Light-Emitting Diodes with Manganese Halide Tetrahedron Embedded in Anti-Perovskites

The formability of antiperovskite [MX4]­XA3-type (A­(I) = alkali metals; M­(II) = transition metals; X = Cl, Br, I) can be predicted by building the analysis theory. To validate the prediction model, a series of cesium–manganese antiperovskite single crystals with different halogen mixing ratios wer...

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Published inACS energy letters Vol. 6; no. 5; pp. 1901 - 1911
Main Authors Yan, Siyu, Tang, Kaixin, Lin, Yuejian, Ren, Yuanhang, Tian, Wanli, Chen, Hua, Lin, Tingting, Qiu, Longzhen, Pan, Xiaoyong, Wang, Weizhi
Format Journal Article
LanguageEnglish
Published American Chemical Society 14.05.2021
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Abstract The formability of antiperovskite [MX4]­XA3-type (A­(I) = alkali metals; M­(II) = transition metals; X = Cl, Br, I) can be predicted by building the analysis theory. To validate the prediction model, a series of cesium–manganese antiperovskite single crystals with different halogen mixing ratios were synthesized, which not only have [MX4]­XA3-type structures but also are ideal luminescent materials. As the most pure green emission fluorescent antiperovskite, [MnCl2Br2]­BrCs3 shows 520 nm emission with the high photoluminescence quantum yield (93.5%) at room temperature and ultrastable luminescent color from 77 to 523 K due to the strict confinement of high-density luminescent centers. By fabricating the perovskite film with the double-source thermal evaporation method, the first all-inorganic cesium–manganese halide antiperovskite light-emitting diode is reported, with maximum external quantum efficiency up to 12.5%, maximum luminance up to 3990 cd m–2, and half-life of 756 min operated at 5.0 V.
AbstractList The formability of antiperovskite [MX4]­XA3-type (A­(I) = alkali metals; M­(II) = transition metals; X = Cl, Br, I) can be predicted by building the analysis theory. To validate the prediction model, a series of cesium–manganese antiperovskite single crystals with different halogen mixing ratios were synthesized, which not only have [MX4]­XA3-type structures but also are ideal luminescent materials. As the most pure green emission fluorescent antiperovskite, [MnCl2Br2]­BrCs3 shows 520 nm emission with the high photoluminescence quantum yield (93.5%) at room temperature and ultrastable luminescent color from 77 to 523 K due to the strict confinement of high-density luminescent centers. By fabricating the perovskite film with the double-source thermal evaporation method, the first all-inorganic cesium–manganese halide antiperovskite light-emitting diode is reported, with maximum external quantum efficiency up to 12.5%, maximum luminance up to 3990 cd m–2, and half-life of 756 min operated at 5.0 V.
Author Lin, Yuejian
Yan, Siyu
Tian, Wanli
Wang, Weizhi
Chen, Hua
Pan, Xiaoyong
Tang, Kaixin
Ren, Yuanhang
Lin, Tingting
Qiu, Longzhen
AuthorAffiliation National Engineering Lab of Special Display Technology, State Key Lab of Advanced Display Technology, Academy of Optoelectronic Technology
Fudan University
ASTAR (Agency for Science, Technology and Research)
Advanced Materials Laboratory, Department of Chemistry
School of Material & Science Engineering
Institute of Materials Research and Engineering
State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Polymers and Polymer Composite Materials, Department of Macromolecular Science
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  email: weizhiwang@fudan.edu.cn
  organization: State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Polymers and Polymer Composite Materials, Department of Macromolecular Science
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Snippet The formability of antiperovskite [MX4]­XA3-type (A­(I) = alkali metals; M­(II) = transition metals; X = Cl, Br, I) can be predicted by building the analysis...
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