Mechanism of Cycloaddition Reactions between Ketene and N-Silyl-, N-Germyl-, and N-Stannylimines:  A Theoretical Investigation

• Published in: The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Vol. 109; no. 48; pp. 11022 - 11026
• Main Authors: Campomanes, Pablo, Menéndez, M. Isabel, Sordo, Tomás L
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 08.12.2005

A theoretical study of the cycloaddition reactions of ketene and N-silyl-, N-germyl-, and N-stannylimines were performed at the B3LYP/6-311+G(d,p) theory level using the LANL2DZ effective core potential for Ge and Sn and taking into account the effect of diethyl ether solvent by means of the polariz...