Intercalation-Induced Exfoliation and Thickness-Modulated Electronic Structure of a Layered Ternary Vanadium Oxide
Solid-state compounds wherein electrons cannot be described as noninteracting particles and instead show strongly correlated behavior are of interest both as systems manifesting novel quantum chemical phenomena as well as for electronic device applications. In the absence of predictive theoretical d...
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Published in | Chemistry of materials Vol. 29; no. 7; pp. 3285 - 3294 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
United States
American Chemical Society
11.04.2017
American Chemical Society (ACS) |
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Abstract | Solid-state compounds wherein electrons cannot be described as noninteracting particles and instead show strongly correlated behavior are of interest both as systems manifesting novel quantum chemical phenomena as well as for electronic device applications. In the absence of predictive theoretical descriptors, modulation of the properties of these compounds tends to be challenging, and generalizable strategies for modulating closely coupled lattice, orbital, and spin degrees of freedom are exceedingly sparse. Here, it is shown that exfoliation mediated by cation intercalation can serve as a powerful means of modulating the electronic structure of layered correlated materials. Using a strongly correlated and charge-ordered layered compound, δ-Sr0.50V2O5, as a model system, it is shown that the band gap can be drastically altered from ca. 1.07 to 2.32 eV and the electron correlation strength can be greatly modified by intercalation-driven exfoliation to 2D nanosheets upon elimination of structural coherence along one dimension. These findings suggest that intercalation chemistry and solution-phase exfoliation provide a versatile strategy for modulating the electronic structure of quantum materials with potential for realizing Mott and neuromorphic circuitry. |
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AbstractList | Solid-state compounds wherein electrons cannot be described as noninteracting particles and instead show strongly correlated behavior are of interest both as systems manifesting novel quantum chemical phenomena as well as for electronic device applications. In the absence of predictive theoretical descriptors, modulation of the properties of these compounds tends to be challenging, and generalizable strategies for modulating closely coupled lattice, orbital, and spin degrees of freedom are exceedingly sparse. Here, it is shown that exfoliation mediated by cation intercalation can serve as a powerful means of modulating the electronic structure of layered correlated materials. Using a strongly correlated and charge-ordered layered compound, δ-Sr0.50V2O5, as a model system, it is shown that the band gap can be drastically altered from ca. 1.07 to 2.32 eV and the electron correlation strength can be greatly modified by intercalation-driven exfoliation to 2D nanosheets upon elimination of structural coherence along one dimension. These findings suggest that intercalation chemistry and solution-phase exfoliation provide a versatile strategy for modulating the electronic structure of quantum materials with potential for realizing Mott and neuromorphic circuitry. |
Author | Moewes, Alexander Marley, Peter M Tolhurst, Thomas M De Jesus, Luis R Banerjee, Sarbajit Andrews, Justin L |
AuthorAffiliation | Department of Chemistry Department of Physics and Engineering Physics Department of Materials Science and Engineering University of Saskatchewan |
AuthorAffiliation_xml | – name: – name: Department of Chemistry – name: Department of Physics and Engineering Physics – name: University of Saskatchewan – name: Department of Materials Science and Engineering |
Author_xml | – sequence: 1 givenname: Justin L surname: Andrews fullname: Andrews, Justin L – sequence: 2 givenname: Luis R surname: De Jesus fullname: De Jesus, Luis R – sequence: 3 givenname: Thomas M surname: Tolhurst fullname: Tolhurst, Thomas M organization: University of Saskatchewan – sequence: 4 givenname: Peter M surname: Marley fullname: Marley, Peter M – sequence: 5 givenname: Alexander surname: Moewes fullname: Moewes, Alexander email: alex.moewes@usask.ca organization: University of Saskatchewan – sequence: 6 givenname: Sarbajit orcidid: 0000-0002-2028-4675 surname: Banerjee fullname: Banerjee, Sarbajit email: banerjee@chem.tamu.edu |
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Title | Intercalation-Induced Exfoliation and Thickness-Modulated Electronic Structure of a Layered Ternary Vanadium Oxide |
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