Self-Assembly of Chiral Menthol Molecules from a Liquid Film into Ring-Banded Spherulites
We investigate the growth of spherulites in the wake of a solidification front in a thin film of liquid menthol. We observed that the two enantiomeric forms of menthol ((−)-menthol and (+)-menthol)) form ring-banded spherulites, in which needle-like crystals self-assemble into high- and low-density...
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| Published in | Crystal growth & design Vol. 19; no. 7; pp. 4063 - 4069 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
American Chemical Society
03.07.2019
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| Online Access | Get full text |
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| Abstract | We investigate the growth of spherulites in the wake of a solidification front in a thin film of liquid menthol. We observed that the two enantiomeric forms of menthol ((−)-menthol and (+)-menthol)) form ring-banded spherulites, in which needle-like crystals self-assemble into high- and low-density crystal regions. Interestingly, the racemic mixture produces nonbanded spherulites consisting of closely packed plate-like crystals. In the ring-banded spherulitic growth, we could clearly identify the curvature effect of the solidification front on the pattern formation on a millimeter spatial scale. We developed a numerical model based on the Cahn–Hilliard equation, which qualitatively describes the main features observed in experiments, namely, the formation of periodic ring-banded structures and the curvature effect of the propagating solidification front. |
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| AbstractList | We investigate the growth of spherulites in the wake of a solidification front in a thin film of liquid menthol. We observed that the two enantiomeric forms of menthol ((−)-menthol and (+)-menthol)) form ring-banded spherulites, in which needle-like crystals self-assemble into high- and low-density crystal regions. Interestingly, the racemic mixture produces nonbanded spherulites consisting of closely packed plate-like crystals. In the ring-banded spherulitic growth, we could clearly identify the curvature effect of the solidification front on the pattern formation on a millimeter spatial scale. We developed a numerical model based on the Cahn–Hilliard equation, which qualitatively describes the main features observed in experiments, namely, the formation of periodic ring-banded structures and the curvature effect of the propagating solidification front. |
| Author | Zuba, Zita Christenson, Hugo K Molnár, János Lagzi, István Szűcs, Rózsa Holló, Gábor Kovács, Tamás |
| AuthorAffiliation | MTA-BME Condensed Matter Research Group Eötvös Loránd University Department of Physical Chemistry and Materials Science School of Physics and Astronomy Budapest University of Technology and Economics MTA-BME Computer Driven Chemistry Laboratory for Chemical Kinetics Department of Physics |
| AuthorAffiliation_xml | – name: School of Physics and Astronomy – name: Eötvös Loránd University – name: MTA-BME Computer Driven Chemistry – name: Department of Physics – name: Budapest University of Technology and Economics – name: MTA-BME Condensed Matter Research Group – name: Laboratory for Chemical Kinetics – name: Department of Physical Chemistry and Materials Science |
| Author_xml | – sequence: 1 givenname: Tamás surname: Kovács fullname: Kovács, Tamás organization: Eötvös Loránd University – sequence: 2 givenname: Rózsa surname: Szűcs fullname: Szűcs, Rózsa organization: Budapest University of Technology and Economics – sequence: 3 givenname: Gábor surname: Holló fullname: Holló, Gábor organization: Budapest University of Technology and Economics – sequence: 4 givenname: Zita surname: Zuba fullname: Zuba, Zita organization: Budapest University of Technology and Economics – sequence: 5 givenname: János surname: Molnár fullname: Molnár, János organization: Budapest University of Technology and Economics – sequence: 6 givenname: Hugo K orcidid: 0000-0002-7648-959X surname: Christenson fullname: Christenson, Hugo K organization: School of Physics and Astronomy – sequence: 7 givenname: István orcidid: 0000-0002-2303-5965 surname: Lagzi fullname: Lagzi, István email: istvanlagzi@gmail.com organization: Budapest University of Technology and Economics |
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| Title | Self-Assembly of Chiral Menthol Molecules from a Liquid Film into Ring-Banded Spherulites |
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