Polymer Nanoparticles for the Release of Fragrances: How the Physicochemical Properties Influence the Adsorption on Textile and the Delivery of Limonene
The market of cosmetic and personal care products is continuously growing its impact. In particular, the products that are currently driving this growth have a strict connection with fragrances (e.g., perfumes, detergents, body creams, and softeners). Since the fragrances are volatile molecules, ver...
Saved in:
Published in | Industrial & engineering chemistry research Vol. 59; no. 28; pp. 12766 - 12773 |
---|---|
Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
15.07.2020
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | The market of cosmetic and personal care products is continuously growing its impact. In particular, the products that are currently driving this growth have a strict connection with fragrances (e.g., perfumes, detergents, body creams, and softeners). Since the fragrances are volatile molecules, very often, they are encapsulated in polymeric nanoparticles (NPs) that mediate their release and hence prolong the fragrance perception. Toward this aim, it is highly desirable to maximize the interaction between the carrier and the substrate, which would avoid the NP desorption following scrubbing and repeated washing. In the case of laundry products, limited NP desorption is also crucial to prevent the accumulation of nanoplastics in the environment, which is nowadays strictly regulated. Therefore, a thorough study highlighting the influence of the different physicochemical properties of the NPs on their adsorption behavior is urgently required. In this work, we synthesized polymer NPs with different sizes, surface charges, glass transition temperatures, and degrees of cross-linking through emulsion free-radical polymerization to investigate how these parameters affect the NP adsorption onto a textile substrate (composition: 90% cotton/10% elastane). This study can provide interesting guidelines in the design of new fragrance delivery systems as well as in the optimization of those already adopted in the market. Finally, we investigated the possibility of loading and mediating the release in air of limonene, one of the most common odorous molecules in the cosmetic field, overcoming its well-known volatility. |
---|---|
AbstractList | The market of cosmetic and personal care products is continuously growing its impact. In particular, the products that are currently driving this growth have a strict connection with fragrances (e.g., perfumes, detergents, body creams, and softeners). Since the fragrances are volatile molecules, very often, they are encapsulated in polymeric nanoparticles (NPs) that mediate their release and hence prolong the fragrance perception. Toward this aim, it is highly desirable to maximize the interaction between the carrier and the substrate, which