Epitaxy of Calcite on Mica
We report for the first time the conditions under which oriented overgrowth of calcite occurs on muscovite mica. Calcite grows in a (001) orientation parallel to the basal cleavage plane on mica surfaces that have been weathered at ambient humidity (35−40%) for periods of at least 1 h, but no epitax...
Saved in:
Published in | Crystal growth & design Vol. 10; no. 2; pp. 734 - 738 |
---|---|
Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Washington,DC
American Chemical Society
03.02.2010
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | We report for the first time the conditions under which oriented overgrowth of calcite occurs on muscovite mica. Calcite grows in a (001) orientation parallel to the basal cleavage plane on mica surfaces that have been weathered at ambient humidity (35−40%) for periods of at least 1 h, but no epitaxy is found on freshly cleaved mica. Nanometer-thin K2CO3 crystallites are known to form on mica surfaces weathered in this manner, and our experiments show that the presence of these crystallites during the initial stages of nucleation and growth is necessary for the epitaxial growth of calcite. Calcium ions do not adsorb to mica surfaces at the solution concentrations (≤20 mM) used in these experiments, and we suggest that the crystallites provide patches on the surface where the local concentration of both carbonate and calcium ions is high enough to promote epitaxy. |
---|---|
AbstractList | We report for the first time the conditions under which oriented overgrowth of calcite occurs on muscovite mica. Calcite grows in a (001) orientation parallel to the basal cleavage plane on mica surfaces that have been weathered at ambient humidity (35−40%) for periods of at least 1 h, but no epitaxy is found on freshly cleaved mica. Nanometer-thin K2CO3 crystallites are known to form on mica surfaces weathered in this manner, and our experiments show that the presence of these crystallites during the initial stages of nucleation and growth is necessary for the epitaxial growth of calcite. Calcium ions do not adsorb to mica surfaces at the solution concentrations (≤20 mM) used in these experiments, and we suggest that the crystallites provide patches on the surface where the local concentration of both carbonate and calcium ions is high enough to promote epitaxy. |
Author | Christenson, Hugo K Stephens, Christopher J Meldrum, Fiona C Mouhamad, Youmna |
Author_xml | – sequence: 1 givenname: Christopher J surname: Stephens fullname: Stephens, Christopher J – sequence: 2 givenname: Youmna surname: Mouhamad fullname: Mouhamad, Youmna – sequence: 3 givenname: Fiona C surname: Meldrum fullname: Meldrum, Fiona C – sequence: 4 givenname: Hugo K surname: Christenson fullname: Christenson, Hugo K email: h.k.christenson@leeds.ac.uk |
BackLink | http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22551392$$DView record in Pascal Francis |
