Ultrafast Spatial Imaging of Charge Dynamics in Heterogeneous Polymer Blends

Proof-of-concept transient absorption microscopy (TAM) with simultaneously high spatial and temporal resolution was demonstrated to image charge generation and recombination in model systems of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) blends upon extended t...

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Published inThe journal of physical chemistry letters Vol. 3; no. 7; pp. 879 - 884
Main Authors Wong, Chris Tsz On, Lo, Shun Shang, Huang, Libai
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 05.04.2012
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Abstract Proof-of-concept transient absorption microscopy (TAM) with simultaneously high spatial and temporal resolution was demonstrated to image charge generation and recombination in model systems of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) blends upon extended thermal annealing. Significant spatial heterogeneity in charge generation and recombination dynamics was revealed on the length scale of hundreds of nanometers near the micrometer-sized PCBM crystallites, suggesting that information obtained in ensemble measurements by integrating over microscopically inhomogeneous areas could be misleading. In contrast to previous studies, high sensitivity of our instrumentation allows us to employ low excitation intensities to minimize higher-order recombination processes. TAM provides a unique noncontact tool to probe local functionality in microscopically heterogeneous energy harvesting systems.
AbstractList Proof-of-concept transient absorption microscopy (TAM) with simultaneously high spatial and temporal resolution was demonstrated to image charge generation and recombination in model systems of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) blends upon extended thermal annealing. Significant spatial heterogeneity in charge generation and recombination dynamics was revealed on the length scale of hundreds of nanometers near the micrometer-sized PCBM crystallites, suggesting that information obtained in ensemble measurements by integrating over microscopically inhomogeneous areas could be misleading. In contrast to previous studies, high sensitivity of our instrumentation allows us to employ low excitation intensities to minimize higher-order recombination processes. TAM provides a unique noncontact tool to probe local functionality in microscopically heterogeneous energy harvesting systems.
Author Wong, Chris Tsz On
Lo, Shun Shang
Huang, Libai
AuthorAffiliation University of Notre Dame
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  givenname: Shun Shang
  surname: Lo
  fullname: Lo, Shun Shang
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  givenname: Libai
  surname: Huang
  fullname: Huang, Libai
  email: lhuang2@nd.edu
BackLink https://www.ncbi.nlm.nih.gov/pubmed/26286414$$D View this record in MEDLINE/PubMed
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organic solar cells
transient absorption microscopy
atomic force microscopy
ultrafast spectroscopy
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Snippet Proof-of-concept transient absorption microscopy (TAM) with simultaneously high spatial and temporal resolution was demonstrated to image charge generation and...
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Title Ultrafast Spatial Imaging of Charge Dynamics in Heterogeneous Polymer Blends
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