Recyclable Biophenolic Nanospheres for Sustainable and Durable Multifunctional Applications in Thermosets

Nanomaterials have a critical role in functional materials engineering; however, their efficient recycling, durable use, and multifunctional integration remain a huge challenge for sustainable development. Herein, we report multifunctional biophenolic nanospheres that exploit stimuli-responsive reve...

Full description

Saved in:
Bibliographic Details
Published inACS materials letters Vol. 5; no. 6; pp. 1692 - 1702
Main Authors Zeng, Fu-Rong, Liu, Bo-Wen, Wang, Zi-Hao, Zhang, Jia-Yan, Chen, Xue-Lian, Zhao, Hai-Bo, Wang, Yu-Zhong
Format Journal Article
LanguageEnglish
Published American Chemical Society 05.06.2023
Online AccessGet full text

Cover

Abstract Nanomaterials have a critical role in functional materials engineering; however, their efficient recycling, durable use, and multifunctional integration remain a huge challenge for sustainable development. Herein, we report multifunctional biophenolic nanospheres that exploit stimuli-responsive reversible assembly based on multiple directional interactions, allowing for closed-loop recycling and durability, even in complex systems of thermosets. The biobased nanospheres can serve long-term in various environments (high temperature, water, acid, surfactant solutions, etc.). By matching disassembly conditions, the nanospheres can be circularly dissociated into precursors, removed from application systems, reassembled, and reused sustainably. The corresponding mechanism is illustrated by experimental characterization and theoretical simulation. We further demonstrate the recycling and durable multifunctional effects of the nanospheres in thermoset foams. The reproducible nanospheres with diverse radical scavenging abilities endow nanocomposites with excellent mechanical enhancement, aging resistance, and durable flame retardancy. This study paves the way for tackling the pressing issue of high-value functional nanomaterial sustainability.
AbstractList Nanomaterials have a critical role in functional materials engineering; however, their efficient recycling, durable use, and multifunctional integration remain a huge challenge for sustainable development. Herein, we report multifunctional biophenolic nanospheres that exploit stimuli-responsive reversible assembly based on multiple directional interactions, allowing for closed-loop recycling and durability, even in complex systems of thermosets. The biobased nanospheres can serve long-term in various environments (high temperature, water, acid, surfactant solutions, etc.). By matching disassembly conditions, the nanospheres can be circularly dissociated into precursors, removed from application systems, reassembled, and reused sustainably. The corresponding mechanism is illustrated by experimental characterization and theoretical simulation. We further demonstrate the recycling and durable multifunctional effects of the nanospheres in thermoset foams. The reproducible nanospheres with diverse radical scavenging abilities endow nanocomposites with excellent mechanical enhancement, aging resistance, and durable flame retardancy. This study paves the way for tackling the pressing issue of high-value functional nanomaterial sustainability.
