Elastic Binder for High-Performance Sulfide-Based All-Solid-State Batteries
Sulfide-based all-solid-state batteries (ASSBs) offer enhanced safety and potentially high energy density. Particularly, an “anode-less” electrode containing metallic seeds that form a solid-solution with lithium was recently introduced to improve the cycle life of sulfide-based ASSB cells. However,...
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Published in | ACS energy letters Vol. 7; no. 4; pp. 1374 - 1382 |
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Main Authors | , , , , , , , , , , |
Format | Journal Article |
Language | English |
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American Chemical Society
08.04.2022
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Abstract | Sulfide-based all-solid-state batteries (ASSBs) offer enhanced safety and potentially high energy density. Particularly, an “anode-less” electrode containing metallic seeds that form a solid-solution with lithium was recently introduced to improve the cycle life of sulfide-based ASSB cells. However, this anode-less electrode is gradually destabilized because the metal particles undergo severe volume expansion during repeated cycling. Furthermore, the irreversibility of the electrode in early cycles impairs the energy density of the cell significantly. Herein, we introduce an elastic polymer known as “Spandex” as a binder for the silver–carbon composite. The soft and hard segments of this binder act synergistically in that the former engages in strong hydrogen bonding with the active material and the latter promotes elastic adjustment of the binder network. This binder design significantly improves the charge–discharge reversibility and long-term cyclability of the anode-less ASSB cell and provides insights into elastic binder systems for high-capacity ASSB anodes that undergo a large volume expansion. |
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AbstractList | Sulfide-based all-solid-state batteries (ASSBs) offer enhanced safety and potentially high energy density. Particularly, an “anode-less” electrode containing metallic seeds that form a solid-solution with lithium was recently introduced to improve the cycle life of sulfide-based ASSB cells. However, this anode-less electrode is gradually destabilized because the metal particles undergo severe volume expansion during repeated cycling. Furthermore, the irreversibility of the electrode in early cycles impairs the energy density of the cell significantly. Herein, we introduce an elastic polymer known as “Spandex” as a binder for the silver–carbon composite. The soft and hard segments of this binder act synergistically in that the former engages in strong hydrogen bonding with the active material and the latter promotes elastic adjustment of the binder network. This binder design significantly improves the charge–discharge reversibility and long-term cyclability of the anode-less ASSB cell and provides insights into elastic binder systems for high-capacity ASSB anodes that undergo a large volume expansion. |
Author | Chang, Barsa Lee, Sangheon Oh, Jihoon Lee, Taegeun Kim, Yunsung Im, Gahyeon Choi, Jang Wook Lee, Jieun Choi, Seung Ho Kim, Hyuntae Lee, Nohjoon |
AuthorAffiliation | School of Chemical and Biological Engineering and Institute of Chemical Processes Advanced Battery Development Team |
AuthorAffiliation_xml | – name: School of Chemical and Biological Engineering and Institute of Chemical Processes – name: Advanced Battery Development Team |
Author_xml | – sequence: 1 givenname: Jihoon orcidid: 0000-0002-3603-6975 surname: Oh fullname: Oh, Jihoon organization: School of Chemical and Biological Engineering and Institute of Chemical Processes – sequence: 2 givenname: Seung Ho surname: Choi fullname: Choi, Seung Ho organization: Advanced Battery Development Team – sequence: 3 givenname: Barsa surname: Chang fullname: Chang, Barsa organization: School of Chemical and Biological Engineering and Institute of Chemical Processes – sequence: 4 givenname: Jieun surname: Lee fullname: Lee, Jieun organization: School of Chemical and Biological Engineering and Institute of Chemical Processes – sequence: 5 givenname: Taegeun surname: Lee fullname: Lee, Taegeun organization: School of Chemical and Biological Engineering and Institute of Chemical Processes – sequence: 6 givenname: Nohjoon surname: Lee fullname: Lee, Nohjoon organization: School of Chemical and Biological Engineering and Institute of Chemical Processes – sequence: 7 givenname: Hyuntae surname: Kim fullname: Kim, Hyuntae organization: School of Chemical and Biological Engineering and Institute of Chemical Processes – sequence: 8 givenname: Yunsung surname: Kim fullname: Kim, Yunsung organization: Advanced Battery Development Team – sequence: 9 givenname: Gahyeon surname: Im fullname: Im, Gahyeon organization: Advanced Battery Development Team – sequence: 10 givenname: Sangheon surname: Lee fullname: Lee, Sangheon email: sheonlee@hyundai.com organization: Advanced Battery Development Team – sequence: 11 givenname: Jang Wook orcidid: 0000-0001-8783-0901 surname: Choi fullname: Choi, Jang Wook email: jangwookchoi@snu.ac.kr organization: School of Chemical and Biological Engineering and Institute of Chemical Processes |
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Snippet | Sulfide-based all-solid-state batteries (ASSBs) offer enhanced safety and potentially high energy density. Particularly, an “anode-less” electrode containing... |
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Title | Elastic Binder for High-Performance Sulfide-Based All-Solid-State Batteries |
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