Catalytic Heaters at Oil and Gas Sites May be a Significant yet Overlooked Seasonal Source of Methane Emissions

Successful reduction of oil and gas sector methane emissions to meet near-zero intensity targets requires the identification and mitigation of all possible sources. One potentially important source is catalytic heaters, which have largely escaped attention in regulatory and mitigation efforts despit...

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Published inEnvironmental science & technology letters Vol. 11; no. 9; pp. 948 - 953
Main Authors Festa-Bianchet, Simon A., Mohammadikharkeshi, Milad, Tyner, David R., Johnson, Matthew R.
Format Journal Article
LanguageEnglish
Published American Chemical Society 10.09.2024
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Abstract Successful reduction of oil and gas sector methane emissions to meet near-zero intensity targets requires the identification and mitigation of all possible sources. One potentially important source is catalytic heaters, which have largely escaped attention in regulatory and mitigation efforts despite being ubiquitous at upstream production sites in cold climate regions. This study reports direct in situ measurements of the exhaust streams of 38 natural gas-fired catalytic heaters at upstream production sites in British Columbia, Canada. All heaters in the sample showed consistently poor methane conversion with mean destruction efficiencies of 61 ± 5% while releasing 235 [+31/–28] g of methane per cubic meter of fuel. Although individual units are generally small methane sources (mean of 0.28 ± 0.04 kg/h), their prevalence means they could represent 6% of the total provincial upstream methane inventory and as an aggregate methane source could be 5× more significant than abandoned wells. Notably, these heaters are seasonal sources whose emissions would be missed in measurement campaigns occurring solely in summer months. However, additional measurements from a small number of heat medium burners demonstrate that, where feasible, methane emissions can be reduced by approximately 425× by replacing catalytic heaters with centralized heat systems.
AbstractList Successful reduction of oil and gas sector methane emissions to meet near-zero intensity targets requires the identification and mitigation of all possible sources. One potentially important source is catalytic heaters, which have largely escaped attention in regulatory and mitigation efforts despite being ubiquitous at upstream production sites in cold climate regions. This study reports direct in situ measurements of the exhaust streams of 38 natural gas-fired catalytic heaters at upstream production sites in British Columbia, Canada. All heaters in the sample showed consistently poor methane conversion with mean destruction efficiencies of 61 ± 5% while releasing 235 [+31/–28] g of methane per cubic meter of fuel. Although individual units are generally small methane sources (mean of 0.28 ± 0.04 kg/h), their prevalence means they could represent 6% of the total provincial upstream methane inventory and as an aggregate methane source could be 5× more significant than abandoned wells. Notably, these heaters are seasonal sources whose emissions would be missed in measurement campaigns occurring solely in summer months. However, additional measurements from a small number of heat medium burners demonstrate that, where feasible, methane emissions can be reduced by approximately 425× by replacing catalytic heaters with centralized heat systems.
Successful reduction of oil and gas sector methane emissions to meet near-zero intensity targets requires the identification and mitigation of all possible sources. One potentially important source is catalytic heaters, which have largely escaped attention in regulatory and mitigation efforts despite being ubiquitous at upstream production sites in cold climate regions. This study reports direct in situ measurements of the exhaust streams of 38 natural gas-fired catalytic heaters at upstream production sites in British Columbia, Canada. All heaters in the sample showed consistently poor methane conversion with mean destruction efficiencies of 61 ± 5% while releasing 235 [+31/–28] g of methane per cubic meter of fuel. Although individual units are generally small methane sources (mean of 0.28 ± 0.04 kg/h), their prevalence means they could represent 6% of the total provincial upstream methane inventory and as an aggregate methane source could be 5× more significant than abandoned wells. Notably, these heaters are seasonal sources whose emissions would be missed in measurement campaigns occurring solely in summer months. However, additional measurements from a small number of heat medium burners demonstrate that, where feasible, methane emissions can be reduced by approximately 425× by replacing catalytic heaters with centralized heat systems.
