Henry's Law: A Retrospective
This article reviews the evolution of Henry's law from its original form as a description of the effect of pressure on the solubility of a gas through a description of the vapor pressure of a volatile solute in dilute solution to a basis of the standard state of a solute. We also relate Henry&#...
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| Published in | Journal of chemical education Vol. 81; no. 11; pp. 1647 - 1652 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Easton
Division of Chemical Education
01.11.2004
Journal of Chemical Education, Subscription Department American Chemical Society |
| Subjects | |
| Online Access | Get full text |
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| Abstract | This article reviews the evolution of Henry's law from its original form as a description of the effect of pressure on the solubility of a gas through a description of the vapor pressure of a volatile solute in dilute solution to a basis of the standard state of a solute. We also relate Henry's law to the properties of regular solutions. We raise the question of whether Henry's law is applicable to any finite concentration and conclude that it is properly only a limiting law in the limit of infinite dilution. |
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| AbstractList | This article reviews the evolution of Henry's law from its original form as a description of the effect of pressure on the solubility of a gas through a description of the vapor pressure of a volatile solute in dilute solution to a basis of the standard state of a solute. We also relate Henry's law to the properties of regular solutions. We raise the question of whether Henry's law is applicable to any finite concentration and conclude that it is properly only a limiting law in the limit of infinite dilution. A retrospective view of Henry's law and its applicability in any specific system at a finite concentration is tested. It can be concluded that Henry's law is only a limiting law and is adequate at low mole fractions but is useful for practical purposes where high precision is not required. Rosenberg and Peticolas consider the evolution of Henry's law. They also review the question: Is there sufficient experimental evidence to demonstrate that Henry's law applies in any specific system at finite concentration or whether it is only a limiting law valid at zero concentration of solute? |
| Author | Peticolas, Warner L Rosenberg, Robert M |
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| Copyright | Copyright American Chemical Society Nov 2004 |
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| DOI | 10.1021/ed081p1647 |
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| Snippet | This article reviews the evolution of Henry's law from its original form as a description of the effect of pressure on the solubility of a gas through a... A retrospective view of Henry's law and its applicability in any specific system at a finite concentration is tested. It can be concluded that Henry's law is... Rosenberg and Peticolas consider the evolution of Henry's law. They also review the question: Is there sufficient experimental evidence to demonstrate that... |
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| SubjectTerms | Chemistry Gases Henry, William Henrys law Law Science Education Science Instruction |
| Title | Henry's Law: A Retrospective |
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