A Simple Method To Produce Dendrimer Nanodots over Centimeter Scales by Rapid Evaporation of Solvents

A simple method to produce aggregates of dendrimers in a form of nanometer-sized round dots over an area measured in centimeters is presented. The method is based on rapid evaporation of a solvent from a thin cast film of an electrolyte solution of polyamidoamine dendrimers on mica. Chemically speci...

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Published inLangmuir Vol. 17; no. 6; pp. 1807 - 1810
Main Authors Sano, Masahito, Okamura, Junko, Ikeda, Atsushi, Shinkai, Seiji
Format Journal Article
LanguageEnglish
Published American Chemical Society 23.03.2001
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Abstract A simple method to produce aggregates of dendrimers in a form of nanometer-sized round dots over an area measured in centimeters is presented. The method is based on rapid evaporation of a solvent from a thin cast film of an electrolyte solution of polyamidoamine dendrimers on mica. Chemically specific adsorption, electrostatic interactions, phase transitions, and dewetting instabilities are shown not to be responsible for the dot formation. Changes in temperature and humidity have only little effect. There is a threshold evaporation rate above which the dots are formed. Once formed, the dot size and spacing are independent of the evaporation rate. The dot is also formed by different types of dendrimers and solutes, demonstrating the wide applicability of the present method.
AbstractList A simple method to produce aggregates of dendrimers in a form of nanometer-sized round dots over an area measured in centimeters is presented. The method is based on rapid evaporation of a solvent from a thin cast film of an electrolyte solution of polyamidoamine dendrimers on mica. Chemically specific adsorption, electrostatic interactions, phase transitions, and dewetting instabilities are shown not to be responsible for the dot formation. Changes in temperature and humidity have only little effect. There is a threshold evaporation rate above which the dots are formed. Once formed, the dot size and spacing are independent of the evaporation rate. The dot is also formed by different types of dendrimers and solutes, demonstrating the wide applicability of the present method.
Author Okamura, Junko
Sano, Masahito
Ikeda, Atsushi
Shinkai, Seiji
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