Super Strong and Multi-Reusable Supramolecular Epoxy Hot Melt Adhesives
Hot melt adhesives are widely applied owing to their solvent-free nature. Developing robust and multi-reusable hot melt adhesives without harsh bonding conditions remains a great challenge. Herein, we develop a novel strategy of incorporating flexible side chains into the network of highly noncovale...
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Published in | ACS materials letters Vol. 3; no. 7; pp. 1003 - 1009 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
05.07.2021
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Abstract | Hot melt adhesives are widely applied owing to their solvent-free nature. Developing robust and multi-reusable hot melt adhesives without harsh bonding conditions remains a great challenge. Herein, we develop a novel strategy of incorporating flexible side chains into the network of highly noncovalently cross-linked hot melt adhesives to construct super strong and multi-reusable supramolecular epoxy hot melt adhesives (SEA). The SEA was prepared via polycondensation of diglycidyl ether of bisphenol A with O-(2-ureido-4[1H]-pyrimidinone)-O′-(2-aminopropyl)polypropylene glycol (the noncovalent cross-linker) and O-(2-aminopropyl)-O′-(2-methoxyethyl)polypropylene glycol (the flexible side chain). Impressively, the prepared SEA was endowed with a super high adhesion strength of 10.2 MPa, which is the highest adhesion strength in bonding stainless steel among hot melt adhesives constructed by dynamic bonds to the best of our knowledge. It also featured excellent multiple reusability with more than 80% of the original adhesion strength remained even after reuse for six times. Meanwhile, the SEA displayed an outstanding ability to bond diverse substrates tightly under considerably moderate bonding conditions (80 °C for 5 min). It is highly anticipated that this work will open a new avenue of designing hot melt adhesives with the high adhesion strength and excellent multiple reusability. |
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AbstractList | Hot melt adhesives are widely applied owing to their solvent-free nature. Developing robust and multi-reusable hot melt adhesives without harsh bonding conditions remains a great challenge. Herein, we develop a novel strategy of incorporating flexible side chains into the network of highly noncovalently cross-linked hot melt adhesives to construct super strong and multi-reusable supramolecular epoxy hot melt adhesives (SEA). The SEA was prepared via polycondensation of diglycidyl ether of bisphenol A with O-(2-ureido-4[1H]-pyrimidinone)-O′-(2-aminopropyl)polypropylene glycol (the noncovalent cross-linker) and O-(2-aminopropyl)-O′-(2-methoxyethyl)polypropylene glycol (the flexible side chain). Impressively, the prepared SEA was endowed with a super high adhesion strength of 10.2 MPa, which is the highest adhesion strength in bonding stainless steel among hot melt adhesives constructed by dynamic bonds to the best of our knowledge. It also featured excellent multiple reusability with more than 80% of the original adhesion strength remained even after reuse for six times. Meanwhile, the SEA displayed an outstanding ability to bond diverse substrates tightly under considerably moderate bonding conditions (80 °C for 5 min). It is highly anticipated that this work will open a new avenue of designing hot melt adhesives with the high adhesion strength and excellent multiple reusability. |
Author | Li, Yuquan Xu, Jiang-Fei Sun, Peng Zhang, Xi Qin, Bo |
AuthorAffiliation | Key Laboratory of Organic Optoelectronics & Molecular Engineering, Department of Chemistry |
AuthorAffiliation_xml | – name: Key Laboratory of Organic Optoelectronics & Molecular Engineering, Department of Chemistry |
Author_xml | – sequence: 1 givenname: Peng orcidid: 0000-0002-2640-5378 surname: Sun fullname: Sun, Peng – sequence: 2 givenname: Yuquan surname: Li fullname: Li, Yuquan – sequence: 3 givenname: Bo orcidid: 0000-0003-4342-3452 surname: Qin fullname: Qin, Bo – sequence: 4 givenname: Jiang-Fei orcidid: 0000-0001-8181-6113 surname: Xu fullname: Xu, Jiang-Fei email: xujf@mail.tsinghua.edu.cn – sequence: 5 givenname: Xi orcidid: 0000-0002-4823-9120 surname: Zhang fullname: Zhang, Xi email: xi@mail.tsinghua.edu.cn |
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