BookMark | eNptj0tLw0AUhQepYFtduHWVjQsXsXdmMq-lhPqAFje6DjeXGUmJSZiJYP-9kWrduDoXzncPfAs26_rOM3bJ4ZaD4Ct6c8C5BDxhc66EzY0CNfu9CyvP2CKlHQAYLeWcXa2HZsTPfdaHrMSWmtFnfZdtG8JzdhqwTf7iJ5fs9X79Uj7mm-eHp_Juk6Owbsy1CK7WNQXntACioKUi41FBKEhjkEqglbYwtfFKuKnxmteWwCG3BqVcspvDLsU-pehDNcTmHeO-4lB9S1VHqYm9PrADJsI2ROyoSccHIZTi0ok_DilVu_4jdpPBP3tfIiNXOA |
CitedBy_id | crossref_primary_10_1002_anie_201913327 crossref_primary_10_1002_ange_201913327 crossref_primary_10_1021_ja200309m crossref_primary_10_1016_j_jmat_2019_12_006 crossref_primary_10_1209_0295_5075_105_18004 crossref_primary_10_1021_cg201314k crossref_primary_10_1021_jp503807v crossref_primary_10_1021_acs_cgd_0c00578 crossref_primary_10_1021_es405141j crossref_primary_10_1063_1_4866035 crossref_primary_10_1179_1743280411Y_0000000015 crossref_primary_10_1021_acs_energyfuels_9b01351 crossref_primary_10_3390_min8010017 crossref_primary_10_1021_acs_jpcc_9b00378 crossref_primary_10_1021_ct4002027 crossref_primary_10_1021_acs_cgd_3c01433 crossref_primary_10_1002_aelm_202201031 crossref_primary_10_1016_j_jcrysgro_2022_126545 crossref_primary_10_1016_j_surfrep_2016_03_001 crossref_primary_10_1039_C7CC07441G |
Cites_doi | 10.1021/cg800483g 10.1039/ft9928800243 10.1016/0039-6028(69)90044-2 10.1002/9780470994603 10.1021/la026837k 10.1021/cg801334g 10.1038/217056a0 10.1016/S0008-8846(03)00096-6 10.1063/1.1844393 10.1039/tf9545000684 10.1016/S0022-0248(96)01147-5 10.1002/adfm.200400268 10.1021/cr8002856 10.1021/ja984254k 10.1039/b500584a 10.1021/la981049+ 10.1021/la802124v 10.1126/science.269.5223.515 10.1016/0016-7037(87)90155-4 10.1039/b401594k 10.1016/0039-6028(70)90079-8 10.1088/0957-4484/19/30/305705 10.1002/1521-4095(20020404)14:7<492::AID-ADMA492>3.0.CO;2-L 10.1021/j100148a032 10.1016/0021-9797(84)90316-3 10.1021/la950330a 10.1016/0021-9797(87)90420-6 10.1016/0021-9797(81)90348-9 10.1063/1.1726964 10.1016/j.pcrysgrow.2006.09.002 10.1021/la991404b 10.1126/science.1169434 10.1016/S0016-7037(02)01270-X 10.1016/0040-6090(78)90236-5 10.1016/0021-9797(88)90113-0 10.1039/df9490500201 10.1021/la901311k 10.1107/S0365110X5100163X |
ContentType | Journal Article |
Copyright | Copyright © 2009 American Chemical Society 2015 INIST-CNRS |
Copyright_xml | – notice: Copyright © 2009 American Chemical Society – notice: 2015 INIST-CNRS |
DBID | IQODW AAYXX CITATION |
DOI | 10.1021/cg901130a |
DatabaseName | Pascal-Francis CrossRef |
DatabaseTitle | CrossRef |
DatabaseTitleList | |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Engineering Chemistry Physics |
EISSN | 1528-7505 |
EndPage | 738 |
ExternalDocumentID | 10_1021_cg901130a 22551392 b302247983 |
GroupedDBID | 4.4 53G 55A 5GY 5VS 7~N AABXI ABMVS ABPTK ABUCX ACGFS ACS AEESW AENEX AFEFF ALMA_UNASSIGNED_HOLDINGS AQSVZ BAANH CS3 DU5 EBS ED ED~ EJD F5P GNL IH9 JG JG~ LG6 P2P RNS ROL TN5 UI2 VF5 VG9 W1F X -~X 6J9 ABFRP ABQRX ADHLV AFFNX AHGAQ GGK IHE IQODW AAYXX ABJNI CITATION CUPRZ |
ID | FETCH-LOGICAL-a289t-62f9b6bcf99620ccf635c7ea50f4c6af352a83847b7e5297eae61b8c09a187a33 |
IEDL.DBID | ACS |
ISSN | 1528-7483 |
