[1]Ferrocenophanes, [1]Chromarenophanes, and [1]Vanadarenophanes with Aluminium and Gallium in Bridging Positions
Aluminum- and gallium-bridged [1]ferrocenophanes (4a, 4b), [1]chromarenophanes (5a, 5b), and [1]vanadarenophanes (6a, 6b) were synthesized from the respective dilithiated sandwich compounds with element dichlorides (Me2Ntsi)ECl2 [E = Al, Ga; Me2Ntsi = C(SiMe3)2(SiMe2NMe2)] in moderate to high isolat...
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Published in | Organometallics Vol. 25; no. 24; pp. 5817 - 5823 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
WASHINGTON
American Chemical Society
20.11.2006
Amer Chemical Soc |
Subjects | |
Online Access | Get full text |
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Summary: | Aluminum- and gallium-bridged [1]ferrocenophanes (4a, 4b), [1]chromarenophanes (5a, 5b), and [1]vanadarenophanes (6a, 6b) were synthesized from the respective dilithiated sandwich compounds with element dichlorides (Me2Ntsi)ECl2 [E = Al, Ga; Me2Ntsi = C(SiMe3)2(SiMe2NMe2)] in moderate to high isolated yields (54−97%). The new intramolecularly stabilized aluminum compound (Me2NCH2tsi)AlCl2 (2a) was synthesized, but was proven to be unreactive with respect to [Fe(LiC5H4)2]·2/3TMEDA. The diamagnetic species 2a, 4a, 4b, 5a, and 5b were characterized by NMR spectroscopy (1H, 13C, 27Al), CHN elemental analysis, and mass spectrometry, whereas the paramagnetic compounds 6a and 6b were characterized by IR spectroscopy, CHN elemental analysis, and mass spectrometry. In addition, the molecular structures of compounds 2a, 4a, 4b, 5a, 5b, 6a, and 6b were determined by single-crystal X-ray analysis. All [1]cyclophanes are strained species, as revealed by the following tilt angles α [deg]: 14.33(14) (4a), 15.83(19) (4b), 11.81(9) (5a), 13.24(13) (5b), 14.65(14) (6a), and 15.63(14) (6b). |
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Bibliography: | istex:642FCB85CB643B53195C37C58CE5C2613CF05F0E ark:/67375/TPS-2DZPCRDV-1 |
ISSN: | 0276-7333 1520-6041 |
DOI: | 10.1021/om060736q |