Unexpected High-Substrate-Dependent Ketonization of Aldose on Niobium Phosphate-Supported Magnesia: An Emphasis on Surface Chemisorption

• Published in: Industrial & engineering chemistry research Vol. 61; no. 50; pp. 18362 - 18371
• Main Authors: Gao, Da-Ming, Zhang, Shuoqi, Lei, Tingzhou, Zhu, Jie, Huhe, Taoli, Sun, Fuan, Zeng, Guixiang, Liu, Haichao
• Format: Journal Article
• Language: English
• Published: American Chemical Society 21.12.2022
• Subjects: Kinetics, Catalysis, and Reaction Engineering

A water-tolerant magnesia-based solid base was prepared by combining the use of a non-equilibrium and highly structured dual-porous niobium phosphate (NbP) as the support and high-temperature thermal treatment. The crystal growth of MgO changed, and the bond length of Mg–O was longer than that of pu...