IngestDate | Fri Dec 06 04:36:15 EST 2024 Fri Nov 25 06:04:27 EST 2022 Thu Feb 04 21:43:08 EST 2021 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 2 |
Keywords | Crystallites Epitaxial layers Nucleation Calcium Epitaxy Calcium carbonate Humidity Growth mechanism Cleavage Calcite Mica |
Language | English |
License | CC BY 4.0 |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-a289t-62f9b6bcf99620ccf635c7ea50f4c6af352a83847b7e5297eae61b8c09a187a33 |
PageCount | 5 |
ParticipantIDs | crossref_primary_10_1021_cg901130a pascalfrancis_primary_22551392 acs_journals_10_1021_cg901130a |
ProviderPackageCode | JG~ 55A AABXI GNL VF5 7~N VG9 W1F ACS AEESW AFEFF ABMVS ABUCX IH9 BAANH AQSVZ ED~ UI2 |
PublicationCentury | 2000 |
PublicationDate | 2010-02-03 |
PublicationDateYYYYMMDD | 2010-02-03 |
PublicationDate_xml | – month: 02 year: 2010 text: 2010-02-03 day: 03 |
PublicationDecade | 2010 |
PublicationPlace | Washington,DC |
PublicationPlace_xml | – name: Washington,DC |
PublicationTitle | Crystal growth & design |
PublicationTitleAlternate | Cryst. Growth Des |
PublicationYear | 2010 |
Publisher | American Chemical Society |
Publisher_xml | – name: American Chemical Society |
References | Ehrentraut D. (ref1/cit1) 2006; 52 Archibald D. D. (ref28/cit28) 1996; 12 Pashley R. M. (ref35/cit35) 1984; 97 Yamanaka S. (ref40/cit40) 2009; 9 Lonsdale K. (ref2/cit2) 1968; 217 van der Merwe J. H. (ref4/cit4) 1949; 5 Ogino T. (ref31/cit31) 1987; 51 Ostendorf F. (ref14/cit14) 2009; 25 Alcantar N. (ref37/cit37) 2003; 67 Ohnishi S. (ref13/cit13) 1999; 15 Park R. J. (ref27/cit27) 2004; 14 ref29/cit29 Clarkson J. R. (ref32/cit32) 1992; 88 Christenson H. K. (ref11/cit11) 1993; 97 Loste E. (ref19/cit19) 2003; 19 Lisgarten N. D. (ref6/cit6) 1954; 50 Upreti M. C. (ref33/cit33) 1966; 44 Royer M. (ref3/cit3) 1928; 51 Pastero L. (ref25/cit25) 2008; 8 Kjellander R. (ref36/cit36) 1988; 126 Sato H. (ref9/cit9) 1970; 22 Sarma K. R. (ref7/cit7) 1997; 174 Kohonen M. M. (ref16/cit16) 2000; 16 Kewalramani S. (ref20/cit20) 2008; 24 Schulz L. G. (ref5/cit5) 1951; 4 Pouget E. M. (ref21/cit21) 2009; 323 Colfen H. (ref39/cit39) 2008 Loste E. (ref30/cit30) 2004; 14 Muller K. (ref10/cit10) 1969; 14 Meldrum F. C. (ref26/cit26) 2008; 108 Ostendorf F. (ref15/cit15) 2008; 19 García E. (ref24/cit24) 2003; 33 Pokroy B. (ref23/cit23) 2005 Pashley R. M. (ref34/cit34) 1981; 83 Conrad P. (ref38/cit38) 2005; 122 Christenson H. K. (ref12/cit12) 1987; 117 Travaille A. M. (ref18/cit18) 2002; 14 Berman A. (ref22/cit22) 1995; 269 Takayanagi K. (ref8/cit8) 1978; 48 Aizenberg J. (ref17/cit17) 1999; 121 |
References_xml | – volume: 8 start-page: 3451 year: 2008 ident: ref25/cit25 publication-title: Cryst. Growth Des. doi: 10.1021/cg800483g contributor: fullname: Pastero L. – volume: 88 start-page: 243 year: 1992 ident: ref32/cit32 publication-title: J. Chem. Soc., Faraday Trans. doi: 10.1039/ft9928800243 contributor: fullname: Clarkson J. R. – volume: 14 start-page: 39 year: 1969 ident: ref10/cit10 publication-title: Surf. Sci. doi: 10.1016/0039-6028(69)90044-2 contributor: