Tremella-like Zn–Al–Zr-Layered Double-Hydroxide/Graphene Oxide Nanocomposites for Enhanced Phosphorus Recovery

By virtue of the hydroxyl and carboxyl groups on the graphene oxide (GO) plane, three-dimensional tremella-like Zn–Al–Zr-layered double-hydroxide/GO (Zn–Al–Zr LDH/GO) nanocomposites have been successfully prepared via the self-assembly process. As compared to Zn–Al–Zr LDH, the Zn–Al–Zr LDH/GO nanoco...

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Published inACS applied nano materials Vol. 7; no. 2; pp. 2143 - 2154
Main Authors Ren, Jianhui, Huang, Yao-Yao, Li, Dongmei, Yu, Miao, Chen, Lin, Wang, Jun, Xiong, Kun
Format Journal Article
LanguageEnglish
Published American Chemical Society 26.01.2024
Subjects
phosphorus recovery
graphene oxide
self-assembly
layered double hydroxide
eutrophication
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Abstract By virtue of the hydroxyl and carboxyl groups on the graphene oxide (GO) plane, three-dimensional tremella-like Zn–Al–Zr-layered double-hydroxide/GO (Zn–Al–Zr LDH/GO) nanocomposites have been successfully prepared via the self-assembly process. As compared to Zn–Al–Zr LDH, the Zn–Al–Zr LDH/GO nanocomposite (LDH/GO-4) possesses a hierarchical pore structure; it shows an enlarged pore width which endows it with enhanced phosphorus (P) adsorption capacity, and the fitting of nonlinear Langmuir showed that the maximum adsorption capacity reaches 36.86 ± 0.76 mg-P/g. The fitting of the kinetic model confirmed that the adsorption process was predominantly chemisorption. Meanwhile, fitting of the thermodynamic model indicated that the adsorption process was endothermic, stochastic, and spontaneous. For LDH/GO-4, the [−C–O–Zn­(OH) x ] and [−COO–ZrO­(OH) x ] groups are its chief active sites to chemically absorb P. In this study, LDH/GO-4 can make the total phosphorus (TP) concentration of the real river water decline from 0.28 mg/L to near zero in 24 h, while the Phoslock commercial product only achieves a TP removal rate of 46.43% under the same conditions. Moreover, LDH/GO-4 also has good reusability in a steady recovery of P, and the removal rate of TP was still over 95% after it experienced the adsorption–desorption of P for five cycles. Thus, LDH/GO-4 shows great potential for application in the sustainable P recovery field.
AbstractList By virtue of the hydroxyl and carboxyl groups on the graphene oxide (GO) plane, three-dimensional tremella-like Zn–Al–Zr-layered double-hydroxide/GO (Zn–Al–Zr LDH/GO) nanocomposites have been successfully prepared via the self-assembly process. As compared to Zn–Al–Zr LDH, the Zn–Al–Zr LDH/GO nanocomposite (LDH/GO-4) possesses a hierarchical pore structure; it shows an enlarged pore width which endows it with enhanced phosphorus (P) adsorption capacity, and the fitting of nonlinear Langmuir showed that the maximum adsorption capacity reaches 36.86 ± 0.76 mg-P/g. The fitting of the kinetic model confirmed that the adsorption process was predominantly chemisorption. Meanwhile, fitting of the thermodynamic model indicated that the adsorption process was endothermic, stochastic, and spontaneous. For LDH/GO-4, the [−C–O–Zn­(OH) x ] and [−COO–ZrO­(OH) x ] groups are its chief active sites to chemically absorb P. In this study, LDH/GO-4 can make the total phosphorus (TP) concentration of the real river water decline from 0.28 mg/L to near zero in 24 h, while the Phoslock commercial product only achieves a TP removal rate of 46.43% under the same conditions. Moreover, LDH/GO-4 also has good reusability in a steady recovery of P, and the removal rate of TP was still over 95% after it experienced the adsorption–desorption of P for five cycles. Thus, LDH/GO-4 shows great potential for application in the sustainable P recovery field.
Author Li, Dongmei
Yu, Miao
Chen, Lin
Xiong, Kun
Ren, Jianhui
Wang, Jun
Huang, Yao-Yao
AuthorAffiliation National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics
State Key Laboratory of Environment-Friendly Energy Materials, School of Materials and Chemistry
Southwest University of Science and Technology
Nantong Environmental Security Intelligent Technology Co., Ltd
Tianfu Institute of Research and Innovation
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Keywords phosphorus recovery
graphene oxide
self-assembly
layered double hydroxide
eutrophication
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Title Tremella-like Zn–Al–Zr-Layered Double-Hydroxide/Graphene Oxide Nanocomposites for Enhanced Phosphorus Recovery
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