Rhenium Dihydrogen Complexes with Isonitrile Coligands:  Novel Displacement of Chloride by Hydrogen

• Published in: Journal of the American Chemical Society Vol. 118; no. 44; pp. 10792 - 10802
• Main Authors: Heinekey, D. M, Voges, Mark H, Barnhart, David M
• Format: Journal Article
• Language: English
• Published: WASHINGTON American Chemical Society 06.11.1996; Amer Chemical Soc
• Subjects: Chemistry; Chemistry, Multidisciplinary; Physical Sciences; Science & Technology; H BOND ACTIVATION; INELASTIC-NEUTRON-SCATTERING; ISOCYANIDE COMPLEXES; ELECTRONIC CONTROL; RAY CRYSTAL-STRUCTURES; DPPE = PH2PCH2CH2PPH2; OXIDATIVE ADDITION; TRANSITION-METALS; DIHYDRIDE COORDINATION; POLYHYDRIDE COMPLEXES

The syntheses, properties, and characterization of several new complexes, Re(CNtBu)3(PCy3)2H (1a), Re(CNtBu)3(PR3)2Cl [R = Cy, Ph (2a, 2b)], the 17-electron [Re(CNtBu)3(PCy3)2Cl]+ (3a), the dihydrogen complex, [Re(CNtBu)3(PR3)2(H2)]+ [R = Cy, Ph (4a, 4b)], the coordinatively unsaturated [Re(CNtBu)3(...