Insights into Adsorption of Linear, Monobranched, and Dibranched Alkanes on Pure Silica STW Zeolite as a Promising Material for Their Separation

The adsorption of linear, monobranched and dibranched saturated hydrocarbons in the gasoline range has been studied on pure silica STW zeolite (Si-STW) by using pentane, hexane, and heptane isomers as model adsorbates. Experimental single-component adsorption isotherms and kinetic measurements toget...

Full description

Saved in:
Bibliographic Details
Published inJournal of physical chemistry. C Vol. 124; no. 49; pp. 26821 - 26829
Main Authors Pérez-Botella, Eduardo, Misturini, Alechania, Sala, Andrés, Palomino, Miguel, Corma, Avelino, Sastre, German, Valencia, Susana, Rey, Fernando
Format Journal Article
LanguageEnglish
Published American Chemical Society 10.12.2020
Subjects
C: Surfaces, Interfaces, Porous Materials, and Catalysis
Online AccessGet full text

Cover

Abstract The adsorption of linear, monobranched and dibranched saturated hydrocarbons in the gasoline range has been studied on pure silica STW zeolite (Si-STW) by using pentane, hexane, and heptane isomers as model adsorbates. Experimental single-component adsorption isotherms and kinetic measurements together with configurational bias Monte Carlo (CBMC) and molecular dynamics (MD) simulations were carried out. Significant differences in both the equilibrium adsorption and especially the adsorption kinetics were found, which suggests that the separation of the quaternary-carbon dibranched isomer is feasible. The adsorption capacities and selectivities surpass those of pure silica MFI (Si-MFI), considered as reference. Altogether, Si-STW is presented as a promising adsorbent for increasing the octane number (ON) of the hydroisomerization product by selectively excluding quaternary-carbon dibranched hydrocarbons.
AbstractList The adsorption of linear, monobranched and dibranched saturated hydrocarbons in the gasoline range has been studied on pure silica STW zeolite (Si-STW) by using pentane, hexane, and heptane isomers as model adsorbates. Experimental single-component adsorption isotherms and kinetic measurements together with configurational bias Monte Carlo (CBMC) and molecular dynamics (MD) simulations were carried out. Significant differences in both the equilibrium adsorption and especially the adsorption kinetics were found, which suggests that the separation of the quaternary-carbon dibranched isomer is feasible. The adsorption capacities and selectivities surpass those of pure silica MFI (Si-MFI), considered as reference. Altogether, Si-STW is presented as a promising adsorbent for increasing the octane number (ON) of the hydroisomerization product by selectively excluding quaternary-carbon dibranched hydrocarbons.
Author Sastre, German
Valencia, Susana
Sala, Andrés
Corma, Avelino
Palomino, Miguel
Pérez-Botella, Eduardo
Misturini, Alechania
Rey, Fernando
AuthorAffiliation Universitat Politècnica de València − Consejo Superior de Investigaciones Científicas
AuthorAffiliation_xml – name: Universitat Politècnica de València − Consejo Superior de Investigaciones Científicas
Author_xml – sequence: 1
  givenname: Eduardo
  orcidid: 0000-0001-5622-4693
  surname: Pérez-Botella
  fullname: Pérez-Botella, Eduardo
– sequence: 2
  givenname: Alechania
  orcidid: 0000-0002-5873-8679