Author Zeng, Fu-Rong
Liu, Bo-Wen
Wang, Zi-Hao
Chen, Xue-Lian
Zhao, Hai-Bo
Zhang, Jia-Yan
Wang, Yu-Zhong
AuthorAffiliation The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials, National Engineering Laboratory of Eco-Friendly Polymeric Materials (Sichuan), College of Chemistry
AuthorAffiliation_xml – name: The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials, National Engineering Laboratory of Eco-Friendly Polymeric Materials (Sichuan), College of Chemistry
Author_xml – sequence: 1
  givenname: Fu-Rong
  surname: Zeng
  fullname: Zeng, Fu-Rong
– sequence: 2
  givenname: Bo-Wen
  orcidid: 0000-0002-1355-7495
  surname: Liu
  fullname: Liu, Bo-Wen
– sequence: 3
  givenname: Zi-Hao
  surname: Wang
  fullname: Wang, Zi-Hao
– sequence: 4
  givenname: Jia-Yan
  surname: Zhang
  fullname: Zhang, Jia-Yan
– sequence: 5
  givenname: Xue-Lian
  surname: Chen
  fullname: Chen, Xue-Lian
– sequence: 6
  givenname: Hai-Bo
  orcidid: 0000-0002-5455-2965
  surname: Zhao
  fullname: Zhao, Hai-Bo
  email: haibor7@163.com
– sequence: 7
  givenname: Yu-Zhong
  surname: Wang
  fullname: Wang, Yu-Zhong
  email: polymers@vip.126.com
BookMark eNqNkM1KAzEUhYNUsNa-Q15gajJJ5mcj1PoLVUHrerjNZDAlTYYks-jbm7YupBtd3XPhfId7zyUaWWcVQpiSGSU5vQYZthCV12CCUTHOmCSEE3aGxnnB6ozXZT36pS_QNIQNIYktaM35GOl3JXfSwNoofKtd_6WsM1riV7AupM2rgDvn8ccQImh78IFt8d3gD_plMFF3g5VROwsGz_s-4bDfAtYWr1LE1gUVwxU679KZavozJ-jz4X61eMqWb4_Pi_kyA0Z4zKADEFBSCnkpW8YE1Ax4sQZRQCVLwSreCi6KmrQcCiGhymnerrmsIVdCEDZB1TFXeheCV13Te70Fv2soafatNaetNT-tJfTmBJU6Hn6JHrT5TwA_BiRHs3GDT5WEv7FvapOS4Q
CitedBy_id crossref_primary_10_1039_D3NJ02419A
crossref_primary_10_1016_j_cej_2023_147547
crossref_primary_10_1039_D3SM00709J
crossref_primary_10_1021_acsmaterialslett_4c02041
crossref_primary_10_1039_D3MH00720K
crossref_primary_10_1016_j_ijbiomac_2024_138572
crossref_primary_10_1021_acsapm_3c02706
crossref_primary_10_1016_j_coco_2024_101951
crossref_primary_10_1039_D4MH00116H
crossref_primary_10_1002_adfm_202419263
crossref_primary_10_1021_acsami_3c06860
crossref_primary_10_1039_D4MH00039K
crossref_primary_10_1080_01932691_2023_2245450
crossref_primary_10_1016_j_polymer_2024_126780
crossref_primary_10_1038_s41467_024_46756_0
crossref_primary_10_1016_j_polymdegradstab_2025_111324
crossref_primary_10_1016_j_porgcoat_2023_107947
crossref_primary_10_1016_j_cej_2024_156865
crossref_primary_10_3390_polym16192752
crossref_primary_10_1016_j_matchemphys_2024_130066
crossref_primary_10_1021_acsapm_3c03144
crossref_primary_10_1016_j_coco_2024_101889
crossref_primary_10_1016_j_surfin_2024_104523
crossref_primary_10_1016_j_compositesa_2024_108373
crossref_primary_10_1093_nsr_nwae360
crossref_primary_10_1021_acsmaterialslett_3c00755
crossref_primary_10_1002_admi_202300461
crossref_primary_10_3390_polym15194031
crossref_primary_10_1039_D4MH00607K
crossref_primary_10_1016_j_polymdegradstab_2024_110763
crossref_primary_10_1002_adma_202414880
crossref_primary_10_1021_acsapm_3c02481
crossref_primary_10_1016_j_cej_2023_147971
crossref_primary_10_1016_j_nanoso_2024_101328
Cites_doi 10.1021/acsnano.9b01487
10.1002/adma.202107905
10.1021/acsmaterialslett.9b00283
10.1021/jacs.7b02723
10.1021/acsmaterialslett.2c01173
10.1038/s41557-019-0249-2