Successful reduction of oil and gas sector methane emissions to meet near-zero intensity targets requires the identification and mitigation of all possible sources. One potentially important source is catalytic heaters, which have largely escaped attention in regulatory and mitigation efforts despite being ubiquitous at upstream production sites in cold climate regions. This study reports direct in situ measurements of the exhaust streams of 38 natural gas-fired catalytic heaters at upstream production sites in British Columbia, Canada. All heaters in the sample showed consistently poor methane conversion with mean destruction efficiencies of 61 ± 5% while releasing 235 [+31/-28] g of methane per cubic meter of fuel. Although individual units are generally small methane sources (mean of 0.28 ± 0.04 kg/h), their prevalence means they could represent 6% of the total provincial upstream methane inventory and as an aggregate methane source could be 5× more significant than abandoned wells. Notably, these heaters are seasonal sources whose emissions would be missed in measurement campaigns occurring solely in summer months. However, additional measurements from a small number of heat medium burners demonstrate that, where feasible, methane emissions can be reduced by approximately 425× by replacing catalytic heaters with centralized heat systems.Successful reduction of oil and gas sector methane emissions to meet near-zero intensity targets requires the identification and mitigation of all possible sources. One potentially important source is catalytic heaters, which have largely escaped attention in regulatory and mitigation efforts despite being ubiquitous at upstream production sites in cold climate regions. This study reports direct in situ measurements of the exhaust streams of 38 natural gas-fired catalytic heaters at upstream production sites in British Columbia, Canada. All heaters in the sample showed consistently poor methane conversion with mean destruction efficiencies of 61 ± 5% while releasing 235 [+31/-28] g of methane per cubic meter of fuel. Although individual units are generally small methane sources (mean of 0.28 ± 0.04 kg/h), their prevalence means they could represent 6% of the total provincial upstream methane inventory and as an aggregate methane source could be 5× more significant than abandoned wells. Notably, these heaters are seasonal sources whose emissions would be missed in measurement campaigns occurring solely in summer months. However, additional measurements from a small number of heat medium burners demonstrate that, where feasible, methane emissions can be reduced by approximately 425× by replacing catalytic heaters with centralized heat systems.
Author Festa-Bianchet, Simon A.
Tyner, David R.
Johnson, Matthew R.
Mohammadikharkeshi, Milad
AuthorAffiliation Energy & Emissions Research Laboratory, Department of Mechanical and Aerospace Engineering
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Cites_doi 10.1021/acs.est.2c07318
10.1021/es5040156
10.1016/0378-3820(94)00091-7
10.1126/science.1247045
10.1080/00102200108907844
10.1021/acs.est.0c04265
10.1038/s43247-023-00769-7
10.1021/acs.est.0c00516
10.1126/science.abq0385
10.1021/acs.estlett.9b00158
10.1016/j.aeaoa.2022.100193
10.1021/acs.est.6b05183
10.1021/ie502914k
10.1021/acs.est.0c05492
10.1016/j.joei.2022.07.005
10.1021/es504016r
10.1016/j.coche.2016.08.014
10.1525/elementa.2022.00121
10.3390/environments7040025
10.1016/S0010-2180(00)00151-6
10.1021/acs.est.6b00705
10.1021/acs.est.8b01665
10.1016/j.cattod.2008.11.015
10.1021/acs.estlett.2c00380
10.4236/jep.2017.84029
10.1038/ncomms14012
10.1525/elementa.2023.00053
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Keywords methane slip
incomplete combustion
catalytic heater
field measurements
upstream oil and gas
emissions
destruction efficiency
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References ref6/cit6
ref36/cit36
ref3/cit3
ref27/cit27
ref18/cit18
CAPP A National Inventory of Greenhouse Gas (GHG) (ref35/cit35) 2004
ref11/cit11
ref25/cit25
ref16/cit16
ref29/cit29
ref32/cit32
ref23/cit23
ref39/cit39
ref14/cit14
ref8/cit8
ref5/cit5
ref31/cit31
ref2/cit2
ref43/cit43
ref34/cit34
ref37/cit37
ref28/cit28
ref40/cit40
ref20/cit20
ref17/cit17
ref10/cit10
ref26/cit26
ref19/cit19
ref21/cit21
ref12/cit12
ref15/cit15
ref42/cit42
ref41/cit41
ref22/cit22
ref13/cit13
ref4/cit4
ref1/cit1
ref24/cit24
ref38/cit38
Hendler A. (ref9/cit9) 2009
Government of Canada (ref33/cit33) 2023; 157
ref44/cit44
ref7/cit7
Tucholski D. R. (ref30/cit30) 2003
References_xml – ident: ref43/cit43
– ident: ref2/cit2
– ident: ref21/cit21
  doi: 10.1021/acs.est.2c07318
– ident: ref31/cit31
– ident: ref6/cit6
  doi: 10.1021/es5040156
– ident: ref37/cit37
– volume-title: VOC Emissions from Oil and Condensate Storage Tanks
  year: 2009
  ident: ref9/cit9
  contributor:
    fullname: Hendler A.
