New Type of Li Ion Conductor with 3D Interconnected Nanopores via Polymerization of a Liquid Organic Electrolyte-Filled Lyotropic Liquid-Crystal Assembly
A new type of polymer electrolyte material for Li ion transport has been developed. This material is based on a polymerizable lyotropic (i.e., amphiphilic) liquid crystal (1) that forms a type-II bicontinuous cubic (QII) phase with the common liquid electrolyte, propylene carbonate (PC), and its Li...
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Published in | Journal of the American Chemical Society Vol. 131; no. 44; pp. 15972 - 15973 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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WASHINGTON
American Chemical Society
11.11.2009
Amer Chemical Soc |
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Abstract | A new type of polymer electrolyte material for Li ion transport has been developed. This material is based on a polymerizable lyotropic (i.e., amphiphilic) liquid crystal (1) that forms a type-II bicontinuous cubic (QII) phase with the common liquid electrolyte, propylene carbonate (PC), and its Li salt solutions. The resulting cross-linked, solid−liquid nanocomposite has an ordered, three-dimensional interconnected network of phase-separated liquid PC nanochannels and exhibits a room-temperature ion conductivity of 10−4 to 10−3 S cm−1 when formed with 15 wt % 0.245 M LiClO4−PC solution. This value approaches that of conventional gelled poly(ethylene oxide)-based electrolytes blended with larger amounts of higher-concentration Li salt solutions. It is also similar to that of a bulk 0.245 M LiClO4−PC solution measured using the same AC impedance methods. Preliminary variable-temperature ion conductivity and NMR DOSY studies showed that liquidlike diffusion is present in the QII nanochannels and that good ion conductivity (∼10−4 S cm−1) and PC mobility are retained down to −35 °C (and lower). This type of stable, liquidlike ion conductivity over a broad temperature range is typically not exhibited by conventional gelled-polymer- or liquid-crystal-based electrolytes, making this new material potentially valuable for enabling Li ion batteries that can operate more efficiently over a wider temperature range. |
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AbstractList | A new type of polymer electrolyte material for Li ion transport has been developed. This material is based on a polymerizable lyotropic (i.e., amphiphilic) liquid crystal (1) that forms a type-II bicontinuous cubic (Q(II)) phase with the common liquid electrolyte, propylene carbonate (PC), and its Li salt solutions. The resulting cross-linked, solid-liquid nanocomposite has an ordered, three-dimensional interconnected network of phase-separated liquid PC nanochannels and exhibits a room-temperature ion conductivity of 10(-4) to 10(-3) S cm(-1) when formed with 15 wt % 0.245 M LiClO(4)-PC solution. This value approaches that of conventional gelled poly(ethylene oxide)-based electrolytes blended with larger amounts of higher-concentration Li salt solutions. It is also similar to that of a bulk 0.245 M LiClO(4)-PC solution measured using the same AC impedance methods. Preliminary variable-temperature ion conductivity and NMR DOSY studies showed that liquidlike diffusion is present in the Q(II) nanochannels and that good ion conductivity ( approximately 10(-4) S cm(-1)) and PC mobility are retained down to -35 degrees C (and lower). This type of stable, liquidlike ion conductivity over a broad temperature range is typically not exhibited by conventional gelled-polymer- or liquid-crystal-based electrolytes, making this new material potentially valuable for enabling Li ion batteries that can operate more efficiently over a wider temperature range. A new type of polymer electrolyte material for Li ion transport has been developed. This material is based on a polymerizable lyotropic (i.e., amphiphilic) liquid crystal (1) that forms a type-II bicontinuous cubic (QII) phase with the common liquid electrolyte, propylene carbonate (PC), and its Li salt solutions. The resulting cross-linked, solid−liquid nanocomposite has an ordered, three-dimensional interconnected network of phase-separated liquid PC nanochannels and exhibits a room-temperature ion conductivity of 10−4 to 10−3 S cm−1 when formed with 15 wt % 0.245 M LiClO4−PC solution. This value approaches that of conventional gelled poly(ethylene oxide)-based electrolytes blended with larger amounts of higher-concentration Li salt solutions. It is also similar to that of a bulk 0.245 M LiClO4−PC solution measured using the same AC impedance methods. Preliminary variable-temperature ion conductivity and NMR DOSY studies showed that liquidlike diffusion is present in the QII nanochannels and that good ion conductivity (∼10−4 S cm−1) and PC mobility are retained down to −35 °C (and lower). This type of stable, liquidlike ion conductivity over a broad temperature range is typically not exhibited by conventional gelled-polymer- or liquid-crystal-based electrolytes, making this new material potentially valuable for enabling Li ion batteries that can operate more efficiently over a wider temperature range. A new type of polymer electrolyte material for Li ion transport has been developed. This material is based on a polymerizable lyotropic (i.e., amphiphilic) liquid crystal (1) that forms a type-II bicontinuous cubic (Q(II)) phase with the common liquid electrolyte, propylene carbonate (PC), and its Li salt solutions. The resulting cross-linked, solid-liquid nanocomposite has an ordered, three-dimensional interconnected network of phase-separated liquid PC nanochannels and exhibits a room-temperature ion conductivity of 10(-4) to 10(-3) S cm(-1) when formed with 15 wt % 0.245 M LiClO4-PC solution. This value approaches that of conventional gelled poly(ethylene oxide)-based electrolytes blended with larger amounts of higher-concentration Li salt solutions. It is also similar to that of a bulk 0.245 M LiClO4-PC solution measured using the same AC impedance methods. Preliminary variable-temperature ion conductivity and NMR DOSY studies showed that liquidlike diffusion is present in the Q(II) nanochannels and that good ion conductivity (similar to 10(-4) S cm(-1)) and PC mobility are retained down to -35 degrees C (and lower). This type of stable, liquidlike ion conductivity over a broad temperature range is typically not exhibited by conventional gelled-polymer- or liquid-crystal-based electrolytes, making this new material potentially valuable for enabling Li ion batteries that can operate more efficiently over a wider temperature range. |
Author | Shoemaker, Richard K. Kerr, Robert L. Miller, Seth A. Elliott, Brian J. Gin, Douglas L. |
Author_xml | – sequence: 1 givenname: Robert L. surname: Kerr fullname: Kerr, Robert L. – sequence: 2 givenname: Seth A. surname: Miller fullname: Miller, Seth A. – sequence: 3 givenname: Richard K. surname: Shoemaker fullname: Shoemaker, Richard K. – sequence: 4 givenname: Brian J. surname: Elliott fullname: Elliott, Brian J. email: belliott@tda.com, gin@spot.colorado.edu – sequence: 5 givenname: Douglas L. surname: Gin fullname: Gin, Douglas L. email: belliott@tda.com, gin@spot.colorado.edu |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/19839612$$D View this record in MEDLINE/PubMed |
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Snippet | A new type of polymer electrolyte material for Li ion transport has been developed. This material is based on a polymerizable lyotropic (i.e., amphiphilic)... |
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SubjectTerms | Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology |
Title | New Type of Li Ion Conductor with 3D Interconnected Nanopores via Polymerization of a Liquid Organic Electrolyte-Filled Lyotropic Liquid-Crystal Assembly |
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