Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System

• Published in: Journal of the American Chemical Society Vol. 133; no. 14; pp. 5561 - 5572
• Main Authors: Sun, Chuan-Fu, Hu, Chun-Li, Xu, Xiang, Yang, Bing-Ping, Mao, Jiang-Gao
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 13.04.2011

Four new potassium vanadyl iodates based on lone-pair-containing IO3 and second-order Jahn−Teller distorted VO5 or VO6 asymmetric units, namely, α-KVO2(IO3)2(H2O) (Pbca), β-KVO2(IO3)2(H2O) (P212121), K4[(VO)(IO3)5]2(HIO3)(H2O)2 ·H2O (P1), and K(VO)2O2(IO3)3 ( Ima2) have been successfully synthesized...