Unveiling the Unique Reactivity of Anionic Mn(I) Complexes via Metal–Ligand Cooperation: Nucleophilic Attack on C(sp3)–X Bonds

• Published in: Journal of the American Chemical Society Vol. 146; no. 39; pp. 26649 - 26656
• Main Authors: Li, Hengxu, Fan, Mingjie, Liu, Qiang
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 02.10.2024
• Subjects: catalytic activity; cross-coupling reactions; dehydrogenation; hydrogenation; Lewis acids; Lewis bases; ligands; manganese; reducing agents

Metal–ligand cooperation (MLC) has emerged as a pivotal strategy for the catalytic activation of small molecules within both synthetic and biological arenas. Leveraging this approach, a suite of potent catalytic reactionsencompassing hydrogenation, hydroelementation, and dehydrogenative processesh...