Competitive Coordination of Azide Groups: Synthesis of Solvent-Free and Chlorine-Free Primary Explosives Based on 3‑Amino-1-nitroguanidine

A safe synthesis method for a new generation of primary explosives based on the guiding ideology of the coordination chemistry strategy with excellent performance capabilities has been developed. Based on 3-amino-1-nitroguanidine (ANQ), metal cations Co­(II), Ni­(II), and high-energy azide groups (N...

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Published inCrystal growth & design Vol. 21; no. 12; pp. 7002 - 7007
Main Authors Wang, Ting-wei, Wang, Xiao-jun, Yi, Zhen-xin, Cao, Wen-li, Dong, Wen-shuai, Bi, Yu-fan, Zhu, Shun-guan, Zhang, Jian-Guo
Format Journal Article
LanguageEnglish
Published American Chemical Society 01.12.2021
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Abstract A safe synthesis method for a new generation of primary explosives based on the guiding ideology of the coordination chemistry strategy with excellent performance capabilities has been developed. Based on 3-amino-1-nitroguanidine (ANQ), metal cations Co­(II), Ni­(II), and high-energy azide groups (N3 –), we created two coordination polymer primary explosives which are solvent-free and chlorine-free, and further confirmed by IR, elemental analysis, and single crystal X-ray diffraction. Thermal stability experiments have shown that their thermal decomposition temperature all exceed 170 °C. Sensitivity test and explosion parameter simulation show that 2 and 3 have excellent detonation performance and safety performance. In addition, the results of the initiating efficiency test support that 2 can be used as a suitable primary explosive.
AbstractList A safe synthesis method for a new generation of primary explosives based on the guiding ideology of the coordination chemistry strategy with excellent performance capabilities has been developed. Based on 3-amino-1-nitroguanidine (ANQ), metal cations Co­(II), Ni­(II), and high-energy azide groups (N3 –), we created two coordination polymer primary explosives which are solvent-free and chlorine-free, and further confirmed by IR, elemental analysis, and single crystal X-ray diffraction. Thermal stability experiments have shown that their thermal decomposition temperature all exceed 170 °C. Sensitivity test and explosion parameter simulation show that 2 and 3 have excellent detonation performance and safety performance. In addition, the results of the initiating efficiency test support that 2 can be used as a suitable primary explosive.
Author Wang, Ting-wei
Cao, Wen-li
Wang, Xiao-jun
Yi, Zhen-xin
Dong, Wen-shuai
Zhang, Jian-Guo
Zhu, Shun-guan
Bi, Yu-fan
AuthorAffiliation School of Chemical Engineering
State Key Laboratory of Explosion Science and Technology
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Title Competitive Coordination of Azide Groups: Synthesis of Solvent-Free and Chlorine-Free Primary Explosives Based on 3‑Amino-1-nitroguanidine
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