  surname: Misturini
  fullname: Misturini, Alechania
– sequence: 3
  givenname: Andrés
  surname: Sala
  fullname: Sala, Andrés
– sequence: 4
  givenname: Miguel
  surname: Palomino
  fullname: Palomino, Miguel
– sequence: 5
  givenname: Avelino
  orcidid: 0000-0002-2232-3527
  surname: Corma
  fullname: Corma, Avelino
– sequence: 6
  givenname: German
  orcidid: 0000-0003-0496-6331
  surname: Sastre
  fullname: Sastre, German
– sequence: 7
  givenname: Susana
  surname: Valencia
  fullname: Valencia, Susana
– sequence: 8
  givenname: Fernando
  orcidid: 0000-0003-3227-5669
  surname: Rey
  fullname: Rey, Fernando
  email: frey@itq.upv.es, direccion.itq@csic.es
BookMark eNp1kM1uwjAMgKNpkwZs9x39AJQlbdOWI2J_SKAhwTRpl8pLHQgrCUrKYW-xR14ZbLedbMv-bOvrsnPrLDF2I_hA8FjcogqDzU6pAVe8kCI_Yx0xTOIoT6U8_8vT_JJ1Q9hwLhMukg77mthgVusmgLGNg1EVnN81xllwGqbGEvo-zJx17x6tWlPVB7QV3JnfGkb1B1oK0CLzvSdYmNoohMXyFd7I1aYhwAAIc--2Jhi7ghk25A3WoJ2H5ZqMhwXt0OPh7hW70FgHuj7FHnt5uF-On6Lp8-NkPJpGGBe8iRSnYZ5wVcQioyKWFSdOOpe50JLHcaHyFAVmlY4rISiTQqssSbnSectnrY0e48e9yrsQPOly580W_WcpeHkwWrZGy4PR8mS0RfpH5Kfj9t62D_4__g1pFHzt
CitedBy_id crossref_primary_10_1002_cite_202300008
crossref_primary_10_1021_acs_chemrev_2c00140
crossref_primary_10_1039_D2CC05850B
crossref_primary_10_1016_j_ces_2021_117387
crossref_primary_10_1016_j_energy_2024_131645
crossref_primary_10_1039_D3VA00282A
crossref_primary_10_1002_jcc_26824
crossref_primary_10_1021_acs_jpcc_2c00086
crossref_primary_10_1016_j_ces_2021_116966
crossref_primary_10_1016_j_energy_2022_124924
crossref_primary_10_1021_acs_jpcc_2c04331
Cites_doi 10.1021/ie960472f
10.1021/acs.jpcc.7b05347
10.2174/2211334711205030001
10.1021/jp0447439
10.1007/978-981-13-3504-4_7
10.1002/ppsc.200400923
10.1039/C7TA10002G
10.1002/aic.690110125
10.1039/b101267n
10.1021/ja405088c
10.1021/ja974336t
10.1515/pac-2014-1117
10.1039/B304209J
10.1002/anie.200454058
10.1021/jp980674k
10.1021/acs.langmuir.8b00628
10.1016/j.ccr.2011.03.014
10.1002/qua.560200703
10.1002/anie.201205040
10.1021/jp0376727
10.1039/ft9918701947
10.1016/j.cej.2007.11.026
10.1016/S0167-2991(07)80805-6
10.1080/10916466.2015.1050506
10.1080/10916466.2010.504931
10.1007/s10450-007-9010-z
10.1016/S0009-2509(02)00580-8
10.1002/9783527651276
10.1107/S0108768187098173
10.1039/b103118j
10.1021/acs.energyfuels.9b00704
10.1021/jp982736c
10.1126/science.aao0092
10.1016/j.seppur.2012.12.017
10.1021/acs.jpcc.5b06010
10.1021/jp040216d
10.1080/08927022.2015.1010082
10.1002/aic.690480910
10.1016/S0263-7855(96)00043-4
10.1016/j.micromeso.2010.03.004
10.1021/jp984055n
10.2516/ogst/2009073
10.1039/b100941i
10.1021/jp0264533
ContentType Journal Article
Copyright 2020 American Chemical Society
Copyright_xml – notice: 2020 American Chemical Society
DBID AAYXX
CITATION
DOI 10.1021/acs.jpcc.0c08517
DatabaseName CrossRef
DatabaseTitle CrossRef
DatabaseTitleList
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1932-7455
EndPage 26829
ExternalDocumentID 10_1021_acs_jpcc_0c08517
b92308036
GroupedDBID .K2
53G
55A
5GY
5VS
7~N
85S
8RP
AABXI
ABFLS
ABMVS
ABPPZ
ABUCX
ACGFS
ACNCT
ACS
AEESW
AENEX
AFEFF
ALMA_UNASSIGNED_HOLDINGS
AQSVZ
BAANH
CS3
D0L
DU5
EBS
ED
ED~
F5P
GNL
IH9
IHE
JG
JG~
K2
RNS
ROL
UI2
UKR
VF5
VG9
VQA
W1F
4.4
AAYXX
ABJNI
ABQRX
ADHLV
AHGAQ
CITATION
CUPRZ
GGK
ID FETCH-LOGICAL-a280t-c0e9730c8216e825d0e0ef7571f50228c74a1a6df2d11e651fc6340cf7a286193
IEDL.DBID ACS
ISSN 1932-7447