would avoid the NP desorption following scrubbing and repeated washing. In the case of laundry products, limited NP desorption is also crucial to prevent the accumulation of nanoplastics in the environment, which is nowadays strictly regulated. Therefore, a thorough study highlighting the influence of the different physicochemical properties of the NPs on their adsorption behavior is urgently required. In this work, we synthesized polymer NPs with different sizes, surface charges, glass transition temperatures, and degrees of cross-linking through emulsion free-radical polymerization to investigate how these parameters affect the NP adsorption onto a textile substrate (composition: 90% cotton/10% elastane). This study can provide interesting guidelines in the design of new fragrance delivery systems as well as in the optimization of those already adopted in the market. Finally, we investigated the possibility of loading and mediating the release in air of limonene, one of the most common odorous molecules in the cosmetic field, overcoming its well-known volatility. |
Author | Ilare, Juri Polvara, Elisa Manfredini, Nicolò Contreras Mejia, Daniel Invernizzi, Marzio Sironi, Selena Sponchioni, Mattia Moscatelli, Davide |
AuthorAffiliation | Department of Chemistry, Materials and Chemical Engineering |
AuthorAffiliation_xml | – name: Department of Chemistry, Materials and Chemical Engineering |
Author_xml | – sequence: 1 givenname: Nicolò surname: Manfredini fullname: Manfredini, Nicolò – sequence: 2 givenname: Juri surname: Ilare fullname: Ilare, Juri – sequence: 3 givenname: Marzio surname: Invernizzi fullname: Invernizzi, Marzio – sequence: 4 givenname: Elisa surname: Polvara fullname: Polvara, Elisa – sequence: 5 givenname: Daniel surname: Contreras Mejia fullname: Contreras Mejia, Daniel – sequence: 6 givenname: Selena surname: Sironi fullname: Sironi, Selena – sequence: 7 givenname: Davide orcidid: 0000-0003-2759-9781 surname: Moscatelli fullname: Moscatelli, Davide – sequence: 8 givenname: Mattia orcidid: 0000-0002-8130-6495 surname: Sponchioni fullname: Sponchioni, Mattia email: mattia.sponchioni@polimi.it |
BookMark | eNp1kN1OwjAUxxuDiYjee9kHcNhu7Ta9IyhCQpQYvF5qdyolXUvaoe5NfFw74NbkJL34f5zT3yUaWGcBoRtKxpSk9E7IMNYg_ZhIkpKCn6Eh5SlJOGF8gIakLMuElyW_QJchbAkhnDM2RL8rZ7oGPH4R1u2Eb7U0ELByHrcbwG9gQATATuGZF59eWAnhAc_d90FebbqgpZMbaLQUBq-820HsiA0Lq8weov1gnNTB-V2rncVx1vDTagNY2PqgPoLRX-C7fs1SN_FjFq7QuRImwPXpHaH32dN6Ok-Wr8-L6WSZiLQkbSJUBh-KCJCQ3Rd1zoHyUhZ5nZdcsTpjwFJaF4LlgitZABRpVrCYqYlQNKPZCJFjr_QuBA-q2nndCN9VlFQ92SqSrXqy1YlsjNweI72ydXtv44H_2_8AMjSClg |
