Modulating Charges of Dual Sites in Multivariate Metal–Organic Frameworks for Boosting Selective Aerobic Epoxidation of Alkenes

• Published in: Journal of the American Chemical Society Vol. 145; no. 20; pp. 11085 - 11096
• Main Authors: Liu, Hanlin, Liu, Wei, Xue, Guangxin, Tan, Ting, Yang, Caoyu, An, Pengfei, Chen, Wenxing, Zhao, Wenshi, Fan, Ting, Cui, Chengqian, Tang, Zhiyong, Li, Guodong
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 24.05.2023

Selective aerobic epoxidation of alkenes without any additives is of great industrial importance but still challenging because the competitive side reactions including CC bond cleavage and isomerization are difficult to avoid. Here, we show fabricating Cu­(I) single sites in pristine multivariate m...