Rh(II)-Catalyzed Enynal Cycloisomerization for the Generation of Vinyl Carbene: Divergent Access to Polycyclic Heterocycles
Described herein is an unprecedented example of generating the endocyclic donor–donor vinyl carbene achieved by the dirhodium(II)-catalyzed enynal cycloisomerization. The endocyclic vinyl carbene intermediate could be trapped by a diversity of alkenes, including 1,1-disubstituted alkenes, dienes, a...
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Published in | ACS catalysis Vol. 13; no. 1; pp. 132 - 140 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
06.01.2023
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Subjects | |
Online Access | Get full text |
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