Experimental Gas-Phase and in Silico Investigation of β‑Methyl Elimination from Cationic Palladium Alkyl Species
Herein we disclose experimental and in silico gas-phase studies of β-methyl and β-hydride elimination from cationic diphosphine palladium(II) neopentyl and isobutyl complexes. In particular, we have determined activation barriers for these transformations through mass-spectrometric threshold collis...
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Published in | Organometallics Vol. 34; no. 7; pp. 1301 - 1306 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
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American Chemical Society
13.04.2015
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Abstract | Herein we disclose experimental and in silico gas-phase studies of β-methyl and β-hydride elimination from cationic diphosphine palladium(II) neopentyl and isobutyl complexes. In particular, we have determined activation barriers for these transformations through mass-spectrometric threshold collision-induced dissociation (T-CID) studies. These systems can undergo at least one of the several competitive processes: (1) β-methyl elimination, (2) Pd–C bond homolysis, or (3) β-hydride elimination. We also confirm that qualitative trends in the branching ratios between these processes depend on the diphosphine bite angle, whereas electronic modifications of phosphine electron-donating ability have no significant effect on the barriers for β-methyl elimination within the experimental error. The full reaction manifold has been investigated with density functional theory (DFT) and affords a valuable experimental benchmark for types of organometallic transformations described herein. |
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AbstractList | Herein we disclose experimental and in silico gas-phase studies of β-methyl and β-hydride elimination from cationic diphosphine palladium(II) neopentyl and isobutyl complexes. In particular, we have determined activation barriers for these transformations through mass-spectrometric threshold collision-induced dissociation (T-CID) studies. These systems can undergo at least one of the several competitive processes: (1) β-methyl elimination, (2) Pd–C bond homolysis, or (3) β-hydride elimination. We also confirm that qualitative trends in the branching ratios between these processes depend on the diphosphine bite angle, whereas electronic modifications of phosphine electron-donating ability have no significant effect on the barriers for β-methyl elimination within the experimental error. The full reaction manifold has been investigated with density functional theory (DFT) and affords a valuable experimental benchmark for types of organometallic transformations described herein. |
Author | Chen, Peter Kobylianskii, Ilia J Zhugralin, Adil R |
AuthorAffiliation | ETH Zürich Laboratorium für Organische Chemie |
AuthorAffiliation_xml | – name: ETH Zürich – name: Laboratorium für Organische Chemie |
Author_xml | – sequence: 1 givenname: Adil R surname: Zhugralin fullname: Zhugralin, Adil R – sequence: 2 givenname: Ilia J surname: Kobylianskii fullname: Kobylianskii, Ilia J – sequence: 3 givenname: Peter surname: Chen fullname: Chen, Peter email: peter.chen@org.chem.ethz.ch |