IngestDate Fri Aug 23 01:15:11 EDT 2024
Sat Dec 12 18:48:24 EST 2020
IsPeerReviewed true
IsScholarly true
Issue 49
Language English
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-a280t-c0e9730c8216e825d0e0ef7571f50228c74a1a6df2d11e651fc6340cf7a286193
ORCID 0000-0002-2232-3527
0000-0002-5873-8679
0000-0001-5622-4693
0000-0003-0496-6331
0000-0003-3227-5669
PageCount 9
ParticipantIDs crossref_primary_10_1021_acs_jpcc_0c08517
acs_journals_10_1021_acs_jpcc_0c08517
ProviderPackageCode JG~
55A
AABXI
GNL
VF5
7~N
VG9
W1F
ACS
AEESW
AFEFF
.K2
ABMVS
ABUCX
IH9
BAANH
AQSVZ
ED~
UI2
PublicationCentury 2000
PublicationDate 20201210
2020-12-10
PublicationDateYYYYMMDD 2020-12-10
PublicationDate_xml – month: 12
  year: 2020
  text: 20201210
  day: 10
PublicationDecade 2020
PublicationTitle Journal of physical chemistry. C
PublicationTitleAlternate J. Phys. Chem. C
PublicationYear 2020
Publisher American Chemical Society
Publisher_xml – name: American Chemical Society
References ref9/cit9
ref45/cit45
ref3/cit3
ref27/cit27
ref56/cit56
Llewellyn P. L. (ref35/cit35) 2007; 168
ref16/cit16
ref52/cit52
ref23/cit23
ref59/cit59
ref2/cit2
ref34/cit34
ref37/cit37
ref20/cit20
ref48/cit48
ref60/cit60
ref17/cit17
ref10/cit10
ref53/cit53
ref19/cit19
ref21/cit21
Graeme S. (ref5/cit5) 2004
ref42/cit42
ref46/cit46
Guth J. L. (ref31/cit31) 1986; 28
ref49/cit49
ref13/cit13
ref61/cit61
Pérez-Botella E. (ref8/cit8) 2019
ref24/cit24
ref38/cit38
ref50/cit50
ref54/cit54
Kärger J. (ref33/cit33) 2012
ref6/cit6
ref36/cit36
ref18/cit18
ref11/cit11
ref25/cit25
ref29/cit29
ref32/cit32
ref39/cit39
ref14/cit14
ref57/cit57
ref51/cit51
ref28/cit28
ref40/cit40
ref26/cit26
ref55/cit55
Frisch M. J. (ref43/cit43) 2009
ref12/cit12
ref15/cit15
ref41/cit41
ref58/cit58
ref22/cit22
ref4/cit4
ref30/cit30
ref47/cit47
ref1/cit1
ref44/cit44
ref7/cit7
References_xml – ident: ref13/cit13
  doi: 10.1021/ie960472f
– ident: ref37/cit37
  doi: 10.1021/acs.jpcc.7b05347
– ident: ref20/cit20
– ident: ref21/cit21
  doi: 10.2174/2211334711205030001
– ident: ref9/cit9
– ident: ref14/cit14
– ident: ref50/cit50
  doi: 10.1021/jp0447439
– start-page: 173
  volume-title: Nanoporous Materials for Gas Storage
  year: 2019
  ident: ref8/cit8
  doi: 10.1007/978-981-13-3504-4_7
  contributor:
    fullname: Pérez-Botella E.
– ident: ref25/cit25
– ident: ref28/cit28
  doi: 10.1002/ppsc.200400923
– ident: ref29/cit29
  doi: 10.1039/C7TA10002G
– ident: ref34/cit34
  doi: 10.1002/aic.690110125
– ident: ref46/cit46
  doi: 10.1039/b101267n
– ident: ref26/cit26
  doi: 10.1021/ja405088c
– ident: ref56/cit56
  doi: 10.1021/ja974336t
– ident: ref45/cit45
  doi: 10.1515/pac-2014-1117
– ident: ref48/cit48
  doi: 10.1039/B304209J
– volume-title: Gaussian 09
  year: 2009
  ident: ref43/cit43
  contributor:
    fullname: Frisch M. J.
– ident: ref19/cit19
– ident: ref22/cit22
– ident: ref6/cit6
  doi: 10.1002/anie.200454058
– ident: ref53/cit53
  doi: 10.1021/jp980674k
– ident: ref23/cit23
– ident: ref58/cit58
  doi: 10.1021/acs.langmuir.8b00628
– ident: ref4/cit4
  doi: 10.1016/j.ccr.2011.03.014
– ident: ref42/cit42
  doi: 10.1002/qua.560200703
– ident: ref11/cit11
  doi: 10.1002/anie.201205040
– ident: ref16/cit16
– ident: ref49/cit49
  doi: 10.1021/jp0376727
– volume-title: Advanced Solutions for Paraffins Isomerization
  year: 2004
  ident: ref5/cit5
  contributor:
    fullname: Graeme S.
