: 1972
  year: 1986
  ident: ref16/cit16
  publication-title: Phys. Rev. Lett.
  doi: 10.1103/PhysRevLett.56.1972
  contributor:
    fullname: Hamers R. J.
– volume: 23
  start-page: 1583
  year: 2011
  ident: ref3/cit3
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201004291
  contributor:
    fullname: Song H.
– volume: 12
  start-page: 7259
  year: 2012
  ident: ref4/cit4
  publication-title: Sensors
  doi: 10.3390/s120607259
  contributor:
    fullname: Tsutsui M.
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