Photoinduced Hydroxylation of Organic Halides under Mild Conditions

Presented in this paper is photoinduced hydroxylation of organic halides, providing a mild access to a range of functionalized phenols and aliphatic alcohols. These reactions generally proceed under mild reaction conditions with no need for a photocatalyst or a strong base and show a wide substrate...

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Bibliographic Details
Published inOrganic letters Vol. 21; no. 20; pp. 8479 - 8484
Main Authors Cai, Yue-Ming, Xu, Yu-Ting, Zhang, Xin, Gao, Wen-Xia, Huang, Xiao-Bo, Zhou, Yun-Bing, Liu, Miao-Chang, Wu, Hua-Yue
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 18.10.2019
Subjects
hydroxylation
moieties
organic halogen compounds
phenols
photocatalysts
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Summary:Presented in this paper is photoinduced hydroxylation of organic halides, providing a mild access to a range of functionalized phenols and aliphatic alcohols. These reactions generally proceed under mild reaction conditions with no need for a photocatalyst or a strong base and show a wide substrate scope as well as excellent functional group tolerance. This work highlights the unique role of NaI that allows a challenging transformation to proceed under mild reaction conditions.
Bibliography:ObjectType-Article-1
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ISSN:1523-7060
1523-7052
1523-7052
DOI:10.1021/acs.orglett.9b03317