fullname: Muller K. – volume-title: Mesocrystals and Nonclassical Crystallization year: 2008 ident: ref39/cit39 doi: 10.1002/9780470994603 contributor: fullname: Colfen H. – volume: 19 start-page: 2830 year: 2003 ident: ref19/cit19 publication-title: Langmuir doi: 10.1021/la026837k contributor: fullname: Loste E. – volume: 9 start-page: 3245 year: 2009 ident: ref40/cit40 publication-title: Cryst. Growth Des. doi: 10.1021/cg801334g contributor: fullname: Yamanaka S. – volume: 217 start-page: 56 year: 1968 ident: ref2/cit2 publication-title: Nature doi: 10.1038/217056a0 contributor: fullname: Lonsdale K. – volume: 33 start-page: 1449 year: 2003 ident: ref24/cit24 publication-title: Cem. Concr. Res. doi: 10.1016/S0008-8846(03)00096-6 contributor: fullname: García E. – volume: 122 start-page: 064709 year: 2005 ident: ref38/cit38 publication-title: J. Chem. Phys. doi: 10.1063/1.1844393 contributor: fullname: Conrad P. – volume: 50 start-page: 684 year: 1954 ident: ref6/cit6 publication-title: Trans. Faraday Soc. doi: 10.1039/tf9545000684 contributor: fullname: Lisgarten N. D. – volume: 174 start-page: 487 year: 1997 ident: ref7/cit7 publication-title: J. Cryst. Growth doi: 10.1016/S0022-0248(96)01147-5 contributor: fullname: Sarma K. R. – volume: 14 start-page: 1211 year: 2004 ident: ref30/cit30 publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.200400268 contributor: fullname: Loste E. – volume: 108 start-page: 4332 year: 2008 ident: ref26/cit26 publication-title: Chem. Rev. doi: 10.1021/cr8002856 contributor: fullname: Meldrum F. C. – volume: 121 start-page: 500 year: 1999 ident: ref17/cit17 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja984254k contributor: fullname: Aizenberg J. – start-page: 2140 year: 2005 ident: ref23/cit23 publication-title: Chem. Commun. doi: 10.1039/b500584a contributor: fullname: Pokroy B. – volume: 15 start-page: 3312 year: 1999 ident: ref13/cit13 publication-title: Langmuir doi: 10.1021/la981049+ contributor: fullname: Ohnishi S. – volume: 24 start-page: 10579 year: 2008 ident: ref20/cit20 publication-title: Langmuir doi: 10.1021/la802124v contributor: fullname: Kewalramani S. – volume: 269 start-page: 515 year: 1995 ident: ref22/cit22 publication-title: Science doi: 10.1126/science.269.5223.515 contributor: fullname: Berman A. – volume: 51 start-page: 2757 year: 1987 ident: ref31/cit31 publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(87)90155-4 contributor: fullname: Ogino T. – volume: 14 start-page: 2291 year: 2004 ident: ref27/cit27 publication-title: J. Mater. Chem. doi: 10.1039/b401594k contributor: fullname: Park R. J. – volume: 22 start-page: 229 year: 1970 ident: ref9/cit9 publication-title: Surf. Sci. doi: 10.1016/0039-6028(70)90079-8 contributor: fullname: Sato H. – volume: 19 start-page: 305705 year: 2008 ident: ref15/cit15 publication-title: Nanotechnology doi: 10.1088/0957-4484/19/30/305705 contributor: fullname: Ostendorf F. – volume: 14 start-page: 492 year: 2002 ident: ref18/cit18 publication-title: Adv. Mater. doi: 10.1002/1521-4095(20020404)14:7<492::AID-ADMA492>3.0.CO;2-L contributor: fullname: Travaille A. M. – volume: 97 start-page: 12034 year: 1993 ident: ref11/cit11 publication-title: J. Phys. Chem. doi: 10.1021/j100148a032 contributor: fullname: Christenson H. K. – volume: 51 start-page: 7 year: 1928 ident: ref3/cit3 publication-title: Bull. Soc. Fr. Miner. contributor: fullname: Royer M. – ident: ref29/cit29 – volume: 97 start-page: 446 year: 1984 ident: ref35/cit35 publication-title: J. Colloid Interface Sci. doi: 10.1016/0021-9797(84)90316-3 contributor: fullname: Pashley R. M. – volume: 12 start-page: 538 year: 1996 ident: ref28/cit28 publication-title: Langmuir doi: 10.1021/la950330a contributor: fullname: Archibald D. D. – volume: 117 start-page: 576 year: 1987 ident: ref12/cit12 publication-title: J. Colloid Interface Sci. doi: 10.1016/0021-9797(87)90420-6 contributor: fullname: Christenson H. K. – volume: 83 start-page: 531 year: 1981 ident: ref34/cit34 publication-title: J. Colloid Interface Sci. doi: 10.1016/0021-9797(81)90348-9 contributor: fullname: Pashley R. M. – volume: 44 start-page: 1936 year: 1966 ident: ref33/cit33 publication-title: J. Chem. Phys. doi: 10.1063/1.1726964 contributor: fullname: Upreti M. C. – volume: 52 start-page: 280 year: 2006 ident: ref1/cit1 publication-title: Prog. Cryst, Growth Charact. Mater. doi: 10.1016/j.pcrysgrow.2006.09.002 contributor: fullname: Ehrentraut D. – volume: 16 start-page: 7285 year: 2000 ident: ref16/cit16 publication-title: Langmuir doi: 10.1021/la991404b contributor: fullname: Kohonen M. M. – volume: 323 start-page: 1455 year: 2009 ident: ref21/cit21 publication-title: Science doi: 10.1126/science.1169434 contributor: fullname: Pouget E. M. – volume: 67 start-page: 1289 year: 2003 ident: ref37/cit37 publication-title: Geochim. Cosmochim. Acta doi: 10.1016/S0016-7037(02)01270-X contributor: fullname: Alcantar N. – volume: 48 start-page: 137 year: 1978 ident: ref8/cit8 publication-title: Thin Solid Films doi: 10.1016/0040-6090(78)90236-5 contributor: fullname: Takayanagi K. – volume: 126 start-page: 194 year: 1988 ident: ref36/cit36 publication-title: J. Colloid Interface Sci. doi: 10.1016/0021-9797(88)90113-0 contributor: fullname: Kjellander R. – volume: 5 start-page: 201 year: 1949 ident: ref4/cit4 publication-title: Faraday Discuss. doi: 10.1039/df9490500201 contributor: fullname: van der Merwe J. H. – volume: 25 start-page: 10764 year: 2009 ident: ref14/cit14 publication-title: Langmuir doi: 10.1021/la901311k contributor: fullname: Ostendorf F. – volume: 4 start-page: 483 year: 1951 ident: ref5/cit5 publication-title: Acta Crystallogr. doi: 10.1107/S0365110X5100163X contributor: fullname: Schulz L. G. |
SSID | ssj0007633 |
Score | 2.1251433 |
Snippet | We report for the first time the conditions under which oriented overgrowth of calcite occurs on muscovite mica. Calcite grows in a (001) orientation parallel... |
SourceID | crossref pascalfrancis acs |
