Sequential and Simultaneous Melt Intercalation of Poly(ethylene oxide) and Poly(methyl methacrylate) into Layered Silicates
Both poly(ethylene oxide) (PEO) and poly(methyl methacrylate) (PMMA) were melt intercalated in a sequential or simultaneous (blend) manner into two layered silicates, a sodium montmorillonite (MMT) and an organically modified bentonite (B34). The B34 nanoclay, which was already pre-intercalated to t...
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Published in | Macromolecules Vol. 38; no. 5; pp. 1744 - 1751 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
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American Chemical Society
08.03.2005
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Abstract | Both poly(ethylene oxide) (PEO) and poly(methyl methacrylate) (PMMA) were melt intercalated in a sequential or simultaneous (blend) manner into two layered silicates, a sodium montmorillonite (MMT) and an organically modified bentonite (B34). The B34 nanoclay, which was already pre-intercalated to the point of saturation by PEO, was found able to take up additional PMMA. The converse was also found to be true where, despite the silicate galleries being saturated by PMMA, additional PEO was able to be incorporated. This implies that the packing density of the mixed PEO and PMMA phase in the gallery of B34 is greater than that of either polymer alone in the gallery. The intercalation of a miscible PEO/PMMA blend into B34 results in a greater increase in the spacing between layers than by either for a PEO-B34 hybrid or for a saturated PMMA−B34 hybrid. However, the intercalation of a PEO/PMMA blend into MMT results in the same gallery size increase as for the PEO−MMT hybrid. The organically modified bentonite is thus able to host a higher concentration of macromolecular chains from a miscible blend than from either polymer alone. The presence of PEO, which has a lower intercalation temperature than PMMA, thus encourages reptation of the PMMA into the silicate galleries at temperatures below that it could move in alone. |
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AbstractList | Both poly(ethylene oxide) (PEO) and poly(methyl methacrylate) (PMMA) were melt intercalated in a sequential or simultaneous (blend) manner into two layered silicates, a sodium montmorillonite (MMT) and an organically modified bentonite (B34). The B34 nanoclay, which was already pre-intercalated to the point of saturation by PEO, was found able to take up additional PMMA. The converse was also found to be true where, despite the silicate galleries being saturated by PMMA, additional PEO was able to be incorporated. This implies that the packing density of the mixed PEO and PMMA phase in the gallery of B34 is greater than that of either polymer alone in the gallery. The intercalation of a miscible PEO/PMMA blend into B34 results in a greater increase in the spacing between layers than by either for a PEO-B34 hybrid or for a saturated PMMA−B34 hybrid. However, the intercalation of a PEO/PMMA blend into MMT results in the same gallery size increase as for the PEO−MMT hybrid. The organically modified bentonite is thus able to host a higher concentration of macromolecular chains from a miscible blend than from either polymer alone. The presence of PEO, which has a lower intercalation temperature than PMMA, thus encourages reptation of the PMMA into the silicate galleries at temperatures below that it could move in alone. |
Author | Shen, Zhiqi Simon, George P Cheng, Yi-Bing |
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Keywords | Mixing Organic clay Polymer blends Montmorillonite Insertion Methyl methacrylate polymer Experimental study Ethylene oxide polymer Sequential method Supramolecular structure Bentonite Nanocomposite Manufacturing Growth from melt Comparative study |
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Snippet | Both poly(ethylene oxide) (PEO) and poly(methyl methacrylate) (PMMA) were melt intercalated in a sequential or simultaneous (blend) manner into two layered... |
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SubjectTerms | Applied sciences Composites Exact sciences and technology Forms of application and semi-finished materials Polymer industry, paints, wood Technology of polymers |
Title | Sequential and Simultaneous Melt Intercalation of Poly(ethylene oxide) and Poly(methyl methacrylate) into Layered Silicates |
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