Chemical Insights from EPR Spectra of Organometallic Radicals and Radical Ions
A review of applications of electron paramagnetic resonance (EPR) to organometallics is given, covering about 35 years of the authors' work. The review includes applications where the conclusions are mainly a picture of electronic structure, though often knowledge of the singly occupied molecul...
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| Published in | Organometallics Vol. 23; no. 2; pp. 154 - 162 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
American Chemical Society
19.01.2004
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| Online Access | Get full text |
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| Abstract | A review of applications of electron paramagnetic resonance (EPR) to organometallics is given, covering about 35 years of the authors' work. The review includes applications where the conclusions are mainly a picture of electronic structure, though often knowledge of the singly occupied molecular orbital (SOMO) has implications for molecular structure. Included in the review are discussions of addition of a second phosphite ligand to [Co{S2C2(CF3)2}P(OMe)3] and a unique example of electronic isomerism (summarized on the cover). |
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| AbstractList | A review of applications of electron paramagnetic resonance (EPR) to organometallics is given, covering about 35 years of the authors' work. The review includes applications where the conclusions are mainly a picture of electronic structure, though often knowledge of the singly occupied molecular orbital (SOMO) has implications for molecular structure. Included in the review are discussions of addition of a second phosphite ligand to [Co{S2C2(CF3)2}P(OMe)3] and a unique example of electronic isomerism (summarized on the cover). |
| Author | Rieger, Philip H Rieger, Anne L |
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| Cites_doi | 10.1021/om970251p 10.1021/ic50179a026 10.1021/ic00182a008 10.1021/ja00385a013 10.1021/ja00521a027 10.1039/f19898503513 10.1039/DT9960003503 10.1021/ic970088q 10.1039/dt9930003103 10.1039/dt9940002903 10.1021/om960374u |
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| Copyright | Copyright © 2004 American Chemical Society |
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| References_xml | – volume-title: Organometallic Radical Processes year: 1990 ident: om030565eb00002/om030565eb00002_1 contributor: fullname: Rieger P. – volume: 1 start-page: 410 year: 1963 ident: om030565eb00004/om030565eb00004_1 publication-title: Phys. Kondens. Mater. contributor: fullname: Kneubühl F. K. – volume: 16 start-page: 4369 year: 1997 ident: om030565eb00014/om030565eb00014_1 publication-title: Organometallics doi: 10.1021/om970251p contributor: fullname: Castellani M. P. – volume: 8 start-page: 95 year: 1987 ident: om030565eb00006/om030565eb00006_1 publication-title: Bull. Magn. Reson. contributor: fullname: DeGray J. A. – volume: 17 start-page: 126 year: 1978 ident: om030565eb00016/om030565eb00016_1 publication-title: Inorg. Chem. doi: 10.1021/ic50179a026 contributor: fullname: Thorn D. L. – volume: 23 start-page: 2019 year: 1984 ident: om030565eb00019/om030565eb00019_1 publication-title: J. Inorg. Chem. doi: 10.1021/ic00182a008 contributor: fullname: Casagrande L. V. – volume: 104 start-page: 5633 year: 1982 ident: om030565eb00017/om030565eb00017_1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00385a013 contributor: fullname: Arewgoda M. – volume: 22 start-page: 2019 year: 1987 ident: om030565eb00020/om030565eb00020_1 publication-title: J. Inorg. Chem. contributor: fullname: Casagrande L. V. – volume: 102 start-page: 156 year: 1980 ident: om030565eb00015/om030565eb00015_1 publication-title: J. Am, Chem. Soc. doi: 10.1021/ja00521a027 contributor: fullname: Peake B. M. – volume: 85 start-page: 3513 year: 1989 ident: om030565eb00012/om030565eb00012_1 publication-title: J. Chem. Soc., Faraday Trans. 1 doi: 10.1039/f19898503513 contributor: fullname: Pike R. D. – volume: 50 start-page: 485 year: 1982 ident: om030565eb00005/om030565eb00005_1 publication-title: J. Magn. Reson. contributor: fullname: In – start-page: 3503 year: 1996 ident: om030565eb00011/om030565eb00011_1 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/DT9960003503 contributor: fullname: Nochomovitz Y. D. – volume: 36 start-page: 3088 year: 1997 ident: om030565eb00018/om030565eb00018_1 publication-title: Inorg. Chem. doi: 10.1021/ic970088q contributor: fullname: Jones P. L. – start-page: 3103 year: 1993 ident: om030565eb00007/om030565eb00007_1 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/dt9930003103 contributor: fullname: Carriedo G. A. – start-page: 2903 year: 1994 ident: om030565eb00008/om030565eb00008_1 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/dt9940002903 contributor: fullname: Carpenter G. B. – volume: 15 start-page: 4791 year: 1996 ident: om030565eb00013/om030565eb00013_1 publication-title: Organometallics doi: 10.1021/om960374u contributor: fullname: Hammack D. J. – volume: 2458 start-page: 2459 year: 2001 ident: om030565eb00001/om030565eb00001_1 publication-title: J. Chem. Soc., Chem. Commun. contributor: fullname: Adams C. J. – volume: 30 start-page: 577 year: 1978 ident: om030565eb00003/om030565eb00003_1 publication-title: J. Magn. Reson. contributor: fullname: Morton J. R. |
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| Title | Chemical Insights from EPR Spectra of Organometallic Radicals and Radical Ions |
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