10.1002/anie.202012477
10.1002/anie.201000044
10.1002/adma.202202177
10.1021/jacs.1c10391
10.1126/sciadv.add8527
10.1016/j.foodchem.2010.08.012
10.1002/adma.202203266
10.1039/c3ta14179a
10.1039/C7CC03280C
10.1016/j.jhazmat.2018.12.077
10.1021/acsmacrolett.1c00729
10.1021/acsmaterialslett.2c00419
10.1016/j.pmatsci.2020.100687
10.1002/anie.202006175
10.1002/adma.201802309
10.1002/adfm.202002234
10.1021/acsmaterialslett.9b00393
10.1021/acs.accounts.0c00150
10.1021/acsmaterialslett.0c00062
10.1126/sciadv.aaq0508
10.1021/acsmaterialslett.2c00283
10.1021/jacs.1c04446
10.1039/C9NR04142G
10.1002/anie.201711735
10.1038/s41467-020-18589-0
10.1039/C8NR07236A
10.1021/ja311374b
10.1021/acsmaterialslett.1c00053
10.1039/D0CS00908C
10.1016/j.eng.2020.08.032
10.1021/jacs.1c08888
10.1002/anie.201605417
10.1038/s41586-020-03149-9
10.1038/s41578-020-0190-4
10.1021/acs.accounts.1c00651
10.1002/anie.202007039
10.1002/anie.201805781
10.1103/PhysRevLett.122.047801
10.1038/ncomms14463
10.1126/sciadv.aat7457
10.1002/adfm.202214913
10.1021/acs.macromol.8b02090
10.1016/j.cej.2022.140023
10.1038/s41893-019-0444-6
10.1039/D1SC03561D
ContentType Journal Article
Copyright 2023 American Chemical Society
Copyright_xml – notice: 2023 American Chemical Society
DBID AAYXX
CITATION
DOI 10.1021/acsmaterialslett.3c00403
DatabaseName CrossRef
DatabaseTitle CrossRef
DatabaseTitleList
DeliveryMethod fulltext_linktorsrc
Discipline Engineering
EISSN 2639-4979
EndPage 1702
ExternalDocumentID 10_1021_acsmaterialslett_3c00403
b174539068
GroupedDBID ABQRX
ACS
AHGAQ
ALMA_UNASSIGNED_HOLDINGS
EBS
GGK
M~E
VF5
VG9
AAYXX
ABBLG
ABJNI
ABLBI
BAANH
CITATION
CUPRZ
ID FETCH-LOGICAL-a304t-afaa5a711a27cd335a93a46ba56a8c75384d545690d4a65ca8212db4c9a2e5503
IEDL.DBID ACS
ISSN 2639-4979
IngestDate Thu Apr 24 23:06:15 EDT 2025
Tue Jul 01 04:21:56 EDT 2025
Thu Jul 06 08:30:32 EDT 2023
IsPeerReviewed true
IsScholarly true
Issue 6
Language English
License https://doi.org/10.15223/policy-029
https://doi.org/10.15223/policy-037
https://doi.org/10.15223/policy-045
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-a304t-afaa5a711a27cd335a93a46ba56a8c75384d545690d4a65ca8212db4c9a2e5503
ORCID 0000-0002-1355-7495
0000-0002-5455-2965
PageCount 11
ParticipantIDs crossref_primary_10_1021_acsmaterialslett_3c00403
crossref_citationtrail_10_1021_acsmaterialslett_3c00403
acs_journals_10_1021_acsmaterialslett_3c00403
ProviderPackageCode CITATION
AAYXX
PublicationCentury 2000
PublicationDate 2023-06-05
PublicationDateYYYYMMDD 2023-06-05
PublicationDate_xml – month: 06
  year: 2023
  text: 2023-06-05
  day: 05
PublicationDecade 2020
PublicationTitle ACS materials letters
PublicationTitleAlternate ACS Materials Lett
PublicationYear 2023
Publisher American Chemical Society
Publisher_xml – name: American Chemical Society
References ref9/cit9
ref45/cit45
ref3/cit3
ref27/cit27
ref16/cit16
ref52/cit52
ref23/cit23
ref8/cit8
ref31/cit31
ref2/cit2
ref34/cit34
ref37/cit37
ref20/cit20
ref17/cit17
ref10/cit10
ref35/cit35
ref53/cit53
ref19/cit19
ref21/cit21
ref42/cit42
ref46/cit46
ref49/cit49
ref13/cit13
ref24/cit24
ref38/cit38
ref50/cit50
ref6/cit6
ref36/cit36
ref18/cit18
Zhang J. Y. (ref48/cit48) 2022; 53
ref11/cit11
ref25/cit25
ref29/cit29
ref32/cit32
ref39/cit39
