Synthesis of Lead-Free Perovskite Films by Combinatorial Evaporation: Fast Processes for Screening Different Precursor Combinations

We demonstrate an evaporation-based combinatorial approach for fast screening of precursor combinations for the synthesis of novel perovskite materials. Nine material combinations can be explored simultaneously, which enabled us to synthesize nine different lead-free perovskite compounds. The struct...

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Published inChemistry of materials Vol. 29; no. 23; pp. 9946 - 9953
Main Authors Wong, Man Kwong, Liu, Fangzhou, Kam, Chun Sing, Leung, Tik Lun, Tam, Ho Won, Djurišić, Aleksandra B, Popović, Jasminka, Li, Hangkong, Shih, Kaimin, Low, Kam-Hung, Chan, Wai Kin, Chen, Wei, He, Zhubing, Ng, Annie, Surya, Charles
Format Journal Article
LanguageEnglish
Published American Chemical Society 12.12.2017
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Abstract We demonstrate an evaporation-based combinatorial approach for fast screening of precursor combinations for the synthesis of novel perovskite materials. Nine material combinations can be explored simultaneously, which enabled us to synthesize nine different lead-free perovskite compounds. The structural properties (morphology, crystal structure) and optical properties (UV–vis absorption spectra, photoluminescence) of the prepared materials were investigated. Among these materials, several Sn-based and Pd-based perovskites exhibit strong absorption in the visible spectral range and thus may be of interest for photovoltaic applications. In addition, butyl ammonium tin iodide exhibits bright red emission, and it is of interest for potential light emitting applications.
AbstractList We demonstrate an evaporation-based combinatorial approach for fast screening of precursor combinations for the synthesis of novel perovskite materials. Nine material combinations can be explored simultaneously, which enabled us to synthesize nine different lead-free perovskite compounds. The structural properties (morphology, crystal structure) and optical properties (UV–vis absorption spectra, photoluminescence) of the prepared materials were investigated. Among these materials, several Sn-based and Pd-based perovskites exhibit strong absorption in the visible spectral range and thus may be of interest for photovoltaic applications. In addition, butyl ammonium tin iodide exhibits bright red emission, and it is of interest for potential light emitting applications.
Author Popović, Jasminka
Liu, Fangzhou
He, Zhubing
Shih, Kaimin
Leung, Tik Lun
Chen, Wei
Tam, Ho Won
Wong, Man Kwong
Ng, Annie
Surya, Charles
Chan, Wai Kin
Li, Hangkong
Djurišić, Aleksandra B
Kam, Chun Sing
Low, Kam-Hung
AuthorAffiliation Department of Chemistry
Department of Materials Science and Engineering, Shenzhen Key Laboratory of Full Spectral Solar Electricity Generation (FSSEG)
The Hong Kong Polytechnic University
Department of Electronic and Information Engineering
University of Hong Kong
Center of Excellence for Advanced Materials and Sensing Devices, Division for Materials Physics, Laboratory for Synthesis and Crystallography of Functional Materials
Nazarbayev University
of Hong Kong
Ruđer Bošković Institute
Department of Civil Engineering
School of Engineering
Department of Physics
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Cites_doi 10.1038/s41598-017-05317-w
10.1021/jz502547f
10.1038/nature18306
10.1039/C5TA03593G
10.1021/acs.jpcc.6b02175
10.1002/pssr.201600166
10.1016/0022-0248(78)90170-7
10.1021/acs.nanolett.5b04981
10.1021/acs.jpcc.5b06436
10.1515/zna-1996-1212
10.1103/PhysRevB.93.144105
10.1016/j.poly.2009.02.033
10.1021/acs.chemmater.6b00433
10.1107/S0108270190012410
10.1021/jacs.6b13258
10.1107/S0567740877006761
10.1021/acs.jpclett.7b01302
10.1088/0957-4484/17/2/027
10.1063/1.1677469
10.1080/14686996.2017.1314172
10.1002/ejic.201601499
10.1039/C5SC00961H
10.1016/j.synthmet.2015.07.013
10.1002/9780470166499.ch1
10.1039/c001929a
10.1021/ic402535u
10.1007/s00706-017-1933-9
