Light Fe isotopes in arc magmas from cold subduction zones: Implications for serpentinite-derived fluids oxidized the sub-arc mantle

Arc basalts typically have higher Fe3+/ΣFe ratios but lighter Fe isotopic compositions than mid-ocean ridge basalts (MORB); however, the reasons for these differences are unclear. Here, we report new Fe isotope data for fresh lavas from the Mariana subduction zone, along with available Fe-B-Sr-Nd is...

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Published inGeochimica et cosmochimica acta Vol. 342; pp. 1 - 14
Main Authors Chen, Zuxing, Chen, Jiubin, Tamehe, Landry Soh, Zhang, Yuxiang, Zeng, Zhigang, Zhang, Ting, Shuai, Wangcai, Yin, Xuebo
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.02.2023
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Abstract Arc basalts typically have higher Fe3+/ΣFe ratios but lighter Fe isotopic compositions than mid-ocean ridge basalts (MORB); however, the reasons for these differences are unclear. Here, we report new Fe isotope data for fresh lavas from the Mariana subduction zone, along with available Fe-B-Sr-Nd isotope and B/Nb ratio data for global arc basalts, to constrain the role of serpentinite dehydration in sub-arc mantle oxidation. The basaltic lavas from the Mariana Arc, like other arc basalts from cold subduction zones in the west Pacific, have lighter Fe isotope compositions (δ56Fe = 0.02 ± 0.02‰; 1SD; n = 9) than the MORB-like δ56Fe values of the middle Mariana Trough basalts (δ56Fe = 0.09 ± 0.02‰; 1SD; n = 8). Notably, the significant negative correlations between the δ56Fe values and the proxy for the addition of serpentinite-derived fluids (i.e., B isotopes and B/Nb ratios) indicate that the serpentinite-derived fluid contribution is a first-order control on the across-arc Fe isotope variations. Dehydration of subducted slab serpentinites or dragged-down forearc serpentinites at sub-arc depths can release isotopically light Fe fluids in the form of Fe2+–SOx complexes. Sulfate-rich fluids containing adequate Fe to metasomatize the sub-arc mantle can cause light Fe isotope compositions and high Fe3+/ΣFe ratios in arc basalts. Alternatively, the low δ56Fe values and high Fe3+/ΣFe ratios of arc magmas may be generated by direct melting of the mélange, which includes dragged-down sulfate-rich forearc serpentinites. Comparatively, serpentinite-derived components are absent at back-arc depths because of the earlier breakdown of serpentine minerals. Accordingly, the back-arc basin basalts exhibit MORB-like δ56Fe-δ11B values and B/Nb–Fe3+/ΣFe ratios. Therefore, the across-arc Fe isotope variations and the decoupling of Fe3+/ΣFe and δ56Fe in global arc magmas can be explained by the different contributions of subducted serpentinites.
AbstractList Arc basalts typically have higher Fe3+/ΣFe ratios but lighter Fe isotopic compositions than mid-ocean ridge basalts (MORB); however, the reasons for these differences are unclear. Here, we report new Fe isotope data for fresh lavas from the Mariana subduction zone, along with available Fe-B-Sr-Nd isotope and B/Nb ratio data for global arc basalts, to constrain the role of serpentinite dehydration in sub-arc mantle oxidation. The basaltic lavas from the Mariana Arc, like other arc basalts from cold subduction zones in the west Pacific, have lighter Fe isotope compositions (δ56Fe = 0.02 ± 0.02‰; 1SD; n = 9) than the MORB-like δ56Fe values of the middle Mariana Trough basalts (δ56Fe = 0.09 ± 0.02‰; 1SD; n = 8). Notably, the significant negative correlations between the δ56Fe values and the proxy for the addition of serpentinite-derived fluids (i.e., B isotopes and B/Nb ratios) indicate that the serpentinite-derived fluid contribution is a first-order control on the across-arc Fe isotope variations. Dehydration of subducted slab serpentinites or dragged-down forearc serpentinites at sub-arc depths can release isotopically light Fe fluids in the form of Fe2+–SOx complexes. Sulfate-rich fluids containing adequate Fe to metasomatize the sub-arc mantle can cause light Fe isotope compositions and high Fe3+/ΣFe ratios in arc basalts. Alternatively, the low δ56Fe values and high Fe3+/ΣFe ratios of arc magmas may be generated by direct melting of the mélange, which includes dragged-down sulfate-rich forearc serpentinites. Comparatively, serpentinite-derived components are absent at back-arc depths because of the earlier breakdown of serpentine minerals. Accordingly, the back-arc basin basalts exhibit MORB-like δ56Fe-δ11B values and B/Nb–Fe3+/ΣFe ratios. Therefore, the across-arc Fe isotope variations and the decoupling of Fe3+/ΣFe and δ56Fe in global arc magmas can be explained by the different contributions of subducted serpentinites.
Author Zhang, Ting
Yin, Xuebo
Zhang, Yuxiang
Chen, Zuxing
Zeng, Zhigang
Shuai, Wangcai
Chen, Jiubin
Tamehe, Landry Soh
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  organization: Key Laboratory of Marine Geology and Environment, Institute of Oceanology, Chinese Academy of Sciences, Qingdao, Shandong 266071, China
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Keywords Oxygen fugacity
Arc magmas
Cold subduction zones
Serpentinite dehydration
Fe isotopes
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Snippet Arc basalts typically have higher Fe3+/ΣFe ratios but lighter Fe isotopic compositions than mid-ocean ridge basalts (MORB); however, the reasons for these...
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SubjectTerms Arc magmas
Cold subduction zones
Fe isotopes
Oxygen fugacity
Serpentinite dehydration
Title Light Fe isotopes in arc magmas from cold subduction zones: Implications for serpentinite-derived fluids oxidized the sub-arc mantle
URI https://dx.doi.org/10.1016/j.gca.2022.12.005
Volume 342
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