ref14/cit14
ref5/cit5
ref51/cit51
ref43/cit43
ref28/cit28
ref40/cit40
ref26/cit26
ref12/cit12
ref15/cit15
ref41/cit41
ref22/cit22
ref33/cit33
ref4/cit4
ref30/cit30
ref47/cit47
ref1/cit1
ref44/cit44
ref7/cit7
References_xml – ident: ref1/cit1
  doi: 10.1021/acsnano.9b01487
– ident: ref6/cit6
  doi: 10.1002/adma.202107905
– ident: ref11/cit11
  doi: 10.1021/acsmaterialslett.9b00283
– ident: ref36/cit36
  doi: 10.1021/jacs.7b02723
– ident: ref52/cit52
  doi: 10.1021/acsmaterialslett.2c01173
– ident: ref12/cit12
  doi: 10.1038/s41557-019-0249-2
– ident: ref22/cit22
  doi: 10.1002/anie.202012477
– ident: ref41/cit41
  doi: 10.1002/anie.201000044
– ident: ref9/cit9
  doi: 10.1002/adma.202202177
– ident: ref30/cit30
  doi: 10.1021/jacs.1c10391
– ident: ref7/cit7
  doi: 10.1126/sciadv.add8527
– ident: ref40/cit40
  doi: 10.1016/j.foodchem.2010.08.012
– ident: ref10/cit10
  doi: 10.1002/adma.202203266
– ident: ref49/cit49
  doi: 10.1039/c3ta14179a
– ident: ref26/cit26
  doi: 10.1039/C7CC03280C
– ident: ref45/cit45
  doi: 10.1016/j.jhazmat.2018.12.077
– ident: ref31/cit31
  doi: 10.1021/acsmacrolett.1c00729
– ident: ref5/cit5
  doi: 10.1021/acsmaterialslett.2c00419
– ident: ref4/cit4
  doi: 10.1016/j.pmatsci.2020.100687
– ident: ref25/cit25
  doi: 10.1002/anie.202006175
– ident: ref2/cit2
  doi: 10.1002/adma.201802309
– ident: ref39/cit39
  doi: 10.1002/adfm.202002234
– ident: ref42/cit42
  doi: 10.1021/acsmaterialslett.9b00393
– ident: ref29/cit29
  doi: 10.1021/acs.accounts.0c00150
– ident: ref44/cit44
  doi: 10.1021/acsmaterialslett.0c00062
– ident: ref13/cit13
  doi: 10.1126/sciadv.aaq0508
– ident: ref43/cit43
– ident: ref23/cit23
  doi: 10.1021/acsmaterialslett.2c00283
– ident: ref21/cit21
  doi: 10.1021/jacs.1c04446
– ident: ref35/cit35
  doi: 10.1039/C9NR04142G
– ident: ref47/cit47
  doi: 10.1002/anie.201711735
– ident: ref27/cit27
  doi: 10.1038/s41467-020-18589-0
– ident: ref32/cit32
  doi: 10.1039/C8NR07236A
– ident: ref33/cit33
  doi: 10.1021/ja311374b
– ident: ref17/cit17
  doi: 10.1021/acsmaterialslett.1c00053
– ident: ref28/cit28
  doi: 10.1039/D0CS00908C
– ident: ref46/cit46
  doi: 10.1016/j.eng.2020.08.032
– ident: ref18/cit18
  doi: 10.1021/jacs.1c08888
– ident: ref8/cit8
  doi: 10.1002/anie.201605417
– ident: ref14/cit14
  doi: 10.1038/s41586-020-03149-9
– ident: ref16/cit16
  doi: 10.1038/s41578-020-0190-4
– ident: ref3/cit3
  doi: 10.1021/acs.accounts.1c00651
– ident: ref19/cit19
  doi: 10.1002/anie.202007039
– ident: ref34/cit34
  doi: 10.1002/anie.201805781
– ident: ref38/cit38
  doi: 10.1103/PhysRevLett.122.047801
– ident: ref37/cit37
  doi: 10.1038/ncomms14463
– volume: 53
  start-page: 842
  year: 2022
  ident: ref48/cit48
  publication-title: Acta Polym. Sin.
– ident: ref24/cit24
  doi: 10.1126/sciadv.aat7457
– ident: ref53/cit53
  doi: 10.1002/adfm.202214913
– ident: ref50/cit50
  doi: 10.1021/acs.macromol.8b02090
– ident: ref51/cit51
  doi: 10.1016/j.cej.2022.140023
– ident: ref15/cit15
  doi: 10.1038/s41893-019-0444-6
– ident: ref20/cit20
  doi: 10.1039/D1SC03561D
SSID ssj0002161944
Score 2.4233263
Snippet Nanomaterials have a critical role in functional materials engineering; however, their efficient recycling, durable use, and multifunctional integration remain...
