Ag–Cu Embedded SDS Nanoparticles for Efficient Removal of Toxic Organic Dyes from Water Medium
Remediation of industrial water pollution is a trending subject to date for the researchers around the globe, due to its detrimental effects on human life as well as aquatic life. Azo dyes are the largest industrial water polluters in respect of volume while anthraquinone the second largest. Therefo...
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Published in | Industrial & engineering chemistry research Vol. 62; no. 11; pp. 4765 - 4777 |
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Main Authors | , , , , , , , , , , , , , , |
Format | Journal Article |
Language | English |
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American Chemical Society
22.03.2023
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Abstract | Remediation of industrial water pollution is a trending subject to date for the researchers around the globe, due to its detrimental effects on human life as well as aquatic life. Azo dyes are the largest industrial water polluters in respect of volume while anthraquinone the second largest. Therefore, humongous considerations are being enumerated for the removal and decolorization of azo (AZ) dyestuff; however, for anthraquinone (AQ) dyes, these efforts are considerably minimal; although the later one poses a greater threat to environmental contamination, because of their reinforced structure. The current study is an effort toward this foremost issue. Chemical reduction synthesis of silver–copper (Ag–Cu) bimetallic nanoparticles (BNPs) was achieved using NaBH4 as a reducing agent and sodium dodecyl sulfate (SDS) as a stabilizer. Characterization and morphological evaluation indicates two distinctive UV/vis absorption peaks for Ag and Cu. XRD studies for nanocomposite showed crystallite size of 8.96014 nm having an FCC structure. SEM with EDX confirmed the particle sizes of BNPs and SDS to be 17.14 and 114.56 nm, respectively. Potential catalytic activity and kinetic parameters of Ag–Cu BNPs@SDS were monitored against Methylene Blue (MB), Methyl Orange (MO), and eosin-y (EY). The percentage degradation recorded for the nanocatalyst against MO, MB, and EY was 95.21%, 98.57%, and 96.65%, respectively. This method can be adopted for the removal of multiple dyes from industrial effluent on a larger scale. |
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AbstractList | Remediation of industrial water pollution is a trending subject to date for the researchers around the globe, due to its detrimental effects on human life as well as aquatic life. Azo dyes are the largest industrial water polluters in respect of volume while anthraquinone the second largest. Therefore, humongous considerations are being enumerated for the removal and decolorization of azo (AZ) dyestuff; however, for anthraquinone (AQ) dyes, these efforts are considerably minimal; although the later one poses a greater threat to environmental contamination, because of their reinforced structure. The current study is an effort toward this foremost issue. Chemical reduction synthesis of silver–copper (Ag–Cu) bimetallic nanoparticles (BNPs) was achieved using NaBH4 as a reducing agent and sodium dodecyl sulfate (SDS) as a stabilizer. Characterization and morphological evaluation indicates two distinctive UV/vis absorption peaks for Ag and Cu. XRD studies for nanocomposite showed crystallite size of 8.96014 nm having an FCC structure. SEM with EDX confirmed the particle sizes of BNPs and SDS to be 17.14 and 114.56 nm, respectively. Potential catalytic activity and kinetic parameters of Ag–Cu BNPs@SDS were monitored against Methylene Blue (MB), Methyl Orange (MO), and eosin-y (EY). The percentage degradation recorded for the nanocatalyst against MO, MB, and EY was 95.21%, 98.57%, and 96.65%, respectively. This method can be adopted for the removal of multiple dyes from industrial effluent on a larger scale. |
Author | Habila, Mohamed A. Show, Pau Loke Ashraf, Adnan Chuah, Lai Fatt Bhatti, Muhammad Pervaiz Mubashir, Muhammad Aljuwayid, Ahmed Muteb Saleem, Aimon Eldesoky, Gaber E. Chong, Jun Wei Roy Ali, Faisal Mehmood, Saira Younas, Umer Bokhari, Awais Ahmad, Awais |
AuthorAffiliation | Zhejiang Provincial Key Laboratory for Subtropical Water Environment and Marine Biological Resources Protection Department of Chemical and Environmental Engineering, Faculty of Science and Engineering SIMATS Department of Chemistry, College of Science Department of Petroleum Engineering, School of Engineering Faculty of Maritime Studies Department of Chemistry Department of Sustainable Engineering, Saveetha School of Engineering Khalifa University Universiti Malaysia Terengganu Departamento de Quimica Organica Department of Chemical Engineering Wenzhou University |
AuthorAffiliation_xml | – name: Department of Chemical Engineering – name: Faculty of Maritime Studies – name: Khalifa University – name: Department of Chemistry – name: Department of Petroleum Engineering, School of Engineering – name: Wenzhou University – name: Department of Chemical and Environmental Engineering, Faculty of Science and Engineering – name: Department of Chemistry, College of Science – name: Zhejiang Provincial Key Laboratory for Subtropical Water Environment and Marine Biological Resources Protection – name: Department of Sustainable Engineering, Saveetha School of Engineering – name: SIMATS – name: Departamento de Quimica Organica – name: Universiti Malaysia Terengganu |
Author_xml | – sequence: 1 givenname: Faisal surname: Ali fullname: Ali, Faisal organization: Department of Chemistry – sequence: 2 givenname: Saira surname: Mehmood fullname: Mehmood, Saira organization: Department of Chemistry – sequence: 3 givenname: Adnan surname: Ashraf fullname: Ashraf, Adnan organization: Department of Chemistry – sequence: 4 givenname: Aimon surname: Saleem fullname: Saleem, Aimon organization: Department of Chemistry – sequence: 5 givenname: Umer surname: Younas fullname: Younas, Umer email: umer.younas@chem.uol.edu.pk organization: Department of Chemistry – sequence: 6 givenname: Awais surname: Ahmad fullname: Ahmad, Awais email: fawaisahmed@gcuf.edu.pk organization: Departamento de Quimica Organica – sequence: 7 givenname: Muhammad Pervaiz surname: Bhatti fullname: Bhatti, Muhammad Pervaiz email: mpbhatti786@gmail.com organization: Department of Chemistry – sequence: 8 givenname: Gaber E. surname: Eldesoky fullname: Eldesoky, Gaber E. organization: Department of Chemistry, College of Science – sequence: 9 givenname: Ahmed Muteb surname: Aljuwayid fullname: Aljuwayid, Ahmed Muteb organization: Department of Chemistry, College of Science – sequence: 10 givenname: Mohamed A. orcidid: 0000-0003-1910-0311 surname: Habila fullname: Habila, Mohamed A. organization: Department of Chemistry, College of Science – sequence: 11 givenname: Awais surname: Bokhari fullname: Bokhari, Awais organization: Department of Chemical Engineering – sequence: 12 givenname: Muhammad surname: Mubashir fullname: Mubashir, Muhammad organization: Department of Petroleum Engineering, School of Engineering – sequence: 13 givenname: Lai Fatt surname: Chuah fullname: Chuah, Lai Fatt organization: Universiti Malaysia Terengganu – sequence: 14 givenname: Jun Wei Roy surname: Chong fullname: Chong, Jun Wei Roy organization: Department of Chemical and Environmental Engineering, Faculty of Science and Engineering – sequence: 15 givenname: Pau Loke orcidid: 0000-0002-0913-5409 surname: Show fullname: Show, Pau Loke email: pauLoke.Show@nottingham.edu.my, showpauloke@gmail.com organization: Khalifa University |
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Title | Ag–Cu Embedded SDS Nanoparticles for Efficient Removal of Toxic Organic Dyes from Water Medium |
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