– ident: ref44/cit44
  doi: 10.1039/ft9918701947
– ident: ref52/cit52
  doi: 10.1016/j.cej.2007.11.026
– volume: 168
  volume-title: Introduction to Zeolite Science and Practice
  year: 2007
  ident: ref35/cit35
  doi: 10.1016/S0167-2991(07)80805-6
  contributor:
    fullname: Llewellyn P. L.
– ident: ref1/cit1
  doi: 10.1080/10916466.2015.1050506
– ident: ref2/cit2
  doi: 10.1080/10916466.2010.504931
– ident: ref61/cit61
  doi: 10.1007/s10450-007-9010-z
– ident: ref51/cit51
  doi: 10.1016/S0009-2509(02)00580-8
– volume-title: Diffusion in Nanoporous Materials
  year: 2012
  ident: ref33/cit33
  doi: 10.1002/9783527651276
  contributor:
    fullname: Kärger J.
– ident: ref38/cit38
  doi: 10.1107/S0108768187098173
– ident: ref10/cit10
  doi: 10.1039/b103118j
– ident: ref3/cit3
  doi: 10.1021/acs.energyfuels.9b00704
– ident: ref32/cit32
– ident: ref24/cit24
– ident: ref57/cit57
  doi: 10.1021/jp982736c
– ident: ref60/cit60
  doi: 10.1126/science.aao0092
– ident: ref12/cit12
  doi: 10.1016/j.seppur.2012.12.017
– ident: ref41/cit41
  doi: 10.1021/acs.jpcc.5b06010
– ident: ref59/cit59
  doi: 10.1021/jp040216d
– ident: ref36/cit36
  doi: 10.1080/08927022.2015.1010082
– ident: ref18/cit18
  doi: 10.1002/aic.690480910
– ident: ref17/cit17
– ident: ref39/cit39
– ident: ref40/cit40
  doi: 10.1016/S0263-7855(96)00043-4
– ident: ref55/cit55
  doi: 10.1016/j.micromeso.2010.03.004
– volume: 28
  start-page: 121
  volume-title: Studies in Surface Science and Catalysis
  year: 1986
  ident: ref31/cit31
  contributor:
    fullname: Guth J. L.
– ident: ref27/cit27
  doi: 10.1021/jp984055n
– ident: ref15/cit15
  doi: 10.2516/ogst/2009073
– ident: ref7/cit7
– ident: ref54/cit54
  doi: 10.1039/b100941i
– ident: ref47/cit47
  doi: 10.1021/jp0264533
– ident: ref30/cit30
SSID ssj0053013
Score 2.436989
Snippet The adsorption of linear, monobranched and dibranched saturated hydrocarbons in the gasoline range has been studied on pure silica STW zeolite (Si-STW) by...
SourceID crossref
acs
SourceType Aggregation Database
Publisher
StartPage 26821
SubjectTerms C: Surfaces, Interfaces, Porous Materials, and Catalysis
Title Insights into Adsorption of Linear, Monobranched, and Dibranched Alkanes on Pure Silica STW Zeolite as a Promising Material for Their Separation
URI http://dx.doi.org/10.1021/acs.jpcc.0c08517
Volume 124
