Pillar[6]arene-Based Photoresponsive Host–Guest Complexation
The trans form of an azobenzene-containing guest can complex with a pillar[6]arene, while it cannot complex with pillar[5]arenes due to the different cavity sizes of the pillar[6]arene and the pillar[5]arenes. The spontaneous aggregation of its host–guest complex with the pillar[6]arene can be rever...
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| Published in | Journal of the American Chemical Society Vol. 134; no. 20; pp. 8711 - 8717 |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
WASHINGTON
American Chemical Society
23.05.2012
Amer Chemical Soc |
| Subjects | |
| Online Access | Get full text |
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| Abstract | The trans form of an azobenzene-containing guest can complex with a pillar[6]arene, while it cannot complex with pillar[5]arenes due to the different cavity sizes of the pillar[6]arene and the pillar[5]arenes. The spontaneous aggregation of its host–guest complex with the pillar[6]arene can be reversibly photocontrolled by irradiation with UV and visible light, leading to a switch between irregular aggregates and vesicle-like aggregates. This new pillar[6]arene-based photoresponsive host–guest recognition motif can work in organic solvents and is a good supplement to the existing widely used cyclodextrin/azobenzene recognition motif. |
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| AbstractList | The trans form of an azobenzene-containing guest can complex with a pillar[6]arene, while it cannot complex with pillar[5]arenes due to the different cavity sizes of the pillar[6]arene and the pillar[5]arenes. The spontaneous aggregation of its host–guest complex with the pillar[6]arene can be reversibly photocontrolled by irradiation with UV and visible light, leading to a switch between irregular aggregates and vesicle-like aggregates. This new pillar[6]arene-based photoresponsive host–guest recognition motif can work in organic solvents and is a good supplement to the existing widely used cyclodextrin/azobenzene recognition motif. The trans form of an azobenzene-containing guest can complex with a pillar[6]arene, while it cannot complex with pillar[S]arenes due to the different cavity sizes of the pillar[6]arene and the pillar[S]arenes. The spontaneous aggregation of its host guest complex with the pillar[6]arene can be reversibly photocontrolled by irradiation with UV and visible light, leading to a switch between irregular aggregates and vesicle-like aggregates. This new pillar[6]arene-based photoresponsive host guest recognition motif can work in organic solvents and is a good supplement to the existing widely used cyclodextrin/azobenzene recognition motif. |
| Author | Zheng, Bo Han, Chengyou Chen, Jianzhuang Yan, Xuzhou Liu, Shiyong Yu, Guocan Zhang, Zibin Huang, Feihe |
| AuthorAffiliation | University of Science and Technology of China Zhejiang University |
| AuthorAffiliation_xml | – name: University of Science and Technology of China – name: Zhejiang University |
| Author_xml | – sequence: 1 givenname: Guocan surname: Yu fullname: Yu, Guocan – sequence: 2 givenname: Chengyou surname: Han fullname: Han, Chengyou – sequence: 3 givenname: Zibin surname: Zhang fullname: Zhang, Zibin – sequence: 4 givenname: Jianzhuang surname: Chen fullname: Chen, Jianzhuang – sequence: 5 givenname: Xuzhou surname: Yan fullname: Yan, Xuzhou – sequence: 6 givenname: Bo surname: Zheng fullname: Zheng, Bo – sequence: 7 givenname: Shiyong surname: Liu fullname: Liu, Shiyong email: sliu@ustc.edu.cn, fhuang@zju.edu.cn – sequence: 8 givenname: Feihe surname: Huang fullname: Huang, Feihe email: sliu@ustc.edu.cn, fhuang@zju.edu.cn |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/22540829$$D View this record in MEDLINE/PubMed |
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| Snippet | The trans form of an azobenzene-containing guest can complex with a pillar[6]arene, while it cannot complex with pillar[5]arenes due to the different cavity... The trans form of an azobenzene-containing guest can complex with a pillar[6]arene, while it cannot complex with pillar[S]arenes due to the different cavity... |
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| SubjectTerms | aromatic hydrocarbons Azo Compounds - chemical synthesis Azo Compounds - chemistry Calixarenes - chemical synthesis Calixarenes - chemistry Chemistry Chemistry, Multidisciplinary Crystallography, X-Ray cyclodextrins irradiation Light Magnetic Resonance Spectroscopy Models, Molecular Phenols - chemical synthesis Phenols - chemistry Photochemical Processes Physical Sciences Science & Technology solvents Stereoisomerism |
| Title | Pillar[6]arene-Based Photoresponsive Host–Guest Complexation |
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