Stable Interfaces in a Sodium Metal-Free, Solid-State Sodium-Ion Battery with Gradient Composite Electrolyte

Composite electrolytes (CE) combining a ceramic filler and a polymer matrix is an effective way to enhance battery safety. But the increased ceramic filler mass fraction decreases the flexibility, which increases the interfacial resistance. To alleviate interfacial resistance further, a gradient com...

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Published inACS applied materials & interfaces Vol. 13; no. 33; pp. 39355 - 39362
Main Authors Ran, Lingbing, Tao, Shiwei, Gentle, Ian, Luo, Bin, Li, Ming, Rana, MdMasud, Wang, Lianzhou, Knibbe, Ruth
Format Journal Article
LanguageEnglish
Published American Chemical Society 25.08.2021
Subjects
Energy, Environmental, and Catalysis Applications
polymer
composite electrolyte
sodium metal-free anode
NASICON
solid-state battery
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Abstract Composite electrolytes (CE) combining a ceramic filler and a polymer matrix is an effective way to enhance battery safety. But the increased ceramic filler mass fraction decreases the flexibility, which increases the interfacial resistance. To alleviate interfacial resistance further, a gradient composite electrolyte (GCE) using a Sc, Ge-doped Na3Zr2Si2PO12 (NZSP) as the ceramic filler and poly­(ethylene oxide) (PEO) as the polymer matrix is proposed. The outer layer contains a low concentration of ceramic filler to improve interfacial contact, and the central layer contains a high concentration of ceramic filler to inhibit dendrite penetration. This GCE possesses an enhanced conductivity (4.0 × 10–5 S cm–1 at 30 °C) and a reduced interfacial resistance. Furthermore, the safety was boosted using Sn4P3@CNT/C as the high-capacity anode active material and Na3V2(PO4)3 (NVP) as the cathode active material. This ultrasafe sodium metal-free, solid-state sodium-ion battery (SSSIB) displays an impressive cycling performance.
AbstractList Composite electrolytes (CE) combining a ceramic filler and a polymer matrix is an effective way to enhance battery safety. But the increased ceramic filler mass fraction decreases the flexibility, which increases the interfacial resistance. To alleviate interfacial resistance further, a gradient composite electrolyte (GCE) using a Sc, Ge-doped Na3Zr2Si2PO12 (NZSP) as the ceramic filler and poly­(ethylene oxide) (PEO) as the polymer matrix is proposed. The outer layer contains a low concentration of ceramic filler to improve interfacial contact, and the central layer contains a high concentration of ceramic filler to inhibit dendrite penetration. This GCE possesses an enhanced conductivity (4.0 × 10–5 S cm–1 at 30 °C) and a reduced interfacial resistance. Furthermore, the safety was boosted using Sn4P3@CNT/C as the high-capacity anode active material and Na3V2(PO4)3 (NVP) as the cathode active material. This ultrasafe sodium metal-free, solid-state sodium-ion battery (SSSIB) displays an impressive cycling performance.
Author Li, Ming
Knibbe, Ruth
Wang, Lianzhou
Gentle, Ian
Ran, Lingbing
Rana, MdMasud
Luo, Bin
Tao, Shiwei
AuthorAffiliation The University of Queensland
School of Mechanical and Mining Engineering
School of Chemistry and Molecular Biosciences
Australian Institute for Bioengineering and Nanotechnology (AIBN)
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Snippet Composite electrolytes (CE) combining a ceramic filler and a polymer matrix is an effective way to enhance battery safety. But the increased ceramic filler...
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SubjectTerms Energy, Environmental, and Catalysis Applications
Title Stable Interfaces in a Sodium Metal-Free, Solid-State Sodium-Ion Battery with Gradient Composite Electrolyte
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