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1LT8MwDI5gHODCG_GWD3BAWkeStcl2nAZoIA0hbROIS5UmqRigdlq7C7-Cn4zTdgLxkDg2atLKcezviy2bkBNKTTtiLPKkRvjmSxl4ETPM423BNBOqJbW77-jfit7Iv3kIHj7L5HyP4HN2rnTWeJ5o3aDawQO5SJa4SyB0MKg7mFvdABW1WUaQETH6vqxCkr-t4ByRzr44oi8e5WqtbE2UFYUIXSLJS2OWRw399rNM4z9-dp2sVsASOqUmbJAFm2yS5e68n9sWeb9OMsfEMxgneQodk6XTwl5AGgNSUlT5OuARTyPXa-PJmjqoxMDFeP4MndcXhZYRcMrdbGphMHY3fjAY3sOjdXl0FlQGCu6mKX4UfSL0VV5oOCA0hqGLScDAltXG02SbjK4uh92eV_Vj8BRv0dzT1LbRIOCmMmGRWRpqqY1lIFkcuDI6WvqKKWFibhizImCxFk2f6ljifCRqzR1SS9LE7hJA2IAnP7I2Zm1f-C2FVJALRY1C-hZYukdOUZRhdZ6ysAiVcxYWgyjfsJLvHjmbb2I4Kctz_Pnu_j_XPCAr3JFqxtFHHZJaPp3ZI0QeeXRcqNwHQM3StQ
link.rule.ids 315,786,790,2782,27109,27957,27958,57093,57143
linkProvider American Chemical Society
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV3Nb9MwFH_axmG7wIAhCgzeYRyQls4vTez2WHWbuo9OE-20aZfIsR1RhpKpSS_8FfzJPKfJmBBIcIwVv1j2-_j9_JxngD0h7CAlSgNlGL5FSsVBSpaCcCDJkNR9Zfx-x-RCjq-i05v4Zg2o_ReGB1GypLJO4v-qLkAHvu3rvTFdYTxKUOvwJFZMxz0aGk1b5xuzvvZWiWQGjlGkmszknyT4eGTKR_HoUWA5fgafH4ZUnye56y6rtGu-_1at8b_GvA1PG5iJw5VePIc1l7-AzVF7u9tL-HGSl56XlzjPqwKHtiwWtffAIkMmqGwA-8gGX6T-5o0vzu6jzi0ezttnHH670-wnkbtcLhcOp3O__4fT2TXeOn-qzqEuUePlouCPcoTEia5qfUcGyjjzGQqculXt8SLfgavjo9loHDS3MwQ67IsqMMIN2D3wEpN0zDOtcMJlKlaUxb6ojlGRJi1tFloiJ2PKjOxFwmSK-zNt672CjbzI3WtABhHsB1LnMhpEMuprJoah1MJqJnOxEx34yFOZNNZVJnXiPKSkbuT5TZr57cCndi2T-1Wxjr----YfZX6AzfFscp6cn1ycvYWt0NNtCjl6vYONarF0u4xJqvR9rYU_AV1V2yA
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV3NT9swFH-CTgIusAETMNjeAQ5IpNhpYrfHqqyiMFCllg9xiRzb0QooqZr0sr9if_Ke0wQhtEnsGCt2LPt9_H5-znsAh4yZTsx57ElN8C2QMvRibrjndwTXXKi21O684-panN8EF_fh_RKE9b8wNImcRsrLIL7T6qlJqgwD_NS1P061bjLtkIJchg-hq9_tEFFvVBvgkGS2tQgmE3gMAllFJ_82gvNJOn_lk145l_4G3L5Mq7xT8tScF3FT_3qTsfG_5_0R1iu4id2FfHyCJZtuwmqvrvK2Bb8Hae74eY6TtMiwa_JsVloRzBIkokqKcIKk-FnsKnD8tOYEVWrwbFI_Y_f5SZG9ROoynM8sjibuHBBH4zt8sO52nUWVo8LhLKOPkqfEK1WUco8EmHHsIhU4sosc5Fm6DTf97-PeuVdVafCU32aFp5ntkJmgrebCEt80zDKbSNqYJHTJdbQMFFfCJL7h3IqQJ1q0AqYTSf2JvrU-QyPNUrsDSGCC7EFsbcI7gQjaigiiLxQzikhdaNkuHNFSRpWW5VEZQPd5VDbS-kbV-u7Ccb2f0XSRtOOf7-69c8xvsDI860c_BteXX2DNd6yb--TE9qFRzOb2gKBJEX8tBfEPfv_dmg
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Insights+into+Adsorption+of+Linear%2C+Monobranched%2C+and+Dibranched+Alkanes+on+Pure+Silica+STW+Zeolite+as+a+Promising+Material+for+Their+Separation&rft.jtitle=Journal+of+physical+chemistry.+C&rft.au=Pe%CC%81rez-Botella%2C+Eduardo&rft.au=Misturini%2C+Alechania&rft.au=Sala%2C+Andre%CC%81s&rft.au=Palomino%2C+Miguel&rft.date=2020-12-10&rft.pub=American+Chemical+Society&rft.issn=1932-7447&rft.eissn=1932-7455&rft.volume=124&rft.issue=49&rft.spage=26821&rft.epage=26829&rft_id=info:doi/10.1021%2Facs.jpcc.0c08517&rft.externalDocID=b92308036
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1932-7447&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1932-7447&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1932-7447&client=summon