10.1002/anie.201511792
10.1021/acs.inorgchem.5b01896
10.1107/S2052520616003954
10.1107/S0567739476001551
10.1016/j.solmat.2016.09.022
10.1016/0025-5408(88)90019-0
10.1002/adfm.201600958
10.1021/acs.jpcc.5b11845
10.1039/C5SC04845A
10.1016/0038-1098(78)90152-7
10.1631/jzus.A0820736
10.1107/S0108270188003634
10.1103/PhysRevB.4.2213
10.1007/s00339-006-3733-7
10.1002/adma.201605448
10.1021/cm9505097
10.1002/chem.201503680
10.1021/ja508464w
10.1039/C5RA21291J
10.1016/0375-9601(77)90287-0
10.1007/s00339-004-3102-3
10.1103/PhysRevB.61.1026
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References ref9/cit9
ref45/cit45
ref3/cit3
ref27/cit27
ref16/cit16
ref23/cit23
ref8/cit8
ref31/cit31
ref2/cit2
ref34/cit34
ref37/cit37
ref20/cit20
ref48/cit48
ref17/cit17
ref10/cit10
ref35/cit35
ref19/cit19
ref21/cit21
ref42/cit42
ref46/cit46
ref49/cit49
ref13/cit13
ref24/cit24
ref38/cit38
ref50/cit50
ref6/cit6
ref36/cit36
ref18/cit18
ref11/cit11
ref25/cit25
ref29/cit29
ref32/cit32
ref39/cit39
ref14/cit14
ref5/cit5
ref43/cit43
ref28/cit28
ref40/cit40
ref26/cit26
ref12/cit12
ref15/cit15
ref41/cit41
ref22/cit22
ref33/cit33
ref4/cit4
ref30/cit30
ref47/cit47
ref1/cit1
ref44/cit44
ref7/cit7
References_xml – ident: ref11/cit11
  doi: 10.1038/s41598-017-05317-w
– ident: ref1/cit1
  doi: 10.1021/jz502547f
– ident: ref49/cit49
  doi: 10.1038/nature18306
– ident: ref26/cit26
  doi: 10.1039/C5TA03593G
– ident: ref48/cit48
  doi: 10.1021/acs.jpcc.6b02175
– ident: ref44/cit44
  doi: 10.1002/pssr.201600166
– ident: ref20/cit20
  doi: 10.1016/0022-0248(78)90170-7
– ident: ref27/cit27
  doi: 10.1021/acs.nanolett.5b04981
– ident: ref31/cit31
  doi: 10.1021/acs.jpcc.5b06436
– ident: ref37/cit37
  doi: 10.1515/zna-1996-1212
– ident: ref32/cit32
  doi: 10.1103/PhysRevB.93.144105
– ident: ref39/cit39
  doi: 10.1016/j.poly.2009.02.033
– ident: ref46/cit46
  doi: 10.1021/acs.chemmater.6b00433
– ident: ref10/cit10
  doi: 10.1107/S0108270190012410
– ident: ref43/cit43
  doi: 10.1021/jacs.6b13258
– ident: ref42/cit42
  doi: 10.1038/s41598-017-05317-w
– ident: ref9/cit9
  doi: 10.1107/S0567740877006761
– ident: ref29/cit29
  doi: 10.1021/acs.jpclett.7b01302
– ident: ref18/cit18
  doi: 10.1088/0957-4484/17/2/027
– ident: ref38/cit38
  doi: 10.1063/1.1677469
– ident: ref28/cit28
  doi: 10.1080/14686996.2017.1314172
– ident: ref40/cit40
  doi: 10.1002/ejic.201601499
– ident: ref4/cit4
  doi: 10.1039/C5SC00961H
– ident: ref23/cit23
  doi: 10.1016/j.synthmet.2015.07.013
– ident: ref7/cit7
  doi: 10.1002/9780470166499.ch1
– ident: ref25/cit25
  doi: 10.1039/c001929a
– ident: ref21/cit21
  doi: 10.1021/ic402535u
– ident: ref3/cit3
  doi: 10.1007/s00706-017-1933-9
– ident: ref15/cit15
  doi: 10.1002/anie.201511792
– ident: ref22/cit22
  doi: 10.1021/acs.inorgchem.5b01896
– ident: ref34/cit34
  doi: 10.1107/S2052520616003954
– ident: ref35/cit35
  doi: 10.1107/S0567739476001551
– ident: ref45/cit45
  doi: 10.1016/j.solmat.2016.09.022
– ident: ref33/cit33
  doi: 10.1016/0025-5408(88)90019-0
– ident: ref30/cit30
  doi: 10.1002/adfm.201600958
– ident: ref2/cit2
  doi: 10.1021/acs.jpcc.5b11845
– ident: ref5/cit5
  doi: 10.1039/C5SC04845A
– ident: ref12/cit12
  doi: 10.1016/0038-1098(78)90152-7
– ident: ref24/cit24
  doi: 10.1631/jzus.A0820736
– ident: ref36/cit36
  doi: 10.1107/S0108270188003634
– ident: ref13/cit13
  doi: 10.1103/PhysRevB.4.2213
– ident: ref16/cit16
  doi: 10.1007/s00339-006-3733-7
– ident: ref50/cit50
  doi: 10.1002/adma.201605448
– ident: ref6/cit6
  doi: 10.1021/cm9505097
– ident: ref19/cit19
  doi: 10.1002/chem.201503680
– ident: ref47/cit47
  doi: 10.1021/ja508464w
– ident: ref8/cit8
  doi: 10.1039/C5RA21291J
– ident: ref14/cit14
  doi: 10.1016/0375-9601(77)90287-0
– ident: ref17/cit17
  doi: 10.1007/s00339-004-3102-3
– ident: ref41/cit41
  doi: 10.1103/PhysRevB.61.1026
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Title Synthesis of Lead-Free Perovskite Films by Combinatorial Evaporation: Fast Processes for Screening Different Precursor Combinations
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