Additive Growth and Crystallization of Polymer Films
We demonstrated a polymeric thin film fabrication process in which molecular-scale crystallization proceeds with additive film growth, by employing an innovative vapor-assisted deposition process termed matrix-assisted pulsed laser evaporation (MAPLE). In comparison to solution-casting commonly adop...
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Published in | Macromolecules Vol. 49; no. 7; pp. 2860 - 2867 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
12.04.2016
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Abstract | We demonstrated a polymeric thin film fabrication process in which molecular-scale crystallization proceeds with additive film growth, by employing an innovative vapor-assisted deposition process termed matrix-assisted pulsed laser evaporation (MAPLE). In comparison to solution-casting commonly adopted for the deposition of polymer thin films, this physical vapor deposition (PVD) methodology can prolong the time scale of film formation and allow for the manipulation of temperature during deposition. For the deposition of molecular and atomic systems, such a PVD manner has been demonstrated to facilitate molecular ordering and delicately manipulate crystalline morphology during film growth. Here, using MAPLE, we deposited thin films of a model polymer, poly(ethylene oxide) (PEO), atop a temperature-controlled substrate with an average growth rate of less than 10 nm/h. The mechanism of deposition is sequential addition of nanoscale liquid droplets. We discovered that the deposition process leads to the formation of two-dimensional (2D) PEO crystals, composed of monolamellar crystals laterally grown from larger nucleus droplets. The 2D crystalline coverage and crystal thickness of the films can be manipulated with two processing parameters, deposition time, and temperature. |
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AbstractList | We demonstrated a polymeric thin film fabrication process in which molecular-scale crystallization proceeds with additive film growth, by employing an innovative vapor-assisted deposition process termed matrix-assisted pulsed laser evaporation (MAPLE). In comparison to solution-casting commonly adopted for the deposition of polymer thin films, this physical vapor deposition (PVD) methodology can prolong the time scale of film formation and allow for the manipulation of temperature during deposition. For the deposition of molecular and atomic systems, such a PVD manner has been demonstrated to facilitate molecular ordering and delicately manipulate crystalline morphology during film growth. Here, using MAPLE, we deposited thin films of a model polymer, poly(ethylene oxide) (PEO), atop a temperature-controlled substrate with an average growth rate of less than 10 nm/h. The mechanism of deposition is sequential addition of nanoscale liquid droplets. We discovered that the deposition process leads to the formation of two-dimensional (2D) PEO crystals, composed of monolamellar crystals laterally grown from larger nucleus droplets. The 2D crystalline coverage and crystal thickness of the films can be manipulated with two processing parameters, deposition time, and temperature. |
Author | Shepard, Kimberly B Priestley, Rodney D Purdum, Geoffrey E Guo, Yunlong Arnold, Craig B Jeong, Hyuncheol Loo, Yueh-Lin |
AuthorAffiliation | Princeton University Princeton Institute for the Science and Technology of Materials Department of Chemical and Biological Engineering Mechanical and Aerospace Engineering |
AuthorAffiliation_xml | – name: Mechanical and Aerospace Engineering – name: Department of Chemical and Biological Engineering – name: Princeton Institute for the Science and Technology of Materials – name: Princeton University |
Author_xml | – sequence: 1 givenname: Hyuncheol surname: Jeong fullname: Jeong, Hyuncheol – sequence: 2 givenname: Kimberly B surname: Shepard fullname: Shepard, Kimberly B – sequence: 3 givenname: Geoffrey E surname: Purdum fullname: Purdum, Geoffrey E – sequence: 4 givenname: Yunlong surname: Guo fullname: Guo, Yunlong – sequence: 5 givenname: Yueh-Lin surname: Loo fullname: Loo, Yueh-Lin – sequence: 6 givenname: Craig B surname: Arnold fullname: Arnold, Craig B – sequence: 7 givenname: Rodney D surname: Priestley fullname: Priestley, Rodney D email: rpriestl@princeton.edu |
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CitedBy_id | crossref_primary_10_1021_acs_jpclett_6b02573 crossref_primary_10_1021_acsami_7b13609 crossref_primary_10_1016_j_jddst_2021_103063 crossref_primary_10_1007_s00339_017_0905_6 crossref_primary_10_1021_acs_macromol_7b02345 crossref_primary_10_1063_1_5000509 crossref_primary_10_1021_acsmacrolett_9b00406 crossref_primary_10_1007_s00339_019_2714_6 crossref_primary_10_1016_j_saa_2023_122608 crossref_primary_10_1002_polb_24588 crossref_primary_10_1002_pcr2_10021 crossref_primary_10_1002_pcr2_10153 crossref_primary_10_1007_s10544_017_0224_x crossref_primary_10_1021_acsapm_9b01124 crossref_primary_10_3390_nano9050692 |
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