Photoswitchable Catalytic Aerobic Oxidation of Biomass-Based Furfural: A Selective Route for the Synthesis of 5‑Hydroxy-2(5H)-furanone and Maleic Acid by Using the CdS/MOF Photocatalyst

• Published in: Industrial & engineering chemistry research Vol. 63; no. 20; pp. 8933 - 8948
• Main Authors: Saki, Saeede, Hosseini-Sarvari, Mona, Gu, Yanlong, Zhang, Tianjian
• Format: Journal Article
• Language: English
• Published: American Chemical Society 22.05.2024
• Subjects: Kinetics, Catalysis, and Reaction Engineering
• ISSN: 0888-5885; 1520-5045
• DOI: 10.1021/acs.iecr.4c00363

Selective oxidation of furfural has become important for the synthesis of pharmaceutical intermediates and chemical industries. The development of effective methods for biomass valorization is a very attractive subject. Here, we performed an initial investigation into the photocatalytic selective oxidation of furfural to maleic acid (MA) as a valuable chemical and the vital bioactive intermediate 5-hydroxy-2­(5H)-furanone (HFO). In this work, MOFs-based Ti (NH2-MIL-125) was modified with the easy method by introducing the proper amount of CdS (2.5%) on the surface of NH2-MIL-125. The photocatalyst developed in this work performed best and gave high HFO (52%), MA (90%) selectivity, and high conversion (>90%) of furfural under various reaction conditions. The CdS (2.5%)/NH2-MIL-125 nanocomposite also showed a long-term stability. Synergistic interactions between the active surface of NH2-MIL-125 (which uses organic linkers as an antenna) and the active sites of CdS may result in enhancement of the photocatalytic activity of the CdS (2.5%)/NH2-MIL-125 photocatalyst. An analysis of the mechanism revealed that HFO and MA were produced from furfural through a series of multistep reactions, including oxidation, decarboxylation, and ring opening.