The Trivalent Copper Complex of a Conjugated Bis-dithiocarbazate Schiff Base: Stabilization of Cu in Three Different Oxidation States
The new tribasic N2S2 ligand H3ttfasbz has been synthesized by condensation of 4-thenoyl 2,2,2-trifluoroacetone and S-benzyl dithiocarbazate. On complexation with copper(II) acetate, spontaneous oxidation to the CuIII oxidation state is observed, and the complex [Cu(ttfasbz)] has been isolated and c...
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| Published in | Inorganic chemistry Vol. 52; no. 3; pp. 1650 - 1657 |
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| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
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United States
American Chemical Society
04.02.2013
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| Abstract | The new tribasic N2S2 ligand H3ttfasbz has been synthesized by condensation of 4-thenoyl 2,2,2-trifluoroacetone and S-benzyl dithiocarbazate. On complexation with copper(II) acetate, spontaneous oxidation to the CuIII oxidation state is observed, and the complex [Cu(ttfasbz)] has been isolated and characterized structurally. Reduction to the EPR active CuII analogue has been achieved chemically and also electrochemically, and in both cases, the process is totally reversible. The CuIII/II redox potential of the complex is remarkably low and similar to that of the ferrocenium/ferrocene couple. Further reduction to the formally monovalent (d 10) dianion [CuI(ttfasbz)]2– may be achieved electrochemically. Computational chemistry demonstrates that the three redox states [Cu(ttfasbz)], [Cu(ttfasbz)]−, and [Cu(ttfasbz)]2– are truly CuIII, CuII, and CuI complexes, respectively, and the potentially noninnocent ligand does not undergo any redox reactions. |
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| AbstractList | The new tribasic N(2)S(2) ligand H(3)ttfasbz has been synthesized by condensation of 4-thenoyl 2,2,2-trifluoroacetone and S-benzyl dithiocarbazate. On complexation with copper(II) acetate, spontaneous oxidation to the Cu(III) oxidation state is observed, and the complex [Cu(ttfasbz)] has been isolated and characterized structurally. Reduction to the EPR active Cu(II) analogue has been achieved chemically and also electrochemically, and in both cases, the process is totally reversible. The Cu(III/II) redox potential of the complex is remarkably low and similar to that of the ferrocenium/ferrocene couple. Further reduction to the formally monovalent (d(10)) dianion [Cu(I)(ttfasbz)](2-) may be achieved electrochemically. Computational chemistry demonstrates that the three redox states [Cu(ttfasbz)], [Cu(ttfasbz)](-), and [Cu(ttfasbz)](2-) are truly Cu(III), Cu(II), and Cu(I) complexes, respectively, and the potentially noninnocent ligand does not undergo any redox reactions.The new tribasic N(2)S(2) ligand H(3)ttfasbz has been synthesized by condensation of 4-thenoyl 2,2,2-trifluoroacetone and S-benzyl dithiocarbazate. On complexation with copper(II) acetate, spontaneous oxidation to the Cu(III) oxidation state is observed, and the complex [Cu(ttfasbz)] has been isolated and characterized structurally. Reduction to the EPR active Cu(II) analogue has been achieved chemically and also electrochemically, and in both cases, the process is totally reversible. The Cu(III/II) redox potential of the complex is remarkably low and similar to that of the ferrocenium/ferrocene couple. Further reduction to the formally monovalent (d(10)) dianion [Cu(I)(ttfasbz)](2-) may be achieved electrochemically. Computational chemistry demonstrates that the three redox states [Cu(ttfasbz)], [Cu(ttfasbz)](-), and [Cu(ttfasbz)](2-) are truly Cu(III), Cu(II), and Cu(I) complexes, respectively, and the potentially noninnocent ligand does not undergo any redox reactions. The new tribasic N(2)S(2) ligand H(3)ttfasbz has been synthesized by condensation of 4-thenoyl 2,2,2-trifluoroacetone and S-benzyl dithiocarbazate. On complexation with copper(II) acetate, spontaneous oxidation to the Cu(III) oxidation state is observed, and the complex [Cu(ttfasbz)] has been isolated and characterized structurally. Reduction to the EPR active Cu(II) analogue has been achieved chemically and also electrochemically, and in both cases, the process is totally reversible. The Cu(III/II) redox potential of the complex is remarkably low and similar to that of the ferrocenium/ferrocene couple. Further reduction to the formally monovalent (d(10)) dianion [Cu(I)(ttfasbz)](2-) may be achieved electrochemically. Computational chemistry demonstrates that the three redox states [Cu(ttfasbz)], [Cu(ttfasbz)](-), and [Cu(ttfasbz)](2-) are truly Cu(III), Cu(II), and Cu(I) complexes, respectively, and the potentially noninnocent ligand does not undergo any redox reactions. The new tribasic N2S2 ligand H3ttfasbz has been synthesized by condensation of 4-thenoyl 2,2,2-trifluoroacetone and S-benzyl dithiocarbazate. On complexation with copper(II) acetate, spontaneous oxidation to the CuIII oxidation state is observed, and the complex [Cu(ttfasbz)] has been isolated and characterized structurally. Reduction to the EPR active CuII analogue has been achieved chemically and also electrochemically, and in both cases, the process is totally reversible. The CuIII/II redox potential of the complex is remarkably low and similar to that of the ferrocenium/ferrocene couple. Further reduction to the formally monovalent (d 10) dianion [CuI(ttfasbz)]2– may be achieved electrochemically. Computational chemistry demonstrates that the three redox states [Cu(ttfasbz)], [Cu(ttfasbz)]−, and [Cu(ttfasbz)]2– are truly CuIII, CuII, and CuI complexes, respectively, and the potentially noninnocent ligand does not undergo any redox reactions. |
| Author | Akbar Ali, Mohammad Brax, Mathilde A. H Wieghardt, Karl Bernhardt, Paul V England, Jason Hanson, Graeme R Yeng, Lee Len Farlow, Anthony J Mirza, Aminul Huq |
| AuthorAffiliation | The University of Queensland Universiti Brunei Darussalam Max Planck Institute for Chemical Energy Conversion |
| AuthorAffiliation_xml | – name: Universiti Brunei Darussalam – name: Max Planck Institute for Chemical Energy Conversion – name: The University of Queensland |
| Author_xml | – sequence: 1 givenname: Mohammad surname: Akbar Ali fullname: Akbar Ali, Mohammad – sequence: 2 givenname: Paul V surname: Bernhardt fullname: Bernhardt, Paul V email: p.bernhardt@uq.edu.au – sequence: 3 givenname: Mathilde A. H surname: Brax fullname: Brax, Mathilde A. H – sequence: 4 givenname: Jason surname: England fullname: England, Jason – sequence: 5 givenname: Anthony J surname: Farlow fullname: Farlow, Anthony J – sequence: 6 givenname: Graeme R surname: Hanson fullname: Hanson, Graeme R – sequence: 7 givenname: Lee Len surname: Yeng fullname: Yeng, Lee Len – sequence: 8 givenname: Aminul Huq surname: Mirza fullname: Mirza, Aminul Huq – sequence: 9 givenname: Karl surname: Wieghardt fullname: Wieghardt, Karl |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/23324063$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1016/j.jpcs.2003.11.015 10.1063/1.1726658 10.1107/S0108767307043930 10.1103/PhysRevB.37.785 10.1016/j.cbpa.2007.02.026 10.1016/j.poly.2007.09.030 10.1080/00958970902855614 10.1063/1.440548 