Engineering Compositional Gradients in Ti-Silicalite‑1 Catalysts for Improved Olefins Epoxidation

• Published in: ACS catalysis Vol. 15; no. 9; pp. 6895 - 6905
• Main Authors: Huang, Chenfeng, Kwon, Ohsung, Yang, Taimin, Flaherty, David W., Rimer, Jeffrey D.
• Format: Journal Article
• Language: English
• Published: American Chemical Society 02.05.2025
• Subjects: eggshell; epoxidation; finned zeolite; seeded growth; TS-1; seeded growth; eggshell; epoxidation; TS-1; finned zeolite

Transitioning from conventional aluminosilicate zeolites to isostructures with alternative heteroatom compositions is a subject of growing interest because the unique properties of these materials offer advantages for relevant catalytic reactions. Replacing aluminum with different metal sites can al...