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Cites_doi | 10.1021/ja005558l 10.1002/anie.200500799 10.1021/om00021a021 10.1021/om500478y 10.1021/om960089a 10.1021/ja078149z 10.1021/ja4084495 10.1021/ja00338a019 10.1021/jp072092l 10.1002/(SICI)1521-3773(19990401)38:7<870::AID-ANIE870>3.0.CO;2-3 10.1002/anie.200906480 10.1002/chem.200902929 10.1021/om010489k 10.1039/B702940N 10.1021/ja512372a 10.1002/cphc.201000063 10.1039/B308864M 10.1021/jo302592g 10.1021/ja065390p 10.1021/cr9903048 10.1002/ange.19941062328 10.1002/jcc.1056 10.1002/1521-3773(20010202)40:3<534::AID-ANIE534>3.0.CO;2-C 10.1002/1521-3773(20011001)40:19<3641::AID-ANIE3641>3.0.CO;2-9 10.1021/ol049833a 10.1063/1.3382344 10.1002/jcc.21759 10.1021/ja110405q 10.1021/ja035293l 10.1021/ja00003a017 10.1021/om00002a053 10.1039/C0CC02566F 10.1021/jp203740n 10.1002/anie.200500368 10.1021/ar700133y 10.1021/ja058550q 10.1021/ja9601043 10.1021/jp0539223 10.1021/ja972131e 10.1021/ja802060t 10.1063/1.441385 10.1063/1.4754130 10.1021/jo00979a024 10.1021/om1000875 10.1002/ejoc.201101616 10.1021/ja406676p |
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References | Fonseca Guerra C. (ref14/cit14c) 1998; 99 Matsuda T. (ref10/cit10a) 2005; 44 Tjelta B. L. (ref8/cit8c) 1996; 118 Catellani M. (ref9/cit9f) 1994; 106 Grimme S. (ref21/cit21b) 2011; 32 Park Y. J. (ref1/cit1c) 2008; 41 Jun C.-H. (ref1/cit1e) 2004; 33 Fedorov A. (ref15/cit15e) 2008; 130 ref20/cit20 Cámpora J. (ref9/cit9c) 2001; 40 Satoh T. (ref2/cit2) 2005; 14 Torker S. (ref15/cit15f) 2008; 130 Horton A. D. (ref9/cit9d) 1996; 15 Ruhland K. (ref1/cit1a) 2012; 14 Nishimura T. (ref7/cit7b) 2000; 122 Klimeš J. (ref19/cit19) 2012; 137 Kobylianskii I. J. (ref15/cit15a) 2013; 135 Frisch M. J. (ref13/cit13) 2009 Moret M. E. (ref15/cit15c) 2010; 49 Schultz N. E. (ref18/cit18) 2005; 109 Narancic S. (ref12/cit12) 2007; 111 Cornehl H. H. (ref8/cit8d) 1995; 14 Tyo E. C. (ref8/cit8a) 2011; 115 Grimme S. (ref21/cit21a) 2010; 132 Zhao P. (ref9/cit9b) 2006; 128 Tolbert M. A. (ref8/cit8f) 1984; 106 Chesnavich W. J. (ref17/cit17) 1981; 74 Bour J. R. (ref9/cit9a) 2013; 78 Nicolaou K. C. (ref5/cit5) 2005; 44 Heck R. F. (ref3/cit3a) 1972; 37 Murakami M. (ref1/cit1b) 2011; 47 Couzijn E. P. A. (ref11/cit11) 2010; 16 Rybtchinski B. (ref1/cit1f) 1999; 38 Mecking S. (ref4/cit4) 2001; 40 Zocher E. (ref15/cit15g) 2007; 129 Tobisu M. (ref1/cit1d) 2008; 37 Couzijn E. P. A. (ref16/cit16a) 2014; 33 Rijs N. J. (ref8/cit8b) 2010; 29 Serra D. (ref15/cit15b) 2011; 133 Velde G. (ref14/cit14b) 2001; 22 Beletskaya I. P. (ref3/cit3b) 2000; 100 ref14/cit14a Matsuda T. (ref10/cit10b) 2004; 6 Batiste L. (ref16/cit16b) 2014; 136 Huang Y. (ref8/cit8e) 1991; 113 Ledford J. (ref6/cit6a) 2001; 20 McNeill K. (ref6/cit6b) 1997; 119 Matsumura S. (ref7/cit7a) 2003; 125 Fedorov A. (ref15/cit15d) 2010; 11 Portnoy M. (ref9/cit9e) 1994; 13 |
References_xml | – volume: 122 start-page: 12049 year: 2000 ident: ref7/cit7b publication-title: J. Am. Chem. Soc. doi: 10.1021/ja005558l contributor: fullname: Nishimura T. – volume: 44 start-page: 4608 year: 2005 ident: ref10/cit10a publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200500799 contributor: fullname: Matsuda T. – volume: 13 start-page: 3465 year: 1994 ident: ref9/cit9e publication-title: Organometallics doi: 10.1021/om00021a021 contributor: fullname: Portnoy M. – volume: 33 start-page: 2889 year: 2014 ident: ref16/cit16a publication-title: Organometallics doi: 10.1021/om500478y contributor: fullname: Couzijn E. P. A. – volume: 15 start-page: 2675 year: 1996 ident: ref9/cit9d publication-title: Organometallics doi: 10.1021/om960089a contributor: fullname: Horton A. D. – volume: 130 start-page: 4808 