10.1021/ic034080u 10.1002/jcc.20495 10.1016/j.jinorgbio.2004.02.003 10.1021/ic702440e 10.1016/0010-8545(95)07011-L 10.1080/00958970701266724 10.1021/ja0356075 10.1002/anie.199703571 10.1002/ejic.200500363 10.1039/C39930000726 10.1021/ic701411y 10.1021/ic00078a037 10.1021/ic00041a019 10.1070/RC2005v074n06ABEH000977 10.1039/f19868202833 10.1021/ic00149a004 10.1021/ic202764j 10.1063/1.1726440 10.1063/1.1726439 10.1039/P29930000799 10.1007/s11243-011-9492-0 10.1146/annurev.bb.11.060182.002135 10.1016/S0277-5387(98)00063-1 10.1039/a706964b 10.1016/S0020-1693(00)84357-1 10.1039/c39820001111 10.1021/ic9608713 10.1016/0009-2614(95)00621-A 10.1002/anie.199628271 10.1021/ja00449a028 10.1002/jcc.20084 10.1039/b508541a 10.1007/s002140050244 10.1016/j.chemphys.2008.10.036 10.1002/(SICI)1521-3773(19990201)38:3<359::AID-ANIE359>3.0.CO;2-5 10.1063/1.450025 10.1016/0022-1902(77)80202-9 10.1107/S0021889897003117 10.1007/BF01035826 10.1002/anie.199316351 10.1039/b406429a 10.1063/1.1731340 10.1039/b916682c 10.1016/j.cplett.2009.09.073 10.1063/1.464913 10.1021/ic2003832 |
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| References | Akbar Ali M. (ref48/cit48) 2011; 36 Weigend F. (ref34/cit34) 2005; 7 Brown S. N. (ref17/cit17) 2012; 51 Oliver K. J. (ref10/cit10) 1982 Neese F. (ref30/cit30) 2010 Du Preez J. G. H. (ref46/cit46) 1987; 133 Gerbeleu N. V. (ref18/cit18) 1992; 31 Wilson R. (ref24/cit24) 1966; 44 Calatayud D. G. (ref51/cit51) 2005; 2005 Eichkorn K. (ref35/cit35) 1997; 97 Pettersen E. F. (ref44/cit44) 2004; 25 Kirchner B. (ref42/cit42) 2007; 11 Neese F. (ref38/cit38) 2009; 356 Neese F. (ref43/cit43) 2004; 65 Maeda H. (ref5/cit5) 2003; 125 Farrugia L. J. (ref29/cit29) 1997; 30 Krebs C. (ref9/cit9) 1999; 38 Ghosh M. (ref16/cit16) 2010; 39 Iskander M. F. (ref45/cit45) 1982; 7 Wilson R. (ref25/cit25) 1966; 44 Cowley A. R. (ref50/cit50) 2004 Eastland G. W. (ref55/cit55) 1986; 82 Sheldrick G. M. (ref28/cit28) 2008; 64 Knof U. (ref19/cit19) 1993; 32 Diaddario L. L. (ref1/cit1) 1983; 22 Xiao Z. (ref52/cit52) 2008; 47 Atkins P. W. (ref23/cit23) 1966; 44 Froncisz W. (ref26/cit26) 1980; 73 Hanss J. (ref12/cit12) 1996; 35 Bhadbhade M. M. (ref54/cit54) 1993; 32 Gerber T. I. A. (ref47/cit47) 2007; 60 Kossmann A. S. (ref37/cit37) 2009; 481 Bossu F. P. (ref4/cit4) 1977; 99 Cervera B. (ref8/cit8) 1998 Pereira E. (ref53/cit53) 2008; 27 McDonald M. R. (ref2/cit2) 1997; 36 Knof U. (ref11/cit11) 1993 Grimme A. S. (ref40/cit40) 2006; 27 Pratesi A. (ref3/cit3) 2007; 46 Will S. (ref6/cit6) 1997; 36 Akbar Ali M. (ref20/cit20) 1977; 39 Desbenoit N. (ref13/cit13) 2009; 62 Noodleman L. (ref41/cit41) 1995; 144 Kivelson D. (ref22/cit22) 1960; 33 Becke A. D. (ref31/cit31) 1986; 84 Butin K. P. (ref14/cit14) 2005; 74 Brückner C. (ref7/cit7) 2003; 42 Becke A. D. (ref32/cit32) 1993; 98 Castiñeiras A. (ref49/cit49) 1998; 17 Hyde J. S. (ref27/cit27) 1982; 11 Klamt A. (ref39/cit39) 1993 Lee C. T. (ref33/cit33) 1988; 37 Hanson G. R. (ref21/cit21) 2004; 98 Eichkorn K. (ref36/cit36) 1995; 240 Kaim W. (ref15/cit15) 2011; 50 |
| References_xml | – volume: 65 start-page: 781 year: 2004 ident: ref43/cit43 publication-title: J. Phys. Chem. Solids doi: 10.1016/j.jpcs.2003.11.015 – volume: 44 start-page: 4440 year: 1966 ident: ref25/cit25 publication-title: J. Chem. Phys. doi: 10.1063/1.1726658 – volume: 64 start-page: 112 year: 2008 ident: ref28/cit28 publication-title: Acta Crystallogr., Sect. A doi: 10.1107/S0108767307043930 – volume: 37 start-page: 785 year: 1988 ident: ref33/cit33 publication-title: Phys. Rev. B: Condens. Matter Mater. Phys. doi: 10.1103/PhysRevB.37.785 – volume: 11 start-page: 134 year: 2007 ident: ref42/cit42 publication-title: Curr. Opin. Chem. Biol. doi: 10.1016/j.cbpa.2007.02.026 – volume: 27 start-page: 335 year: 2008 ident: ref53/cit53 publication-title: Polyhedron doi: 10.1016/j.poly.2007.09.030 – volume: 62 start-page: 2472 year: 2009 ident: ref13/cit13 publication-title: J. Coord. Chem. doi: 10.1080/00958970902855614 – volume: 73 start-page: 3123 year: 1980 ident: ref26/cit26 publication-title: J. Chem. Phys. doi: 10.1063/1.440548 – volume: 42 start-page: 4495 year: 2003 ident: ref7/cit7 publication-title: Inorg. Chem. doi: 10.1021/ic034080u – volume: 27 start-page: 1787 year: 2006 ident: ref40/cit40 publication-title: J. Comput. Chem. doi: 10.1002/jcc.20495 – volume: 98 start-page: 903 year: 2004 ident: ref21/cit21 publication-title: J. Inorg. Biochem. doi: 10.1016/j.jinorgbio.2004.02.003 – volume: 47 start-page: 4338 year: 2008 ident: ref52/cit52 publication-title: Inorg. Chem. doi: 10.1021/ic702440e – volume: 144 start-page: 199 year: 1995 ident: ref41/cit41 publication-title: Coord. Chem. Rev. doi: 10.1016/0010-8545(95)07011-L – volume: 60 start-page: 2369 year: 2007 ident: ref47/cit47 publication-title: J. Coord. Chem. doi: 10.1080/00958970701266724 – volume: 125 start-page: 11822 year: 2003 ident: ref5/cit5 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0356075 – volume: 36 start-page: 357 year: 1997 ident: ref6/cit6 publication-title: Angew. Chem., Int. Ed. Engl. doi: 10.1002/anie.199703571 – volume: 2005 start-page: 4401 year: 2005 ident: ref51/cit51 publication-title: Eur. J. Inorg. Chem. doi: 10.1002/ejic.200500363 – start-page: 726 year: 1993 ident: ref11/cit11 publication-title: J. Chem. Soc., Chem. Commun. doi: 10.1039/C39930000726 – volume: 46 start-page: 10038 year: 2007 ident: ref3/cit3 publication-title: Inorg. Chem. doi: 10.1021/ic701411y – volume: 32 start-page: 6122 year: 1993 ident: ref54/cit54 publication-title: Inorg. Chem. doi: 10.1021/ic00078a037 – volume: 31 start-page: 3264 year: 1992 ident: ref18/cit18 publication-title: Inorg. Chem. doi: 10.1021/ic00041a019 – volume: 74 start-page: 531 year: 2005 ident: ref14/cit14 publication-title: Russ. Chem. Rev. doi: 10.1070/RC2005v074n06ABEH000977 – volume: 82 start-page: 2833 year: 1986 ident: ref55/cit55 publication-title: J. Chem. Soc., Faraday Trans. doi: 10.1039/f19868202833 – volume: 22 start-page: 1021 year: 1983 ident: ref1/cit1 publication-title: Inorg. Chem. doi: 10.1021/ic00149a004 – volume: 51 start-page: 1251 year: 2012 ident: ref17/cit17 publication-title: Inorg. Chem. doi: 10.1021/ic202764j – volume: 44 start-page: 169 year: 1966 ident: ref23/cit23 publication-title: J. Chem. Phys. doi: 10.1063/1.1726440 – volume: 44 start-page: 154 year: 1966 ident: ref24/cit24 publication-title: J. Chem. Phys. doi: 10.1063/1.1726439 – start-page: 799 year: 1993 ident: ref39/cit39 publication-title: J. Chem. Soc. Perkin Trans. 2 doi: 10.1039/P29930000799 – volume: 36 start-page: 471 year: 2011 ident: ref48/cit48 publication-title: Transition Met. Chem. doi: 10.1007/s11243-011-9492-0 – volume: 11 start-page: 391 year: 1982 ident: ref27/cit27 publication-title: Annu. Rev. Biophys. Bioeng. doi: 10.1146/annurev.bb.11.060182.002135 – volume: 17 start-page: 2751 year: 1998 ident: ref49/cit49 publication-title: Polyhedron doi: 10.1016/S0277-5387(98)00063-1 – start-page: 781 year: 1998 ident: ref8/cit8 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/a706964b – volume: 133 start-page: 3 year: 1987 ident: ref46/cit46 publication-title: Inorg. Chim. Acta doi: 10.1016/S0020-1693(00)84357-1 – start-page: 1111 year: 1982 ident: ref10/cit10 publication-title: J. Chem. Soc., Chem. Commun. doi: 10.1039/c39820001111 – volume-title: ORCA, an