Bimetallocyclophanes Formed by the π−π Stacking Interaction Approach and Fluorescent Chemosensing Behavior

A new high-yielding synthetic approach for the preparation of bimetallic cyclophane has been achieved through the π−π stacking interaction approach from the flexible ligand 1 and group 11 metal M+. The Cu complex 2a can act as a fluorescent chemosensor for benzenediacetonitrile.

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Bibliographic Details
Published inOrganometallics Vol. 23; no. 4; pp. 632 - 634
Main Authors Xu, Feng-Bo, Li, Qing-Shan, Zeng, Xian-Shun, Leng, Xue-Bing, Zhang, Zheng-Zhi
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 16.02.2004
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
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Summary:A new high-yielding synthetic approach for the preparation of bimetallic cyclophane has been achieved through the π−π stacking interaction approach from the flexible ligand 1 and group 11 metal M+. The Cu complex 2a can act as a fluorescent chemosensor for benzenediacetonitrile.
Bibliography:istex:B9569679AFA22A029380D702BCB831E339BAAB8A
ark:/67375/TPS-ZNZ4FQLD-X
ISSN:0276-7333
1520-6041
DOI:10.1021/om0340037