Coupling High Hardness and Zn Affinity in Amorphous–Crystalline Diamond for Stable Zn Metal Anodes

The highly reversible plating/stripping of Zn is plagued by dendrite growth and side reactions on metallic Zn anodes, retarding the commercial application of aqueous Zn-ion batteries. Herein, a distinctive nano dual-phase diamond (NDPD) comprised of an amorphous–crystalline heterostructure is develo...

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Published inACS nano Vol. 18; no. 22; pp. 14403 - 14413
Main Authors Chen, Yuhan, Yin, Jianan, Zhang, Yaqin, Lyu, Fucong, Qin, Bin, Zhou, Jingwen, Liu, Jia-Hua, Long, Yun-Chen, Mao, Zhengyi, Miao, Mulin, Cai, Xiaoqiang, Fan, Jun, Lu, Jian
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 22.05.2024
Subjects
aqueous batteries
mechanical and chemical synergism
Zn dendrites
amorphous−crystalline heterostructure
nano dual-phase diamond
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Abstract The highly reversible plating/stripping of Zn is plagued by dendrite growth and side reactions on metallic Zn anodes, retarding the commercial application of aqueous Zn-ion batteries. Herein, a distinctive nano dual-phase diamond (NDPD) comprised of an amorphous–crystalline heterostructure is developed to regulate Zn deposition and mechanically block dendrite growth. The rich amorphous–crystalline heterointerfaces in the NDPD endow modified Zn anodes with enhanced Zn affinity and result in homogeneous nucleation. In addition, the unparalleled hardness of the NDPD effectively overcomes the high growth stress of dendrites and mechanically impedes their proliferation. Moreover, the hydrophobic surfaces of the NDPD facilitate the desolvation of hydrate Zn2+ and prevent water-mediated side reactions. Consequently, the Zn@NDPD presents an ultrastable lifespan exceeding 3200 h at 5 mA cm–2 and 1 mAh cm–2. The practical application potential of Zn@NDPD is further demonstrated in full cells. This work exhibits the great significance of a chemical–mechanical synergistic anode modification strategy in constructing high-performance aqueous Zn-ion batteries.
AbstractList The highly reversible plating/stripping of Zn is plagued by dendrite growth and side reactions on metallic Zn anodes, retarding the commercial application of aqueous Zn-ion batteries. Herein, a distinctive nano dual-phase diamond (NDPD) comprised of an amorphous-crystalline heterostructure is developed to regulate Zn deposition and mechanically block dendrite growth. The rich amorphous-crystalline heterointerfaces in the NDPD endow modified Zn anodes with enhanced Zn affinity and result in homogeneous nucleation. In addition, the unparalleled hardness of the NDPD effectively overcomes the high growth stress of dendrites and mechanically impedes their proliferation. Moreover, the hydrophobic surfaces of the NDPD facilitate the desolvation of hydrate Zn and prevent water-mediated side reactions. Consequently, the Zn@NDPD presents an ultrastable lifespan exceeding 3200 h at 5 mA cm and 1 mAh cm . The practical application potential of Zn@NDPD is further demonstrated in full cells. This work exhibits the great significance of a chemical-mechanical synergistic anode modification strategy in constructing high-performance aqueous Zn-ion batteries.
The highly reversible plating/stripping of Zn is plagued by dendrite growth and side reactions on metallic Zn anodes, retarding the commercial application of aqueous Zn-ion batteries. Herein, a distinctive nano dual-phase diamond (NDPD) comprised of an amorphous-crystalline heterostructure is developed to regulate Zn deposition and mechanically block dendrite growth. The rich amorphous-crystalline heterointerfaces in the NDPD endow modified Zn anodes with enhanced Zn affinity and result in homogeneous nucleation. In addition, the unparalleled hardness of the NDPD effectively overcomes the high growth stress of dendrites and mechanically impedes their proliferation. Moreover, the hydrophobic surfaces of the NDPD facilitate the desolvation of hydrate Zn2+ and prevent water-mediated side reactions. Consequently, the Zn@NDPD presents an ultrastable lifespan exceeding 3200 h at 5 mA cm-2 and 1 mAh cm-2. The practical application potential of Zn@NDPD is further demonstrated in full cells. This work exhibits the great significance of a chemical-mechanical synergistic anode modification strategy in constructing high-performance aqueous Zn-ion batteries.
Author Lyu, Fucong
Qin, Bin
Fan, Jun
Lu, Jian
Long, Yun-Chen
Chen, Yuhan
Yin, Jianan
Miao, Mulin
Mao, Zhengyi
Zhou, Jingwen
Liu, Jia-Hua
Cai, Xiaoqiang
Zhang, Yaqin
AuthorAffiliation Department of Chemistry
Shenyang National Laboratory for Materials Science
Centre for Advanced Structural Materials, City University of Hong Kong Shenzhen Research Institute, Greater Bay Joint Division
School of Mechanical Engineering and Automation
Key Laboratory of Magnetic Molecules and Magnetic Information Materials of Ministry of Education & School of Chemistry and Materials Science
City University of Hong Kong
Department of Mechanical Engineering
Department of Materials Science and Engineering
CityU-Shenzhen Futian Research Institute
Shanxi Normal University
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mechanical and chemical synergism
Zn dendrites
amorphous−crystalline heterostructure
nano dual-phase diamond
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Snippet The highly reversible plating/stripping of Zn is plagued by dendrite growth and side reactions on metallic Zn anodes, retarding the commercial application of...
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Title Coupling High Hardness and Zn Affinity in Amorphous–Crystalline Diamond for Stable Zn Metal Anodes
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