year: 2008 ident: ref15/cit15f publication-title: J. Am. Chem. Soc. doi: 10.1021/ja078149z contributor: fullname: Torker S. – volume: 136 start-page: 9296 year: 2014 ident: ref16/cit16b publication-title: J. Am. Chem. Soc. doi: 10.1021/ja4084495 contributor: fullname: Batiste L. – volume: 106 start-page: 8117 year: 1984 ident: ref8/cit8f publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00338a019 contributor: fullname: Tolbert M. A. – volume: 111 start-page: 7006 year: 2007 ident: ref12/cit12 publication-title: J. Phys. Chem. A doi: 10.1021/jp072092l contributor: fullname: Narancic S. – volume: 38 start-page: 870 year: 1999 ident: ref1/cit1f publication-title: Angew. Chem., Int. Ed. doi: 10.1002/(SICI)1521-3773(19990401)38:7<870::AID-ANIE870>3.0.CO;2-3 contributor: fullname: Rybtchinski B. – volume: 99 start-page: 391 year: 1998 ident: ref14/cit14c publication-title: Theor. Chem. Acc. contributor: fullname: Fonseca Guerra C. – volume: 49 start-page: 2873 year: 2010 ident: ref15/cit15c publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200906480 contributor: fullname: Moret M. E. – volume: 16 start-page: 5408 year: 2010 ident: ref11/cit11 publication-title: Chem.—Eur. J. doi: 10.1002/chem.200902929 contributor: fullname: Couzijn E. P. A. – ident: ref14/cit14a – volume: 20 start-page: 5266 year: 2001 ident: ref6/cit6a publication-title: Organometallics doi: 10.1021/om010489k contributor: fullname: Ledford J. – volume: 37 start-page: 300 year: 2008 ident: ref1/cit1d publication-title: Chem. Soc. Rev. doi: 10.1039/B702940N contributor: fullname: Tobisu M. – ident: ref20/cit20 doi: 10.1021/ja512372a – volume: 11 start-page: 1002 year: 2010 ident: ref15/cit15d publication-title: ChemPhysChem doi: 10.1002/cphc.201000063 contributor: fullname: Fedorov A. – volume: 33 start-page: 610 year: 2004 ident: ref1/cit1e publication-title: Chem. Soc. Rev. doi: 10.1039/B308864M contributor: fullname: Jun C.-H. – volume: 78 start-page: 1665 year: 2013 ident: ref9/cit9a publication-title: J. Org. Chem. doi: 10.1021/jo302592g contributor: fullname: Bour J. R. – volume: 129 start-page: 2476 year: 2007 ident: ref15/cit15g publication-title: J. Am. Chem. Soc. doi: 10.1021/ja065390p contributor: fullname: Zocher E. – volume: 100 start-page: 3009 year: 2000 ident: ref3/cit3b publication-title: Chem. Rev. doi: 10.1021/cr9903048 contributor: fullname: Beletskaya I. P. – volume: 106 start-page: 2259 year: 1994 ident: ref9/cit9f publication-title: Angew. Chem., Int. Ed. doi: 10.1002/ange.19941062328 contributor: fullname: Catellani M. – volume: 22 start-page: 931 year: 2001 ident: ref14/cit14b publication-title: Comput. Chem. doi: 10.1002/jcc.1056 contributor: fullname: Velde G. – volume: 40 start-page: 534 year: 2001 ident: ref4/cit4 publication-title: Angew. Chem., Int. Ed. doi: 10.1002/1521-3773(20010202)40:3<534::AID-ANIE534>3.0.CO;2-C contributor: fullname: Mecking S. – volume: 40 start-page: 3641 year: 2001 ident: ref9/cit9c publication-title: Angew. Chem., Int. Ed. doi: 10.1002/1521-3773(20011001)40:19<3641::AID-ANIE3641>3.0.CO;2-9 contributor: fullname: Cámpora J. – volume: 6 start-page: 1257 year: 2004 ident: ref10/cit10b publication-title: Org. Lett. doi: 10.1021/ol049833a contributor: fullname: Matsuda T. – volume: 132 start-page: 154104/1 year: 2010 ident: ref21/cit21a publication-title: J. Chem. Phys. doi: 10.1063/1.3382344 contributor: fullname: Grimme S. – volume: 32 start-page: 1456 year: 2011 ident: ref21/cit21b publication-title: J. Comput. Chem. doi: 10.1002/jcc.21759 contributor: fullname: Grimme S. – volume: 133 start-page: 8914 year: 2011 ident: ref15/cit15b publication-title: J. Am. Chem. Soc. doi: 10.1021/ja110405q contributor: fullname: Serra D. – volume: 125 start-page: 8862 year: 2003 ident: ref7/cit7a publication-title: J. Am. Chem. Soc. doi: 10.1021/ja035293l contributor: fullname: Matsumura S. – volume-title: Gaussian 09 year: 2009 ident: ref13/cit13 contributor: fullname: Frisch M. J. – volume: 113 start-page: 840 year: 1991 ident: ref8/cit8e publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00003a017 contributor: fullname: Huang Y. – volume: 14 start-page: 992 year: 1995 ident: ref8/cit8d publication-title: Organometallics doi: 10.1021/om00002a053 contributor: fullname: Cornehl H. H. – volume: 47 start-page: 1100 year: 2011 ident: ref1/cit1b publication-title: Chem. Commun. doi: 10.1039/C0CC02566F contributor: fullname: Murakami M. – volume: 14 start-page: 55 year: 2005 ident: ref2/cit2 publication-title: Top. Organomet. Chem. contributor: fullname: Satoh T. – volume: 115 start-page: 16797 year: 2011 ident: ref8/cit8a publication-title: J. Phys. Chem. C doi: 10.1021/jp203740n contributor: fullname: Tyo E. C. – volume: 44 start-page: 4442 year: 2005 ident: ref5/cit5 publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200500368 contributor: fullname: Nicolaou K. C. – volume: 41 start-page: 222 year: 2008 ident: ref1/cit1c publication-title: Acc. Chem. Res. doi: 10.1021/ar700133y contributor: fullname: Park Y. J. – volume: 128 start-page: 3124 year: 2006 ident: ref9/cit9b publication-title: J. Am. Chem. Soc. doi: 10.1021/ja058550q contributor: fullname: Zhao P. – volume: 118 start-page: 9652 year: 1996 ident: ref8/cit8c publication-title: J. Am. Chem. Soc. doi: 10.1021/ja9601043 contributor: fullname: Tjelta B. L. – volume: 109 start-page: 11127 year: 2005 ident: ref18/cit18 publication-title: J. Phys. Chem. A doi: 10.1021/jp0539223 contributor: fullname: Schultz N. E. – volume: 119 start-page: 11244 year: 1997 ident: ref6/cit6b publication-title: J. Am. Chem. Soc. doi: 10.1021/ja972131e contributor: fullname: McNeill K. – volume: 130 start-page: 8880 year: 2008 ident: ref15/cit15e publication-title: J. Am. Chem. Soc. doi: 10.1021/ja802060t contributor: fullname: Fedorov A. – volume: 74 start-page: 2228 year: 1981 ident: ref17/cit17 publication-title: J. Chem. Phys. doi: 10.1063/1.441385 contributor: fullname: Chesnavich W. J. – volume: 137 start-page: 120901/1 year: 2012 ident: ref19/cit19 publication-title: J. Chem. Phys. doi: 10.1063/1.4754130 contributor: fullname: Klimeš J. – volume: 37 start-page: 2320 year: 1972 ident: ref3/cit3a publication-title: J. Org. Chem. doi: 10.1021/jo00979a024 contributor: fullname: Heck R. F. – volume: 29 start-page: 2282 year: 2010 ident: ref8/cit8b publication-title: Organometallics doi: 10.1021/om1000875 contributor: fullname: Rijs N. J. – volume: 14 start-page: 2683 year: 2012 ident: ref1/cit1a publication-title: Eur. J. Org. Chem. doi: 10.1002/ejoc.201101616 contributor: fullname: Ruhland K. – volume: 135 start-page: 13648 year: 2013 ident: ref15/cit15a publication-title: J. Am. Chem. Soc. doi: 10.1021/ja406676p contributor: fullname: Kobylianskii I. J. |
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Title | Experimental Gas-Phase and in Silico Investigation of β‑Methyl Elimination from Cationic Palladium Alkyl Species |
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