CitedBy_id | crossref_primary_10_1016_j_eurpolymj_2023_112421 crossref_primary_10_1016_j_colsurfa_2022_128453 crossref_primary_10_1002_mame_202200443 crossref_primary_10_1016_j_cep_2021_108440 crossref_primary_10_3390_molecules25245878 crossref_primary_10_1080_02652048_2023_2178538 crossref_primary_10_1021_acsapm_1c01266 crossref_primary_10_3390_polym14235188 crossref_primary_10_3390_polym13071032 crossref_primary_10_1016_j_porgcoat_2023_107605 crossref_primary_10_1021_acs_iecr_2c00129 crossref_primary_10_1039_D0RE00252F crossref_primary_10_1002_ffj_3711 crossref_primary_10_1007_s10924_021_02173_8 crossref_primary_10_3390_ijms24054685 crossref_primary_10_1016_j_colsurfa_2024_134714 crossref_primary_10_1021_acsami_2c16205 crossref_primary_10_3390_textiles2010003 |
Cites_doi | 10.1021/acsami.8b10717 10.1039/c3cs60286a 10.1039/c8py00863a 10.1016/j.surfin.2017.08.009 10.1002/masy.201300047 10.1021/acs.molpharmaceut.6b00753 10.1039/c8re00221e 10.1002/app.41678 10.2184/lsj.8.310 10.1111/j.1478-4408.2005.tb00277.x 10.1002/ffj.2039 10.1021/acs.iecr.9b04214 10.1016/j.carbpol.2017.11.007 10.4028/www.scientific.net/AMR.535-537.440 10.1007/978-3-319-26932-0 10.1002/adfm.201603843 10.1039/c6ra16030a 10.3390/polym10080851 10.1016/j.snb.2012.03.029 10.1016/j.aca.2015.11.031 10.1021/ma501388w 10.1016/B978-0-08-100262-9.00012-4 10.1016/j.colsurfb.2020.110926 10.1016/j.jconrel.2018.07.008 10.1002/aic.16461 10.1371/journal.pone.0055780 10.1021/acs.iecr.9b05104 10.1016/j.cej.2014.02.024 10.1002/macp.201700380 10.1002/app.33900 |
ContentType | Journal Article |
DBID | AAYXX CITATION |
DOI | 10.1021/acs.iecr.0c02075 |
DatabaseName | CrossRef |
DatabaseTitle | CrossRef |
DatabaseTitleList | |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Engineering |
EISSN | 1520-5045 |
EndPage | 12773 |
ExternalDocumentID | 10_1021_acs_iecr_0c02075 f07752360 |
GroupedDBID | 02 53G 55A 5GY 7~N AABXI ABFLS ABMVS ABPTK ABUCX ACJ ACS AEESW AENEX AFEFF ALMA_UNASSIGNED_HOLDINGS AQSVZ CS3 DU5 EBS ED ED~ F5P GNL IH9 JG JG~ LG6 P2P ROL TAE TN5 UI2 VF5 VG9 W1F WH7 X -~X .DC .K2 4.4 5VS 6TJ AAYXX ABQRX ACGFO ADHLV AGXLV AHGAQ BAANH CITATION CUPRZ GGK ~02 |
ID | FETCH-LOGICAL-a280t-af3ebf0aece397d65e158c76d685f4d34e421d7a46a5fc7ee723743ebd0af1313 |
IEDL.DBID | ACS |
ISSN | 0888-5885 |
IngestDate | Fri Aug 23 02:54:33 EDT 2024 Thu Aug 27 13:41:54 EDT 2020 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 28 |
Language | English |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-a280t-af3ebf0aece397d65e158c76d685f4d34e421d7a46a5fc7ee723743ebd0af1313 |
ORCID | 0000-0003-2759-9781 0000-0002-8130-6495 |
PageCount | 8 |
ParticipantIDs | crossref_primary_10_1021_acs_iecr_0c02075 acs_journals_10_1021_acs_iecr_0c02075 |
ProviderPackageCode | JG~ 55A AABXI GNL VF5 7~N ACJ VG9 W1F ACS AEESW AFEFF ABMVS ABUCX IH9 AQSVZ ED~ UI2 |
PublicationCentury | 2000 |
PublicationDate | 20200715 2020-07-15 |
PublicationDateYYYYMMDD | 2020-07-15 |
PublicationDate_xml | – month: 07 year: 2020 text: 20200715 day: 15 |
PublicationDecade | 2020 |
PublicationTitle | Industrial & engineering chemistry research |
PublicationTitleAlternate | Ind. Eng. Chem. Res |
PublicationYear | 2020 |
Publisher | American Chemical Society |