SourceID crossref
acs
SourceType Enrichment Source
Index Database
Publisher
StartPage 1692
Title Recyclable Biophenolic Nanospheres for Sustainable and Durable Multifunctional Applications in Thermosets
URI http://dx.doi.org/10.1021/acsmaterialslett.3c00403
Volume 5
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV07T8MwELZKWWDgjSgveWBNiV95jKW0qpDKUip1iy52KlWUFDXpAAO_nXMSSgXi0SXKcpZjn_Pd-e6-I-TKmDHiVuw6YHlnJR4gBzybZeHGiF8ooopC4f691xvKu5Ea1Qj_IYLP2TXoDG23cjvwU_Km0FbzxAbZ5B6eZWsOtQfLexXOrF9ug8ncE0UDtbBK4PltMItNOlvBphWQ6e6WhX9ZwU1oc0sem4s8burX78yNa8x_j-xUNidtlUqyT2pJekC2V5gID8kEzccXPbV1VPRmYrkGUksYTPHnO8ss80CSUTRv6eCz3opCaujtYl68F3W8FiPLq0XaWomL00lKURvnT7MsybMjMux2Hto9p-rC4IBwZe7AGECBzxhwXxshFIQCpBeD8iDQ6O0E0lgzLHSNBE9pCBANTSx1CDxB_0cck3o6S5MTQo1RwohYMeOBNCwIkhjQofT9JBy7IMMGcXC1ouoUZVERIOcs-rqEUbWEDeJ_7FekK0pz21lj-g9JtpR8Lmk9_pQ5XXN2Z2TL9qYv8srUOann80VygRZMHl8WKovP_lvnHdnM9Vk
linkProvider American Chemical Society
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV07T8MwELagDMDAG_HGA2tKEtt5jKVQFSgsLRJiiS52KlVAiup0gF_P2Q1t1IHXFkU6y49zvrvc3XeEnCnVR9xKXQcM7yzHC-RAYLIs3BTxC0WELRS-uw_aD_zmUTxWWn3hJDSOpG0Qf8Yu4J3jOzThJqeCKyrqTBoFZItkCW0S3yh3o9md_l7xPeOem5iyHzDbRy0u83i-G8xAlNQViKpgTWudPE1naVNMnuvjIq3LjzkCx38tY4OslRYobUxUZpMsZPkWWa3wEm6TARqT7_LFVFXRi4FhHsgNfTDFT_FQGx6CTFM0dml3Vn1FIVf0cjyyz7aq1yDm5EcjbVSi5HSQU9TN0etQZ4XeIQ-tq16z7ZQ9GRxgLi8c6AMICD0P_FAqxgTEDHiQggggkuj7RFwZoyx2FYdASIgQG1XKZQx-ht4Q2yW1fJhne4QqJZhiqfBUAFx5UZSlgO5lGGZx3wUe7xMHdysp75RObLjc95L5LUzKLdwn4dexJbIkODd9Nl5-IelNJd8mJB8_yhz8cXanZLndu-sknev720OyYrrW24wzcURqxWicHaNtU6QnVos_AUz2_Ik
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3JTsMwELVYJAQHdkRZfeCaksR2lmNZKnYhQSVu0cROpYqSVk16gK9nxgml4sB2iyKN5WWcN5OZecPYkTFdxK3UdYB4ZyVeIAcCyrJwU8QvFFG2UPj2LrjoyKsn9VTn5lAtDE6iwJEKG8SnWz003ZphwDvG92jGVSeDqyqbQpMSilk2T9E7UvDW6cPkF4vvkYtOcWU_ELaXWlzn8nw3GMGULqZgagpv2itVU1U7U5tm8twcl2lTv30hcfz3UlbZcm2J8lalOmtsJsvX2dIUP-EG66FR-ar7VF3FT3rEQJATjTDHT_KgID6CrOBo9PKHzyosDrnhZ-ORfbbVvYSc1Q9H3pqKlvNezlFHRy-DIiuLTdZpnz-eXjh1bwYHhCtLB7oACkLPAz_URggFsQAZpKACiDT6QJE0ZJzFrpEQKA0RYqRJpY7Bz9ArEltsLh_k2TbjxihhRKo8E4A0XhRlKaCbGYZZ3HVBxg3m4G4l9d0qEhs2973k6xYm9RY2WPhxdImuic6p30b_F5LeRHJYkX38KLPzx9kdsoX7s3Zyc3l3vcsWqXm9TTxTe2yuHI2zfTRxyvTAKvI7P5H_DA
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Recyclable+Biophenolic+Nanospheres+for+Sustainable+and+Durable+Multifunctional+Applications+in+Thermosets&rft.jtitle=ACS+materials+letters&rft.au=Zeng%2C+Fu-Rong&rft.au=Liu%2C+Bo-Wen&rft.au=Wang%2C+Zi-Hao&rft.au=Zhang%2C+Jia-Yan&rft.date=2023-06-05&rft.pub=American+Chemical+Society&rft.issn=2639-4979&rft.eissn=2639-4979&rft.volume=5&rft.issue=6&rft.spage=1692&rft.epage=1702&rft_id=info:doi/10.1021%2Facsmaterialslett.3c00403&rft.externalDocID=b174539068
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2639-4979&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2639-4979&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2639-4979&client=summon