Fano-type Effect in Hydrogen-Terminated Pure Nanodiamond
Two novel properties, unique for semiconductors, a negative electron affinity and a high p-type surface electrical conductivity, were discovered in diamond at the end of the last century. Both properties appear when the diamond surface is hydrogenated. A natural question arises: is the influence of...
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Published in | Nano letters Vol. 22; no. 7; pp. 2589 - 2594 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
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American Chemical Society
13.04.2022
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Abstract | Two novel properties, unique for semiconductors, a negative electron affinity and a high p-type surface electrical conductivity, were discovered in diamond at the end of the last century. Both properties appear when the diamond surface is hydrogenated. A natural question arises: is the influence of the surface hydrogen on diamond limited only to the electrical properties? Here, for the first time to our knowledge, we observe a transparency peak at 1328 cm–1 in the infrared absorption of hydrogen-terminated pure (undoped) nanodiamonds. This new optical property is ascribed to Fano-type destructive interference between zone-center optical phonons and free carriers (holes) appearing in the near-surface layer of hydrogenated nanodiamond. This work opens the way to explore the physics of electron–phonon coupling in undoped semiconductors and promises the application of H-terminated nanodiamonds as a new optical material with induced transparency in the infrared optical range. |
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AbstractList | Two novel properties, unique for semiconductors, a negative electron affinity and a high p-type surface electrical conductivity, were discovered in diamond at the end of the last century. Both properties appear when the diamond surface is hydrogenated. A natural question arises: is the influence of the surface hydrogen on diamond limited only to the electrical properties? Here, for the first time to our knowledge, we observe a transparency peak at 1328 cm–1 in the infrared absorption of hydrogen-terminated pure (undoped) nanodiamonds. This new optical property is ascribed to Fano-type destructive interference between zone-center optical phonons and free carriers (holes) appearing in the near-surface layer of hydrogenated nanodiamond. This work opens the way to explore the physics of electron–phonon coupling in undoped semiconductors and promises the application of H-terminated nanodiamonds as a new optical material with induced transparency in the infrared optical range. Two novel properties, unique for semiconductors, a negative electron affinity and a high p-type surface electrical conductivity, were discovered in diamond at the end of the last century. Both properties appear when the diamond surface is hydrogenated. A natural question arises: is the influence of the surface hydrogen on diamond limited only to the electrical properties? Here, for the first time to our knowledge, we observe a transparency peak at 1328 cm in the infrared absorption of hydrogen-terminated pure (undoped) nanodiamonds. This new optical property is ascribed to Fano-type destructive interference between zone-center optical phonons and free carriers (holes) appearing in the near-surface layer of hydrogenated nanodiamond. This work opens the way to explore the physics of electron-phonon coupling in undoped semiconductors and promises the application of H-terminated nanodiamonds as a new optical material with induced transparency in the infrared optical range. |
Author | Pasternak, Dmitrii G Nikolaev, Alexander V Kudryavtsev, Oleg S Vlasov, Igor I Filonenko, Vladimir P Bagramov, Rustem H Romshin, Alexey M Satanin, Arkady M Lebedev, Oleg I Shiryaev, Andrey A |
AuthorAffiliation | Skobeltsyn Institute of Nuclear Physics Lomonosov Moscow State University Moscow Institute of Physics and Technology National Research University Higher School of Economics Frumkin Institute of Physical Chemistry and Electrochemistry RAS School of Electronics, Photonics and Molecular Physics Prokhorov General Physics Institute of the Russian Academy of Sciences Dukhov All-Russia Research Institute of Automatics |
AuthorAffiliation_xml | – name: Skobeltsyn Institute of Nuclear Physics Lomonosov Moscow State University – name: Dukhov All-Russia Research Institute of Automatics – name: Moscow Institute of Physics and Technology – name: National Research University Higher School of Economics – name: Prokhorov General Physics Institute of the Russian Academy of Sciences – name: School of Electronics, Photonics and Molecular Physics – name: Frumkin Institute of Physical Chemistry and Electrochemistry RAS |
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Keywords | nanodiamond Fano interference IR absorption Raman scattering transfer doping |
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Title | Fano-type Effect in Hydrogen-Terminated Pure Nanodiamond |
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