Publisher_xml | – name: American Chemical Society |
References | ref9/cit9 ref6/cit6 ref3/cit3 ref27/cit27 ref11/cit11 ref16/cit16 ref29/cit29 Appell L. (ref35/cit35) 1969 ref32/cit32 ref23/cit23 ref14/cit14 ref8/cit8 ref5/cit5 ref31/cit31 ref2/cit2 ref34/cit34 ref28/cit28 ref20/cit20 ref17/cit17 ref10/cit10 Abadie M. J. M. (ref18/cit18) 2006; 15 ref26/cit26 ref19/cit19 ref21/cit21 ref12/cit12 ref15/cit15 ref22/cit22 ref13/cit13 ref33/cit33 ref4/cit4 ref30/cit30 ref24/cit24 ref7/cit7 |
References_xml | – ident: ref27/cit27 doi: 10.1021/acsami.8b10717 – start-page: 45 year: 1969 ident: ref35/cit35 publication-title: Am. Perfum. Cosmet. contributor: fullname: Appell L. – ident: ref21/cit21 doi: 10.1039/c3cs60286a – ident: ref2/cit2 doi: 10.1039/c8py00863a – volume: 15 start-page: 65 year: 2006 ident: ref18/cit18 publication-title: Iran. Polym. J. contributor: fullname: Abadie M. J. M. – ident: ref17/cit17 doi: 10.1016/j.surfin.2017.08.009 – ident: ref24/cit24 doi: 10.1002/masy.201300047 – ident: ref20/cit20 doi: 10.1021/acs.molpharmaceut.6b00753 – ident: ref33/cit33 doi: 10.1039/c8re00221e – ident: ref4/cit4 doi: 10.1002/app.41678 – ident: ref34/cit34 doi: 10.2184/lsj.8.310 – ident: ref32/cit32 doi: 10.1111/j.1478-4408.2005.tb00277.x – ident: ref5/cit5 doi: 10.1002/ffj.2039 – ident: ref14/cit14 doi: 10.1021/acs.iecr.9b04214 – ident: ref15/cit15 doi: 10.1016/j.carbpol.2017.11.007 – ident: ref8/cit8 – ident: ref22/cit22 doi: 10.4028/www.scientific.net/AMR.535-537.440 – ident: ref12/cit12 doi: 10.1007/978-3-319-26932-0 – ident: ref6/cit6 doi: 10.1002/adfm.201603843 – ident: ref23/cit23 doi: 10.1039/c6ra16030a – ident: ref29/cit29 doi: 10.3390/polym10080851 – ident: ref10/cit10 doi: 10.1016/j.snb.2012.03.029 – ident: ref9/cit9 doi: 10.1016/j.aca.2015.11.031 – ident: ref19/cit19 doi: 10.1021/ma501388w – ident: ref28/cit28 doi: 10.1016/B978-0-08-100262-9.00012-4 – ident: ref26/cit26 doi: 10.1016/j.colsurfb.2020.110926 – ident: ref7/cit7 doi: 10.1016/j.jconrel.2018.07.008 – ident: ref13/cit13 doi: 10.1002/aic.16461 – ident: ref11/cit11 doi: 10.1371/journal.pone.0055780 – ident: ref30/cit30 doi: 10.1021/acs.iecr.9b05104 – ident: ref16/cit16 doi: 10.1016/j.cej.2014.02.024 – ident: ref31/cit31 doi: 10.1002/macp.201700380 – ident: ref3/cit3 doi: 10.1002/app.33900 |
SSID | ssj0005544 |
Score | 2.4721227 |
Snippet | The market of cosmetic and personal care products is continuously growing its impact. In particular, the products that are currently driving this growth have a... |
SourceID | crossref acs |
SourceType | Aggregation Database Publisher |
StartPage | 12766 |
SubjectTerms | Materials and Interfaces |
Title | Polymer Nanoparticles for the Release of Fragrances: How the Physicochemical Properties Influence the Adsorption on Textile and the Delivery of Limonene |
URI | http://dx.doi.org/10.1021/acs.iecr.0c02075 |