SourceType | Aggregation Database Index Database Publisher |
StartPage | 734 |
SubjectTerms | Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science; rheology Equations of state, phase equilibria, and phase transitions Exact sciences and technology General studies of phase transitions Materials science Methods of deposition of films and coatings; film growth and epitaxy Nucleation Physics Theory and models of film growth |
Title | Epitaxy of Calcite on Mica |
URI | http://dx.doi.org/10.1021/cg901130a |
Volume | 10 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwhV3dS8MwED_GfFARP6bipo6ivna0ubVJH6U6hjBfdLC3kqTJi9IN14H613tt17Hh13MTklzucr9fL7kDuMFIGyWN76LhiggKmZRUnnSRCS1SVILZ4j_k6DEcjvsPk2DSgOtfIvjMJ5JYvI5Ej0DQFuNEuwv8Ez-tjlsykPIWfcDKxJhYpw9a71q4Hj3fcD17MzknKdiqfMWaTxkcwF39Mqe6SvLSW-Sqpz-_J2r8a7qHsL_ElM5tpQRH0DBZC7bjupRbC3bXsg4eQ-e-qBTy_uFMrRPLV02g05lmzoi26wTGg_vneOguSyS4kphS7obMRipU2hJtYZ7WlvCD5kYGnu3rUFqCV1IgeSDFTcAi-mJCXwntRdIXXCKeQjObZuYMHEF7SY5KIDLTTw0KZThPFfWOUrLqqA1dkmGyVPF5UkavmZ-sFtyGq1q8yaxKlfFTo-6G4Fct6VwJCI2yzn_DnMNOFcFnrocX0MzfFuaSgEGuuqVifAHFLa7n |
link.rule.ids | 314,780,784,2765,27076,27924,27925,56738,56788 |
linkProvider | American Chemical Society |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV3fT8IwEL4YfEBj_IEaQcXF-DqytWzrHs0CQQVehIS3pe3aF80gbiTqX--tGwjGRJ_Xbu31rvfdrv0O4I6GUgmuXJuqQGCAgibFhcNtSphkCRWM6OI_5GjsD6bdx5k3q2hyirswOIgM35SZJP43u4CLsWJxSZI6iIV2vaJUZQGDouf1rot2Yg7Te8TwY9IVi9Bm18IDyWzLAx0seIbC0GUViw3X0j8qaxSZQZkTJS-dZS468vMHX-P_Rn0MhxXCtO5LlTiBHZU2oB6tCrs1YH-Dg_AUWr2ibsj7hzXXVsRfJUJQa55aI1y8M5j2e5NoYFcFE2yOcVNu-0SHwhdSYxBDHCk1ogkZKO45uit9rhFscUbRH4lAeSTEJ8p3BZNOyF0WcErPoZbOU3UBFsOVRbfFKCWqmyjKhAqCRGDvMEEbD5vQxvnGlcJnscllEzdeT7gJtyspx4uSOOO3Ru0t-a9b4i7jITYlrb8-cwP1wWQ0jIcP46dL2Ctz-8R26BXU8relukbIkIu20ZUvLUO3VA |
linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV3rS8MwED9kgg_Ex1Tc1FnErx1tsrbpx1E35mNT0MG-lSRNvky6YTtQ_3qvj5VNBP3cpL0k9_hd73IHcEN9qQRXtkmVJ9BBQZHiwuImJUyyiApGdPYfcjhyB-PO_cSZlI5idhcGiUjwTUkexM-keh7pssKAjf5idlGSWoiHNh3UslkKVzd4qTQvykqeUO-QvEYmXVYSWp2aWSGZrFmhvTlPcEN00clixbz0D-CpIizPKpm2F6loy68fNRv_T_kh7JdI0-gWrHEEGyquw3awbPBWh92VWoTH0Oxl_UM-Po2ZNgL-JhGKGrPYGOIhnsC433sNBmbZOMHk6D-lpku0L1whNTozxJJSI6qQnuKOpTvS5RpBF2cU7ZLwlEN8fKJcWzBp-dxmHqf0FGrxLFZnYDA8YTRfjFKiOpGiTCjPiwTO9iOUdb8BLVxzWDJ-EuYxbWKH1YIbcL3c6XBeFND4bVBr7QyqkahtHMSopPnXZ65g6_m2Hz7ejR7OYacI8RPTohdQS98X6hKRQypaObt8A3nYudc |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Epitaxy+of+Calcite+on+Mica&rft.jtitle=Crystal+growth+%26+design&rft.au=STEPHENS%2C+Christopher+J&rft.au=MOUHAMAD%2C+Youmna&rft.au=MELDRUM%2C+Fiona+C&rft.au=CHRISTENSON%2C+Hugo+K&rft.date=2010-02-03&rft.pub=American+Chemical+Society&rft.issn=1528-7483&rft.eissn=1528-7505&rft.volume=10&rft.issue=2&rft.spage=734&rft.epage=738&rft_id=info:doi/10.1021%2Fcg901130a&rft.externalDBID=n%2Fa&rft.externalDocID=22551392 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1528-7483&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1528-7483&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1528-7483&client=summon |