Synthesis, Crystal Structure, and Luminescence of Zn/Cd Coordination Polymers with a New Fuctionalized Terpyridyl Carboxylate Ligand

• Published in: Crystal growth & design Vol. 14; no. 4; pp. 1629 - 1641
• Main Authors: Xu, Bing, Xie, Juan, Hu, Huai-Ming, Yang, Xiao-Le, Dong, Fa-Xin, Yang, Meng-Lin, Xue, Gang-Lin
• Format: Journal Article
• Language: English
• Published: Washington,DC American Chemical Society 02.04.2014
• Subjects: Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Exact sciences and technology; Growth from solutions; Materials science; Methods of crystal growth; physics of crystal growth; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation; Optical properties of bulk materials and thin films; Other materials; Physics; Specific materials; Structure of solids and liquids; crystallography; Structure of specific crystalline solids; pH value; Molecular structure; Polychelate; Dicarboxylic acids; Organometallic compounds; Luminescence; Photoluminescence; XRD; Thermal stability; Thermal properties; Monocrystals; Lamellar structure; Benzene; Optical properties; Crystal growth from solutions; Ligands; Carboxylates; Bilayers; Organic compounds; Crystal structure

Eight new coordination polymers, [Zn(L)Cl] n (1), [Zn2(L)4] n ·2nH2O (2), [Zn2(L)2(1,3-bdc)] n (3), [Zn2(L)(1,3-bdc)(OH)] n ·0.5nH2O (4), [Zn9(L)4(1,3-bdc)6(OH)2] n ·3nH2O (5), [Zn2(L)2(1,4-bdc)] n ·nH2O (6), [Cd2(L)4] n ·nH2O (7), and [Cd3(L)2(1,3-bdc)2] n ·nH2O (8) [HL = 4′-(2-carboxyphenyl)-4,2′:...