Light Fe isotopes in arc magmas from cold subduction zones: Implications for serpentinite-derived fluids oxidized the sub-arc mantle
Arc basalts typically have higher Fe3+/ΣFe ratios but lighter Fe isotopic compositions than mid-ocean ridge basalts (MORB); however, the reasons for these differences are unclear. Here, we report new Fe isotope data for fresh lavas from the Mariana subduction zone, along with available Fe-B-Sr-Nd is...
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Published in | Geochimica et cosmochimica acta Vol. 342; pp. 1 - 14 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier Ltd
01.02.2023
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Abstract | Arc basalts typically have higher Fe3+/ΣFe ratios but lighter Fe isotopic compositions than mid-ocean ridge basalts (MORB); however, the reasons for these differences are unclear. Here, we report new Fe isotope data for fresh lavas from the Mariana subduction zone, along with available Fe-B-Sr-Nd isotope and B/Nb ratio data for global arc basalts, to constrain the role of serpentinite dehydration in sub-arc mantle oxidation. The basaltic lavas from the Mariana Arc, like other arc basalts from cold subduction zones in the west Pacific, have lighter Fe isotope compositions (δ56Fe = 0.02 ± 0.02‰; 1SD; n = 9) than the MORB-like δ56Fe values of the middle Mariana Trough basalts (δ56Fe = 0.09 ± 0.02‰; 1SD; n = 8). Notably, the significant negative correlations between the δ56Fe values and the proxy for the addition of serpentinite-derived fluids (i.e., B isotopes and B/Nb ratios) indicate that the serpentinite-derived fluid contribution is a first-order control on the across-arc Fe isotope variations. Dehydration of subducted slab serpentinites or dragged-down forearc serpentinites at sub-arc depths can release isotopically light Fe fluids in the form of Fe2+–SOx complexes. Sulfate-rich fluids containing adequate Fe to metasomatize the sub-arc mantle can cause light Fe isotope compositions and high Fe3+/ΣFe ratios in arc basalts. Alternatively, the low δ56Fe values and high Fe3+/ΣFe ratios of arc magmas may be generated by direct melting of the mélange, which includes dragged-down sulfate-rich forearc serpentinites. Comparatively, serpentinite-derived components are absent at back-arc depths because of the earlier breakdown of serpentine minerals. Accordingly, the back-arc basin basalts exhibit MORB-like δ56Fe-δ11B values and B/Nb–Fe3+/ΣFe ratios. Therefore, the across-arc Fe isotope variations and the decoupling of Fe3+/ΣFe and δ56Fe in global arc magmas can be explained by the different contributions of subducted serpentinites. |
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AbstractList | Arc basalts typically have higher Fe3+/ΣFe ratios but lighter Fe isotopic compositions than mid-ocean ridge basalts (MORB); however, the reasons for these differences are unclear. Here, we report new Fe isotope data for fresh lavas from the Mariana subduction zone, along with available Fe-B-Sr-Nd isotope and B/Nb ratio data for global arc basalts, to constrain the role of serpentinite dehydration in sub-arc mantle oxidation. The basaltic lavas from the Mariana Arc, like other arc basalts from cold subduction zones in the west Pacific, have lighter Fe isotope compositions (δ56Fe = 0.02 ± 0.02‰; 1SD; n = 9) than the MORB-like δ56Fe values of the middle Mariana Trough basalts (δ56Fe = 0.09 ± 0.02‰; 1SD; n = 8). Notably, the significant negative correlations between the δ56Fe values and the proxy for the addition of serpentinite-derived fluids (i.e., B isotopes and B/Nb ratios) indicate that the serpentinite-derived fluid contribution is a first-order control on the across-arc Fe isotope variations. Dehydration of subducted slab serpentinites or dragged-down forearc serpentinites at sub-arc depths can release isotopically light Fe fluids in the form of Fe2+–SOx complexes. Sulfate-rich fluids containing adequate Fe to metasomatize the sub-arc mantle can cause light Fe isotope compositions and high Fe3+/ΣFe ratios in arc basalts. Alternatively, the low δ56Fe values and high Fe3+/ΣFe ratios of arc magmas may be generated by direct melting of the mélange, which includes dragged-down sulfate-rich forearc serpentinites. Comparatively, serpentinite-derived components are absent at back-arc depths because of the earlier breakdown of serpentine minerals. Accordingly, the back-arc basin basalts exhibit MORB-like δ56Fe-δ11B values and B/Nb–Fe3+/ΣFe ratios. Therefore, the across-arc Fe isotope variations and the decoupling of Fe3+/ΣFe and δ56Fe in global arc magmas can be explained by the different contributions of subducted serpentinites. |
Author | Zhang, Ting Yin, Xuebo Zhang, Yuxiang Chen, Zuxing Zeng, Zhigang Shuai, Wangcai Chen, Jiubin Tamehe, Landry Soh |
Author_xml | – sequence: 1 givenname: Zuxing surname: Chen fullname: Chen, Zuxing email: chenzuxing@qdio.ac.cn organization: Key Laboratory of Marine Geology and Environment, Institute of Oceanology, Chinese Academy of Sciences, Qingdao, Shandong 266071, China – sequence: 2 givenname: Jiubin surname: Chen fullname: Chen, Jiubin organization: Institute of Surface-Earth System Science, Tianjin University, 300072, China – sequence: 3 givenname: Landry Soh surname: Tamehe fullname: Tamehe, Landry Soh organization: China Nonferrous Metals (Guilin) Geology and Mining Co. Ltd, Guilin 541004, China – sequence: 4 givenname: Yuxiang surname: Zhang fullname: Zhang, Yuxiang organization: Key Laboratory of Marine Geology and Environment, Institute of Oceanology, Chinese Academy of Sciences, Qingdao, Shandong 266071, China – sequence: 5 givenname: Zhigang surname: Zeng fullname: Zeng, Zhigang organization: Key Laboratory of Marine Geology and Environment, Institute of Oceanology, Chinese Academy of Sciences, Qingdao, Shandong 266071, China – sequence: 6 givenname: Ting surname: Zhang fullname: Zhang, Ting organization: Institute of Surface-Earth System Science, Tianjin University, 300072, China – sequence: 7 givenname: Wangcai surname: Shuai fullname: Shuai, Wangcai organization: Institute of Surface-Earth System Science, Tianjin University, 300072, China – sequence: 8 givenname: Xuebo surname: Yin fullname: Yin, Xuebo organization: Key Laboratory of Marine Geology and Environment, Institute of Oceanology, Chinese Academy of Sciences, Qingdao, Shandong 266071, China |
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Snippet | Arc basalts typically have higher Fe3+/ΣFe ratios but lighter Fe isotopic compositions than mid-ocean ridge basalts (MORB); however, the reasons for these... |
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SubjectTerms | Arc magmas Cold subduction zones Fe isotopes Oxygen fugacity Serpentinite dehydration |
Title | Light Fe isotopes in arc magmas from cold subduction zones: Implications for serpentinite-derived fluids oxidized the sub-arc mantle |
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