Phosphorolytic Cleavage of Phosphate and Phosphonoformate Diesters by Cetyltrimethylammonium Iodosobenzoate

Micellar cetyltrimethylammonium iodosobenzoate (4) cleaves P−O ester linkages of bis(p-nitrophenyl) phosphate (3), methoxycarbonyl phenyl phosphonoformate (6), and hexyloxycarbonyl phenyl phosphonoformate (7). Kinetic advantages of several orders of magnitude are obtained relative to the unassisted...

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Bibliographic Details
Published inLangmuir Vol. 18; no. 7; pp. 2468 - 2470
Main Authors Moss, Robert A, Vijayaraghavan, Saketh, Kanamathareddy, Suseela
Format Journal Article
LanguageEnglish
Published American Chemical Society 02.04.2002
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Summary:Micellar cetyltrimethylammonium iodosobenzoate (4) cleaves P−O ester linkages of bis(p-nitrophenyl) phosphate (3), methoxycarbonyl phenyl phosphonoformate (6), and hexyloxycarbonyl phenyl phosphonoformate (7). Kinetic advantages of several orders of magnitude are obtained relative to the unassisted hydrolyses.
Bibliography:istex:84DAF305286C74183B12A923D7BBB085CE760878
ark:/67375/TPS-NXR3Q2Z8-7
ISSN:0743-7463
1520-5827
DOI:10.1021/la0116488