Ab Initio, Density Functional and Semiempirical Electronic Structure Package year: 2010 ident: ref30/cit30 – volume: 36 start-page: 3119 year: 1997 ident: ref2/cit2 publication-title: Inorg. Chem. doi: 10.1021/ic9608713 – volume: 240 start-page: 283 year: 1995 ident: ref36/cit36 publication-title: Chem. Phys. Lett. doi: 10.1016/0009-2614(95)00621-A – volume: 35 start-page: 2827 year: 1996 ident: ref12/cit12 publication-title: Angew. Chem., Int. Ed. Engl. doi: 10.1002/anie.199628271 – volume: 99 start-page: 2195 year: 1977 ident: ref4/cit4 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00449a028 – volume: 25 start-page: 1605 year: 2004 ident: ref44/cit44 publication-title: J. Comput. Chem. doi: 10.1002/jcc.20084 – volume: 7 start-page: 3297 year: 2005 ident: ref34/cit34 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/b508541a – volume: 97 start-page: 119 year: 1997 ident: ref35/cit35 publication-title: Theor. Chem. Acc. doi: 10.1007/s002140050244 – volume: 356 start-page: 98 year: 2009 ident: ref38/cit38 publication-title: Chem. Phys. doi: 10.1016/j.chemphys.2008.10.036 – volume: 38 start-page: 359 year: 1999 ident: ref9/cit9 publication-title: Angew. Chem., Int. Ed. doi: 10.1002/(SICI)1521-3773(19990201)38:3<359::AID-ANIE359>3.0.CO;2-5 – volume: 84 start-page: 4524 year: 1986 ident: ref31/cit31 publication-title: J. Chem. Phys. doi: 10.1063/1.450025 – volume: 39 start-page: 1785 year: 1977 ident: ref20/cit20 publication-title: J. Inorg. Nucl. Chem. doi: 10.1016/0022-1902(77)80202-9 – volume: 30 start-page: 565 year: 1997 ident: ref29/cit29 publication-title: J. Appl. Crystallogr. doi: 10.1107/S0021889897003117 – volume: 7 start-page: 135 year: 1982 ident: ref45/cit45 publication-title: Transition Met. Chem. doi: 10.1007/BF01035826 – volume: 32 start-page: 1635 year: 1993 ident: ref19/cit19 publication-title: Angew. Chem., Int. Ed. Engl. doi: 10.1002/anie.199316351 – start-page: 2404 year: 2004 ident: ref50/cit50 publication-title: Dalton Trans. doi: 10.1039/b406429a – volume: 33 start-page: 1094 year: 1960 ident: ref22/cit22 publication-title: J. Chem. Phys. doi: 10.1063/1.1731340 – volume: 39 start-page: 1996 year: 2010 ident: ref16/cit16 publication-title: Dalton Trans. doi: 10.1039/b916682c – volume: 481 start-page: 240 year: 2009 ident: ref37/cit37 publication-title: Chem. Phys. Lett. doi: 10.1016/j.cplett.2009.09.073 – volume: 98 start-page: 5648 year: 1993 ident: ref32/cit32 publication-title: J. Chem. Phys. doi: 10.1063/1.464913 – volume: 50 start-page: 9752 year: 2011 ident: ref15/cit15 publication-title: Inorg. Chem. doi: 10.1021/ic2003832 |
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| Snippet | The new tribasic N2S2 ligand H3ttfasbz has been synthesized by condensation of 4-thenoyl 2,2,2-trifluoroacetone and S-benzyl dithiocarbazate. On complexation... The new tribasic N(2)S(2) ligand H(3)ttfasbz has been synthesized by condensation of 4-thenoyl 2,2,2-trifluoroacetone and S-benzyl dithiocarbazate. On... |
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| StartPage | 1650 |
| SubjectTerms | Copper - chemistry Crystallography, X-Ray Hydrazines - chemistry Ligands Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oxidation-Reduction Quantum Theory Schiff Bases - chemistry Sulfhydryl Compounds - chemistry |
| Title | The Trivalent Copper Complex of a Conjugated Bis-dithiocarbazate Schiff Base: Stabilization of Cu in Three Different Oxidation States |
| URI | http://dx.doi.org/10.1021/ic302596h https://www.ncbi.nlm.nih.gov/pubmed/23324063 https://www.proquest.com/docview/1284287346 |
| Volume | 52 |
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