Volume | 59 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1LSwMxEA5aL3rwLb7JQQ8etu5mN5utt6KWKipFW-htyWMiorbSrUj9Jf5cJ-kWiw8Q9rQJyZJNZr5kJt9HyEEaWsGdoImUigcJN7UgU1IGUaJT70DH18eub9JmJ7ns8u4XTc73CD6LjqUuqg8IoaqhRmgj-CyZYyKsufSt-undVzoH98KtuGjcTaKMlyHJ31pwjkgXU45oyqM0lsbSRIUnInSJJI_V16Gq6vefNI3_-NhlslgCS1ofz4QVMgO9VbIwRTe4Rj5a_afRMwwomlTcK5cpcRRhK0UYSG_RA6FPo31LEc7eO8UNKE5os__mi32uqHYCW55hgLbcMf7A8bHSi4nSia9YN0V_4C0RxaeN1h8tD5U940vP4MmlgoxcN1c4UXpobNdJp3HePm0GpTJDIFkWDgNpY1A2lKAB8YxJOUQ80yI1acZtYuIEEhYZIZNUcqsFgGAxQhVQJpQ2iqN4g1R62MEmoYYpgFSJmrGQ1KSrwmTGBdhIGZPBFjnEQc3LlVXkPmjOoty9dCOdlyO9RY4mvzN_GRN1_Fl3-59t7pB55rbXjkeT75LKcPAKe4hBhmrfT75PxiPbQg |
link.rule.ids | 315,786,790,2778,27098,27946,27947,57082,57132 |
linkProvider | American Chemical Society |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1NT9wwEB1ROLQc-GiLgFLqQ3voIds4ieMsNwRFS9ldIbpI3CI7HiMEZFEShOCX8HM79mbLClGJSjnZlm059rxne_wG4GsaWilcQBOltAgSYbpBppUKeFKkHkAnz8cGw7R3mvw6E2dzwKdvYagTNdVU-0v8J3UB_sOlXRCT6oQFMRwp3sCCkIRfjg3t_X7y6hA-fiutHfegKBPtzeRLNTg8KuoZPJoBloNlOPnbJe9Pctm5bXSneHim1vhffV6BpZZmst3JvFiFOSzfw-KM-OAHeDweX91fY8XIwNLOuXWQY0RiGZFCdkJ4RAjHxpYRuT138Tew3mG98Z3P9p6jhQu35fUG2LE71K-cOis7nMY98QV3TT2uvF1i9I0IC8gOMVUan7uPV84x5N4106dpU5Lp_QinBz9He72gjdMQqCgLm0DZGLUNFRZI7MakArnICpmaNBM2MXGCScSNVEmqhC0kooxiIi6oTagsj3m8BvMlNbAOzEQaMdWyaywmXeWKRCoTEi3XxmS4Ad9oUPN2ndW5v0KPeO4S3Ujn7UhvwPfpX81vJrId_yy7-co6v8Db3mjQz_uHw6NP8C5yG2-nsCm2YL6pbvEzsZNGb_v5-AdrdeOk |
linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1LT-MwEB4BKyE4sMtLPBbwAQ4cUvJyknKrgKo8VfESt8iOx6sV0KKmaMX-En4uM24KFQIJpJxsy7Yce-azPf4-gM3Et6lkQROltPRiaepeppXygrhInAMdPB87PUtaV_HRjbwZAzl8C0OdKKmm0l3i86p-MLZiGAh2OP0voamaXxDKSeU4_JC0yWLhgsbexVtkh3QarrR--FFRJqvbyY9qYJ9UlCM-acS5NH_C9Wu3XEzJbe2xr2vF_3eMjd_u9y-YqeCmaAzmxyyMYWcOpkdICOfhud29e7rHniBDSzvoKlBOEJgVBA7FOfkl8nSiawWB3D-sw4Hlrmh1_7lsF0FasOyW4x0QbT7c7zFLqzgc6p-4gg1TdnvOPgn6LsknkD0SqmNc7j7ecYDIEzdzQtOnQyZ4Aa6aB5d7La_Sa_BUmPl9T9kItfUVFkgoxyQSA5kVaWKSTNrYRDHGYWBSFSdK2iJFTMOIAAxq4ysbREG0CBMdamAJhAk1YqLTurEY1xUXCVUmU7SBNibDZdiiQc2r9Vbm7io9DHJO5JHOq5Fehu3hn80fBvQdn5Zd-WKdGzDZ3m_mJ4dnx6swFfL-m4k25W-Y6PcecY1ASl-vuyn5AqJ85h4 |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Polymer+Nanoparticles+for+the+Release+of+Fragrances%3A+How+the+Physicochemical+Properties+Influence+the+Adsorption+on+Textile+and+the+Delivery+of+Limonene&rft.jtitle=Industrial+%26+engineering+chemistry+research&rft.au=Manfredini%2C+Nicolo%CC%80&rft.au=Ilare%2C+Juri&rft.au=Invernizzi%2C+Marzio&rft.au=Polvara%2C+Elisa&rft.date=2020-07-15&rft.pub=American+Chemical+Society&rft.issn=0888-5885&rft.eissn=1520-5045&rft.volume=59&rft.issue=28&rft.spage=12766&rft.epage=12773&rft_id=info:doi/10.1021%2Facs.iecr.0c02075&rft.externalDocID=f07752360 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0888-5885&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0888-5885&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0888-5885&client=summon |