– volume-title: Criteria Air Contaminant (CAC) and Hydrogen Sulphide (H2S) Emissions by the Upstream Oil and Gas Industry: Vol. 3, Methodology for Greenhouse Gases
  year: 2004
  ident: ref35/cit35
  contributor:
    fullname: CAPP A National Inventory of Greenhouse Gas (GHG)
– ident: ref4/cit4
– ident: ref38/cit38
  doi: 10.1016/0378-3820(94)00091-7
– ident: ref17/cit17
  doi: 10.1126/science.1247045
– ident: ref27/cit27
  doi: 10.1080/00102200108907844
– ident: ref44/cit44
– ident: ref40/cit40
  doi: 10.1021/acs.est.0c04265
– ident: ref28/cit28
  doi: 10.1038/s43247-023-00769-7
– ident: ref20/cit20
  doi: 10.1021/acs.est.0c00516
– ident: ref26/cit26
  doi: 10.1126/science.abq0385
– ident: ref5/cit5
  doi: 10.1021/acs.estlett.9b00158
– ident: ref12/cit12
  doi: 10.1016/j.aeaoa.2022.100193
– volume: 157
  start-page: 50
  year: 2023
  ident: ref33/cit33
  publication-title: Canada Gaz.
  contributor:
    fullname: Government of Canada
– ident: ref1/cit1
– ident: ref34/cit34
– ident: ref23/cit23
  doi: 10.1021/acs.est.6b05183
– ident: ref36/cit36
  doi: 10.1021/ie502914k
– ident: ref3/cit3
– ident: ref39/cit39
– ident: ref19/cit19
  doi: 10.1021/acs.est.0c05492
– ident: ref22/cit22
  doi: 10.1016/j.joei.2022.07.005
– ident: ref29/cit29
– ident: ref14/cit14
  doi: 10.1021/es504016r
– ident: ref24/cit24
  doi: 10.1016/j.coche.2016.08.014
– ident: ref16/cit16
  doi: 10.1525/elementa.2022.00121
– ident: ref13/cit13
  doi: 10.3390/environments7040025
– ident: ref25/cit25
  doi: 10.1016/S0010-2180(00)00151-6
– volume-title: CO Emissions From a Portable Propane Catalytic Heater
  year: 2003
  ident: ref30/cit30
  contributor:
    fullname: Tucholski D. R.
– ident: ref11/cit11
  doi: 10.1021/acs.est.6b00705
– ident: ref8/cit8
  doi: 10.1021/acs.est.8b01665
– ident: ref32/cit32
  doi: 10.1016/j.cattod.2008.11.015
– ident: ref15/cit15
  doi: 10.1021/acs.estlett.2c00380
– ident: ref7/cit7
  doi: 10.4236/jep.2017.84029
– ident: ref41/cit41
– ident: ref42/cit42
– ident: ref18/cit18
  doi: 10.1038/ncomms14012
– ident: ref10/cit10
  doi: 10.1525/elementa.2023.00053
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Snippet Successful reduction of oil and gas sector methane emissions to meet near-zero intensity targets requires the identification and mitigation of all possible...
Successful reduction of oil and gas sector methane emissions to meet near-zero intensity targets requires the identification and mitigation of all possible...
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SubjectTerms Energy and Climate
Title Catalytic Heaters at Oil and Gas Sites May be a Significant yet Overlooked Seasonal Source of Methane Emissions
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